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Application of Fenton process for cod and phosphorus removal of cattle manure effluents

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Linnaeus ECO-TECH 2016 Kalmar, Sweden, November 21-23, 2016

249

APPLICATION OF FENTON PROCESS FOR

COD AND PHOSPHORUS REMOVAL OF

CATTLE MANURE EFFLUENTS

Ali Matinfar

Ghasem D. Najafpour

Maedeh Mohammadi

Noshirvani University of Technology

Iran

Abstract

Advanced oxidation processes (AOPs) are series of new, novel technologies in wastewater treatment. Such processes are able to treat high organic loading rate and toxic wastewaters by means of chemical oxidation. Fenton process, as an important subunit of AOPs, is a kind of newly enhanced methods that is used in wastewater treatment plants (WWTP). The reaction consists of at least two essential chemical compounds: H2O2 as an oxidant and FeSO4 as catalyst which are used in oxidation process.

For ease of operation (running at room temperature and atmospheric pressure), it does not required long retention time and cost-effectiveness of the chemicals are some of the advantages that are reported in literatures. Results of number of experimental data in different fields of studies such as textile, cosmetic, dye, olive-oil mill and pharmaceutical wastewater proved that it would be capable method in recalcitrant compounds removal like specific antibiotics. It is also able to decrease high organic and inorganic contaminants like phosphorus, heavy metals or particular dyes. In present study, the feasibility of Fenton reaction on COD and phosphorus removal of livestock wastewater is investigated. A COD removal of 84% was obtained at the optimum conditions such as H2O2/COD

andH2O2/Fe2+ratio of 0.067 and 1.23, respectively. In addition, total phosphorus removal was

calculated 99%. The results approved that Fenton process can be used as an effective pre- or post- treatment stage or even utilized as a single treatment process.

Keywords

Advanced oxidation processes, Fenton, Chemical oxygen demand, Scavenge; Hydroxyl radical, Cattle manure effluent

References

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