Analysis of water samples for the campaign 1919-20

(1)

.A.?IALYSIS OF WATER

SAMPLES

FOR THE CAMPAIGN 1919 -20.

****************************************

Copies to:

General Superintendent

....-.-General

Chemist

Assistant Chief Engineer

Superintendent

Traveling Chemist

Laboratory

(2)

I

..3

7

9

/{)

ANALYSIS OF

VL~TER

SAMPLES FOR THE CAMPAIGN 1919 - 20.

INDEX.

CITY WATER

PAGE 1

DITCH WATER

PAGE 2

WATER FROM VIBITE (A) PAN CONDENSOR

PAGE 3

WATER FROM BROWN

(BJ

PAN CONDENSOR

PAGE 4

WATER FRO!r BROWN

(CJ

PAN CONDENSOR

PAGE

5 WATER FROM EVAPORA.TOR CONDE!ifSOR

PAGE

6 WATER TO

WA.SH

PRESSES

PAGE

?

PURE BATTERY SUPPLY WATER

PAGE

8 IMPURE BATTERY SUPPLY WATER

PAGE 9

.S--

WATER FROM MUTE PAN COILS (PIG)

PAGE 10

µ' WATER FROM: BOILER FEED TANK

PAGE 11

(3)

EA.TON

_

Factory

___

0.amp_a.ign -19J.9

Kind of Water:

City

Water

Descripti .. n of Sample:

Average

Sample for the Campaign

Source of Water:

City Ma.ins.

This water is pumped

from

wells,

86 feet deep, looated

about 1/4 Mile Northwest of the Factory.

___

192_

0 _

ANALYSIS _{HYPOTHETICAL COMBINATIONS}

Silica Si02 Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl Sulphuric Acid 504 Carbonic Acid

co.

Organic and Volatile (by difference} TOT AL SOLIDS

COPIES TO Genrral Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

Parts Per I 00,000 Parts Per 100,000

4.16

Silica Si08

4.16 .45

Sodium Chloride NaCl

_4.53

9.83

Sodium Sulphate Na2S04

17.85

2.11

Sodium Carbonate Na2C03

7.56

Magnesium Chloride MgCI

2.75

Magnesium Sulphate MgS04

10.44

22.95

Magnesium Carbonate MgC03

13.61

Calciooi Chloride CaCl2

Calcium Sulphate CaS04

3.61

Calcium Carbonate CaC03

21.90

Ferrous Carbonate FeC03

.93

63.42

3.88

Organic and Volatile {by difference}

_3,88

67.30

TOT AL SOLIDS

_67.30

Page 1.

(4)

- - - - -

~=N

~ _

___

factory

Kind of Water:

DITCH WATER

Descriptian of Sample:

Average Sample for the Campaign

Saurceof Water:

Water ta.ken from Boye's sea.page ditch about 1/4 Mile East of the Factory.

ANALYSIS Silica SiO, Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl

Sulphuric Acid

so.

Carbonic Acid

co.

Organic and Volatile (by difference) TOT AL SOLIDS COPIES TO

General Supt. General Chemist Asst. Genl. Supt. Asst. Cbief Engine« Superintendent Traveling Chemist Laboratory HYPOTHETICAL COMBINATIONS Part, Per l 00,000

4.30

Silica Si02

.20

9.83

Sodium Sulphate Na,S04

2.66

Sodium Carbonate Na,C03

7.35

2.24

21.43

Magnesium Carbonate MgCQ3

15.79

Calcium Chloride CaCl2

Calcium Sulphate

easo.

63.80 ~.10

Organic and Volatile lby difference)

66.90

TOT AL SOLIDS

Page 2.

_

l9Z2_

_

Parts Per I 00,000

4.30

3.69

18.22

11.42

1.21

24.55 .41

63.80

3.10

66.90

(5)

-- -- -- -- -- -- -- -- =

EA.

,.,.

~N

__

_

.

Factory

Kind of Water:

Water from V/hi te Pan Condensor

Description of Sample:

Average Sample for the Campaign

Source of Water:

Ditch Water and condensation from V/hi te Pan.

ANALYSIS Silica Si02 Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl

Sulphuric Acid

so~

Carbonic Acid

co

.

Genn-al Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory HYPOTHETICAL Part. Per 100,000

3.55

Silica Si02

.17

10.03

2.46

6.40

Magnesium Chloride MgCl

1.94

Magnesium Sulphate

Mgso

.

20.52

15.16

Calcium Chloride CaC12

60.23

3.57

Organic and Volatile (by difference)

63.80

TOT AL SOLIDS

Page 3.

__

192 o__

COMBINATIONS Parts Per I 00,000

3.55

3.20

15.87

12.18 .10

24.98 .35

60.23

3.57

63.80

(6)

_ _ _ _ _ _ _EA.TON_ _ _ _

Factory

_{Campaign 19--19}

Kind of Water:

Water from Brown (B) Pan Condensor

Average Sample for the Campaign

Source of Water:

Ditch water and condensation

from Brown (B) Pan.

Part, p.,. I 00,000

Silica Si02

2.58

Silica Si02

Iron Fe

_.13

Calcium Ca

_10.1

₃

Sodium Sulphate Na,S04

Magnesium Mg

_2.50

Sodium Na

_7.09

_{Magnesium Chloride} _MgCI

Chlorine Cl

_2.14

_{Magnesium Sulphate} _MgS0₄

Sulphuric Acid

so.

_20.75

Carbonic Acid

co

.

Organic and Volatile (by difference) TOT AL SOLIDS

COPIES TO Genrral Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

15.95

61.27 5126

66.55

Calci1HD Chloride CaCl2

Ferrous Carbonate FeCOa

Organic and Volatile lby difference) TOT AL SOLIDS

Page 4.

_

192_0__

_

Paris Per 100,000

2.58

3.53

17.60

11.09 .90

25.30 .27

61.27

5.28

66.55

(7)

_

_ _ _

___EA.i'OlL_

__ -

_Factory

_{Campaign_ 1919}

Kind of Water:

Water from

Brown

( C) Pan Condensor

DescriptiGn of Sample:

Average Sample for

the

Campaign

Source of Water:

Ditch water and condensation from Brown {C) Pan

ANALYSIS Silica SiO, Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl

Sulphuric Acid

so.

Carbonic Acid C03

COPIES TO Gen~ral Supt. General Chemist Asst. Genl. Supt. Aost. Chief Engineer Superintendent Traveling Chemist Laboratory HYPOTHETICAL COMBINATIONS Parta Per 100.000

3.93

Silica SiO•

.10

9.45

2.50

7.05

2.04

20.88

14.85 ---60.80

5.30

66.10

TOT AL SOLIDS

Page

5.

T

_

192_0

_

Parta Per I 00.000

3.93

3.36

17.70

11.17 .83

23.60 .21

60.80

5.30

66.10 Ir

- ·Acting'chief Chemi,t.

(8)

EATON

.

Factory

Kind of Water:

_Water

_{from Evaporator Condenser}

Descripti<Jn of Sample:

Average Sample for the Campaign

Source of Water:

_Ditch

_{water and Condensation}

_{from the 5th effect}

of the Evaporators.

-

Campaign 1919

_

J92Q__

ANALYSIS HYPOTHETICAL COMBINATIONS

Silica Si02 Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl

Sulphuric Acid

so.

Carbonic Acid C03

TOT AL SOLIDS

COPIES TO General Supt. General Chemist Asst. Genl. Supt.

Asst. Chief Engineer Superintendent Traveling Chemist

Laboratory

l"arta Per I 00.000 Parr. Per l 00.000

3.51

Silica SiO,

3.51 .19

3.36 a.9o

23.97

2.62

9.08

2.04

Magnesium Sulphate

Mgso.

6.24

21.19

4.72

16.89

22.23 .39

64.42

4.58

69.00

TOT AL SOLIDS

_69.00

Page 6.

(9)

E..A.TON

_Factory

Kind of Water:

Water

to

Wa

sh

l'rC8$88

Average ;;;ample

f'Ol'

the Campaign

Source of Water:

s.ter from all !Ugh and I,ov,

E-Jthaust Traps

Overflow from Boiler Feed

Tank

W

ater from ooils

of

Brown

(B} and

(C}

?3ns

Water

from

s1,t~a~

chests

Of

the

Evar,oratorr

,

and drips from all heaters.

C mpalgn l_?l 9

Silica SiO, Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl

Sulphuric Acid

so.

Carbonic Acid

co

.

Gen~ral Supt. General Chemist Asst. Genl. Supt.

Asst.

Chief Engineer Superintendent Traveling Chemist Laboratory Parb P .. I00.000

2 .01

.01

2 .69

.65

1.96 .41

4.73 4:.97

17.49

1.19 18.6~

Silica Si08

Sodium Carbonate Na.C03

Calcium Sulphate

easo.

Organic and Volatile tby difference) TOT AL SOLIDS

P::,

e

74 _

192--9

Pu11 Per 100,000

5.2~

.lf

17.49 1.H

,

H,56

(10)

EA.IDN

_

factory

Campaign 1919

Kind of Water:

Pure Battery

Supply

Water

Descriptign of Sample:

Average

Sample

for the

Campaign

Source of Water:

Overflow from Press

Wash

water

tank, water from White Pan Condenser

and water from Evaporator Condensor.

J9l.;!

__

Sulphuric Acid

so.

Carbonic Acid C03

TOT AL SOLIDS

COPIES TO General Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

Parts Per 100.000 Parr. Per 100,000

7.50

Silica Si08

7.50 .17

2.52

8.45

Sodium Sulphate Na2SO,

12.66

2.09

5.09

1.53

10.35

16.94

12.76

Calciooi Chloride CaCI,

Calcium Sulphate

easo.

.17

20.96 .35

54.53

5.36

59.69

TOT AL SOLIDS

_59.89

Page

e.

(11)

EA.TON

_

factory

Kind of Water:

Impure Battery

Supply

Water

Average Sample for the Campaign

Source of Water:

Water from White Pan

(A)

Condensor

Brown

Pan

{B) Condensor

Brown Pan

(

C)

Condensor

Evaporator Condensor and overflow from Crystalizers.

Campaign 1919 _

Silica SiO, Iron Fe Calcium Ca Magnesium

Mg

Sodium Na Chlorine Cl Sulphuric Acid S04

Carbonic Acid

co.

COPIES TO

General Supt.

General Chemist Asst, Genl. Supt.

Asst. Chief Engineer Superintendent

Traveling Chemist

Laboratory

Patb Per 100,000

3.87

Silica Si02

I

_.17

12.03

2.50

3.49

1.94

Magnesium Sulphate

Mgso.

19.72

14.96

CalcilHll Chloride CaCl2

F errou~ Carbonate FeC03

58.68 2!70

Organic and Volatile {by difference)

65.38

TOT AL SOLIDS

Page 9.

t

_

192..9

_

Pam Per 100,000

3.87

3.20

6.89

12.38

7.34

24.65 .35

58.68

6.70

65.38

(12)

_

Factory

_.,~·---

_{Campaign 1919}

_{__}

_-~

_{192.Q_____}

Kind of Water: Description of Sample:

Water from

White

Pan Coils (Pig)

Average Sample for the Campaign

Source of Water:

Condensation from the

White

Pan

Coils.

Sulphuric Acid

so.

Carbonic Acid

co

.

Organic and Volatile (by difference) TOT AL SOLIDS COPIES TO Parr. Per 100,000

.76

.06

.39

.oa

.65

.10

.55

1.27

3.86

1 .60

5.46

HYPOTHETICAL COMBINATIONS Silica Si02

Sodium Sulphate Na2S04

Organic and Volatile tby difference) TOT AL SOLIDS Parts Per 100,000

.76

.16

.81

.76

.28

.97

.12

5.46

Genrral Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

Page

10.

/1

I

./2'c:

-

ACt1ngchief

Chem~

(13)

Factory

Crom.:a.ign 1919

Kind of Water:

Water from Boiler Feed Tank

Average

Sample

for the Campaign

Source of Water:

Includes water from steam chests of all effects of the Evaporators,

condensation from coils of White (a) and Brown (B) Pan,

City water and Ditch Water.

ANALYSIS _HYPOTHETICAL_{C0M13INATI0NS}

Paris Per I00,000

Sulphuric Acid

so.

Carbonic Acid

co.

Organic and Volatile (by difference} TOT AL SOLIDS COPIES TO

General Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

.67

.04

.16

.05

.22

.10

.19

.49

1.92

1.64

Silica Si02

Sodium Chloride NaCl Sodium Sulphate Na2S04

Calcium Chloride _'CaCl.,

_.

Organic and Volatile lby difference} TOT AL SOLIDS

Page 11.

_

192..o

~

Pam Per I 00,000

.67

.16

.28

.16

.17

.40

.os

1.92 1,64

3.56

/)

Acting.

-Chief C h e ~

(14)

EA.TON

Factory

Kind of Water:

Water

from

Boilers

Descriptic,n of Sample:

Average

Sample

fer

the

Campaign

Source of Water:

Water

from Boiler

Feed

Tank

Condensation from White Pan Coils.

Sulphuric Acid

so.

Carbonic Acid

co

.

TOT AL SOLIDS COPIES TO Parts Per I 00,000

1.66 .26

3.97 .21

10.02

11.83

62.37

36.64

206.98

30.38

237.36 Campaign 1919

HYPOTHETICAL COMl:lINATIONS Silica Si02

Ferrous Carbonate FeC:0₃

Organic and Volatile lby difference) TOT AL SOLIDS

Gen~ral Supt. General Chemist Asst. Genl. Supt. Asst. Chief Engineer Superintendent Traveling Chemist Laboratory

Page

12. __

192_o___

Parts Per I 00,000