63905Aquazol® 500 Material Safety Data Sheet

(1)

Identification of the Substance/Mixture and of the Company/Undertaking

1.

Product Identifier 1. 1.

Product Name: Aquazol® 500

Article No.: 63905

Relevant identified Uses of the Substance or Mixture and Uses advised against 1. 2.

Identified uses:

Glue

Binding agent Uses advised against:

Details of the Supplier of the Safety Data Sheet (Producer/Importer) 1. 3.

Company: Kremer Pigmente GmbH & Co. KG

Address: Hauptstr. 41-47, 88317 Aichstetten, Germany

Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606

Internet: www.kremer-pigmente.de

EMail: info@kremer-pigmente.de

Importer:

--Emergency No. 1. 4.

Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00)

Hazards Identification

2.

Classification of the Substance or Mixture 2. 1.

Classification according to EC Regulation 1272/2008

This product does not require classification and labelling as hazardous according to CLP/GHS.

Classification according to EC Regulation No. 67/548 or No. 1999/45

The material is not subject to classification according to EC lists. Safety Phrases:

Possible Environmental Effects: Label Elements

2. 2.

No classification required according to the CLP/GHS guidelines. Hazard designation:

Not applicable. Signal word:

Hazard designation: Safety designation:

Hazardous components for labelling: Other Hazards

2 next page:

(2)

2. 3.

Composition/Information on Ingredients

3.

Substance 3. 1. Mixture 3. 2.

Chemical Characterization: Water soluble synthetic resin. Poly (2-ethyl-2-oxazoline) Poly (2-ethyl-2-oxazoline), CAS No. 25805-17-8: 99.9 % 2-Ethyl-2-oxazoline, CAS No. 10431-98-8: < 0.1 % Hazardous Ingredients:

Additional information:

First Aid Measures

4.

Description of the First Aid Measures 4. 1.

General information:

Seek medical attention in case of complaints. After inhalation:

Supply fresh air and seek medical advice in case of complaints. Give artificial respiration in case breathing is not regular or if it has stopped.

After skin contact:

Wash with soap and rinse with plenty of water. After eye contact:

Rinse open eyes with plenty of water. In case of discomfort seek medical help.

After ingestion:

Rinse mouth with plenty of water (do not swallow) until no longer sticky.

If symptoms persist consult physician. Most important Symptoms and Effects, both Acute and Delayed

4. 2.

Symptoms:

No further information available. Effects:

Indication of any Immediate Medical Attention and special Treatment needed 4. 3.

Treatment:

No further information available.

Fire-Fighting Measures

5.

Extinguishing Media 5. 1.

Suitable extinguishing media:

Foam, carbon dioxide (CO2), extinguishing powder, water spray. Unsuitable extinguishing media:

Special Hazards arising from the Substance or Mixture 5. 2.

Special hazards:

When heated or in case of fire: formation of hazard fumes

3 next page:

(3)

possible. Advice for Firefighters

5. 3.

Protective equipment:

Wear self-contained respiratory protective device. Further information:

Accidential Release Measures

6.

Personal Precautions, Protective Equipment and Emergency Procedures 6. 1.

Personal precautions:

Ensure adequate ventilation. Wear protective clothing. Environmental Precautions

6. 2.

Environmental precautions:

No special measures required. Methods and Material for Containment and Cleaning Up

6. 3.

Methods and material:

Take up mechanically and collect in suitable containers for disposal.

Reference to other Sections 6. 4.

Handling and Storage

7.

Precautions for Safe Handling 7. 1.

Instructions on safe handling:

Wear adequate protective clothing (see para. 8). Avoid formation of dust.

Hygienic measures:

Keep away from foodstuffs and drinks.

Do not eat or drink during work. Do not smoke. Conditions for Safe Storage, including any Incompatibilities

7. 2.

Storage conditions:

Store in tightly sealed containers in a dry and cool room. Protect against humidity.

Requirements for storage areas and containers:

Store product in closed containers. Information on fire and explosion

protection:

Do not store together with: strong oxidants. Storage class (VCI):

Further Information: Specific End Use(s) 7. 3.

Further information:

4 next page:

(4)

Exposure Controls/Personal Protection

8.

Parameters to be Controlled 8. 1.

Parameters to be controlled (DE):

none known Parameters to be controlled (EC):

Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC):

Additional Information: Exposure Controls 8. 2.

Technical protective measures:

Provide adequate ventilation/exhaust system. Personal Protection

General protective measures:

Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Respiratory protection:

Dust mask recommended when very dusty (NIOSH-certified). Hand protection:

Protective gloves (EN 374) Protective glove material:

Eye protection:

Tightly fitting safety goggles (EN 166). Body protection:

Physical and Chemical Properties

9.

Information on Basic Physical and Chemical Properties 9. 1.

Form: solid

Color: bright yellow

Odor: none Odor threshold: No information available. pH-Value: neutral Melting temperature: not determined Boiling temperature: not applicable Flash point: 5 next page:

(5)

not applicable Evaporation rate:

not applicable Flammability (solid, gas):

not applicable Upper explosion limit:

no information available Lower explosion limit:

no information available Vapor pressure: not applicable Vapor density: No information available. Density: 1.14 g/cm3 (20°C)

Solubility in water: soluble

Coefficient of variation (n-Octanol/Water): not determined Auto-ignition temperature: > 400°C Decomposition temperature: > 300°C Viscosity, dynamic: not available Explosive properties: not applicable Oxidizing properties: No information available. Bulk density: Further Information 9. 2. Solubility in solvents: Viscosity, kinematic 67 mm2/s Burning class: Solvent content: Solid content: Particle size: Other information:

Stability and Reactivity

10.

Reactivity 10.1. No information available. 6 next page:

(6)

Chemical Stability 10.2.

Stable if used according to specifications. Possibility of Hazardous Reactions

10.3.

Hazardous polymerisation will not occur. Conditions to Avoid 10.4. Conditions to avoid: Avoid humidity. Thermal decomposition: > 300°C Imcompatible Materials 10.5.

Strong oxidizing agents. Hazardous Decomposition Products

10.6.

Carbon monoxide, cabon dioxide and nitrogen oxide. Further Information

10.7.

Toxicological Information

11.

Information on Toxicological Effects 11. 1. Acute Toxicity LD50, oral: 3980 mg/kg (rat) LD50, dermal: No information available. LC50, inhalation: No information available. Primary effects

Irritant effect on skin:

No information available Irritant effect on eyes:

No information available. Inhalation:

Ingestion:

No information available Sensitization:

No sensitizing effects known. Mutagenicity: No data available. Reproductive toxicity: No data available. Cancerogenity: No data available. Teratogenicity: No information available. 7 next page:

(7)

Specific target organ toxicity (STOT):

No data available. Additional toxicological information:

Ecological Information

12.

Aquatic Toxicity 12. 1. No information available. Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity:

Persistency and Degradability 12. 2. No information available. Bioaccumulation 12. 3. No information available. Mobility 12. 4. No data available. Results of PBT- und vPvP Assessment

12. 5.

No data available. Other Adverse Effects

12. 6.

Water hazard class:

Do not let run into surface waters, waste water or soil. Behaviour in sewage systems:

Further ecological effects:

No special effects or hazards known. AOX Value:

Disposal Considerations

13.

Waste Treatment Methods 13. 1.

Product:

Dispose of according to official national and local regulations. European Waste Code (EWC):

Uncleaned packaging:

Dispose of according to official local regulations. Waste Code No.:

Transport Information

14.

UN Number 14. 1.

ADR, IMDG, IATA UN Proper Shipping Name 14. 2.

ADR/RID:

No hazardous goods according to ADR (land transportation). 8 next page:

(8)

IMDG/IATA:

No hazardous goods according to IMDG. Transport Hazard Classes

14. 3. ADR Class: not applicable Hazard no.: Classification code: Tunnel no.:

IMDG Class (sea): Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: Packaging Group 14. 4. ADR/RID: not applicable IMDG: IATA: Environmental Hazards 14. 5. None Special Precautions for User

14. 6.

Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code

14. 7.

Further Information 14. 8.

Regulatory Information

15.

Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture 15. 1.

no information available Local regulations on chemical accidents:

Employment restrictions:

Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment

15. 2.

A Chemical Safety Assessment has not been carried out for this product.

Other Information

16.

This product should be stored, handled and used in accordance 9 next page:

(9)

with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be

(10)

Identification of the Substance/Mixture and of the Company/Undertaking

1.

Product Name: Paraloid™ B 72

Identified uses:

Coatings product Uses advised against:

Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606

Importer:

--Emergency No. 1. 4.

Hazards Identification

2.

Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS)

This product does not require classification and labelling as hazardous according to CLP/GHS.

Classification according to Directive No. 67/548/EC or No. 1999/45/EC

The material is not subject to classification according to EC lists. Safety Phrases:

Possible Environmental Effects: Label Elements

2. 2.

Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS)

This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Not applicable. Signal word: Hazard designation: Safety designation:

Hazardous components for labelling: Other Hazards

2 next page:

(11)

2. 3.

No special hazards known.

Composition/Information on Ingredients

3.

Substance 3. 1. Mixture 3. 2.

Chemical Characterization: Acrylic copolymer Information on Components / Hazardous

Ingredients:

This product does not contain any hazardous components according to EC Guidelines 67/548/EEC and 99/45/EC. Additional information:

First Aid Measures

4.

Take affected persons out into the fresh air. After inhalation:

Supply fresh air and keep patient calm. After skin contact:

Wash off with plenty of water and soap. Consult a physician if irritation persists.

After eye contact:

Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice.

After ingestion:

Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person.

Most important Symptoms and Effects, both Acute and Delayed 4. 2.

Symptoms:

No further information available. Effects:

No further information available. Indication of any Immediate Medical Attention and special Treatment needed 4. 3. Treatment: Treat symptomatically.

Fire-Fighting Measures

5.

CO2, extinguishing powder, water spray. Unsuitable extinguishing media:

None known.

3 next page:

(12)

Special Hazards arising from the Substance or Mixture 5. 2.

Special hazards:

Product is combustible, it burns vigorously with intense heat development.

Advice for Firefighters 5. 3.

Wear self-contained respiratory protective device and full protective gear.

Cool exposed containers with water spray. Do not inhale smoke.

Accidential Release Measures

6.

Provide adequate ventilation. Keep away from sources of ignition. Wear appropriate protective equipment. Keep spectators away. Floor may be slippery; use care to avoid falling.

Environmental Precautions 6. 2.

Keep spills and cleaning runoff out of municipal sewers and open bodies of water.

Methods and Material for Containment and Cleaning Up 6. 3.

Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal.

Reference to other Sections 6. 4.

Protective clothing, see Section 8.

See Section 13 for information on disposal.

Handling and Storage

7.

Avoid contact with eyes, skin and clothing. Wear adequate protective clothing (see para. 8). Hygienic measures:

Avoid contact with eyes and skin.

Do not inhale gas/fumes/vapours/aerosols. Wash hands with soap and water.

Conditions for Safe Storage, including any Incompatibilities 7. 2.

Store product in a cool, dry and well ventilated area. Keep container tightly closed

Requirements for storage areas and

4 next page:

(13)

containers:

Material is combustible. Indoor storage should be limited to restricted areas, which should be equipped with automatic sprinkling systems.

Information on fire and explosion protection:

Take measures to prevent static electricity discharge, earth/ground all equipment.

Storage class (VCI): Further Information:

Monomer vapors may be evolved when material is heated during processing operations.

Specific End Use(s) 7. 3.

Exposure Controls/Personal Protection

8.

Does not contain substances with occupational exposure limits. Parameters to be controlled (DE):

Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC):

Additional Information: Exposure Controls 8. 2.

Use appropriate local exhaust ventilation to control airborne levels. Facilities storing or utilizing this material should be equipped with an eyewash facility.

Personal Protection

General protective measures: Respiratory protection:

None required under normal operating conditions.

Respiratory protection with filter type N95 (corresp. to NIOSH resp. DIN standards) recommended for organic vapors. Filter types R95 or R96 recommended for oil mist.

Hand protection:

Gloves made of cotton. Protective glove material:

Eye protection:

Safety glasses with protective shields (EN 166). Body protection:

5 next page:

(14)

No special measures required.

Physical and Chemical Properties

9.

Information on Basic Physical and Chemical Properties 9. 1. Form: granules Color: clear Odor: acrylic Odor threshold: No information available. pH-Value: not applicable Melting temperature: not available Boiling temperature: not applicable Flash point: not applicable Evaporation rate: not applicable Flammability (solid, gas):

not available Upper explosion limit:

no information available Vapor pressure: not applicable Vapor density: No information available. Density: 0.66 g/cm3

Solubility in water: practically insoluble Coefficient of variation (n-Octanol/Water): no information available Auto-ignition temperature: 393°C Decomposition temperature: No data available. Viscosity, dynamic: not applicable Explosive properties:

(15)

Oxidizing properties: No information available. Bulk density: not applicable Further Information 9. 2. Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information:

Percent volatility: 1 % maximum

Stability and Reactivity

10.

Reactivity 10.1. No information available. Chemical Stability 10.2. None known. Possibility of Hazardous Reactions

10.3. Unknown. Conditions to Avoid 10.4. Conditions to avoid: No information available. Thermal decomposition: No data available. Imcompatible Materials 10.5. No information available. Hazardous Decomposition Products

10.6.

Thermal decomposition may yield acrylic monomers. Further Information

10.7.

Product does not polymerize.

Toxicological Information

11.

Information on Toxicological Effects 11. 1. Acute Toxicity LD50, oral: > 5000 mg/kg (rat) LD50, dermal: > 3000 mg/kg (rabbit) LC50, inhalation: No information available. Primary effects 7 next page:

(16)

Irritant effect on skin:

Slight irritant effect. Irritant effect on eyes:

Slight irritant effect Inhalation:

No information available. Ingestion:

No information available Sensitization:

No relevant data found. Mutagenicity:

No relevant data found. Reproductive toxicity:

No relevant data found. Carcinogenicity:

No relevant data found. Teratogenicity:

No information available. Specific target organ toxicity (STOT):

Repeated exposure: no information available. Single exposure: no information available. Additional toxicological information:

Aspiration hazard: not applicable

Ecological Information

12.

Aquatic Toxicity 12. 1. No information available. Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity:

Persistency and Degradability 12. 2. No information available. Bioaccumulation 12. 3. No information available. Mobility 12. 4. No information available. Results of PBT- und vPvP Assessment

12. 5.

On the basis of available data, the product does not contain and PBT or vPvB in percentage greater than 0.1 %.

Other Adverse Effects 12. 6.

8 next page:

(17)

1, slightly hazardous Behaviour in sewage systems:

Further ecological effects:

No ecological data available. AOX Value:

Disposal Considerations

13.

Product:

In accordance with current regulations, product may be taken to an incineration plant.

European Waste Code (EWC):

The waste code is determined according to the kind of waste and industry stated in the European Waste Catalogue.

Uncleaned packaging: Waste Code No.:

Transport Information

14.

UN Number 14. 1.

ADR/RID:

No hazardous goods according to ADR (land transportation). IMDG/IATA:

14. 3.

ADR Class:

not applicable Hazard no.:

Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group 14. 4. ADR/RID: not applicable IMDG: 9 next page:

(18)

IATA:

Environmental Hazards 14. 5.

Not classified as environmentally hazardous. Special Precautions for User

14. 6.

14. 7. not applicable Further Information 14. 8.

Regulatory Information

15.

1, slightly hazardous for water (German Regulation, self-assessment)

Local regulations on chemical accidents: Employment restrictions:

15. 2.

Exempted from the mandatory REACH Registration since this product is a polymer.

REACH: This mixture contains exclusively components which have been either pre-registered, are exempted from registration or must not be registered according to EC Regulation 1907/2006 (REACH).

Listed in the following inventories:

EINECS (EU), TSCA (US), AICS (AUS), DSL (CA), ENCS (JP), KECI (KR), PICCS (PH), IECSC (CN)

Other Information

16.

This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be

(19)

$961,771DPQHWSnlPQHWEODQGQLQJHQRFKERODJHWI|UHWDJHW

8WJLYQLQJVGDWXP

3URGXNWEHWHFNQLQJ

3URGXNWQDPQ $FHWRQ .HPLVNWQDPQ 3URSDQRQ 6\QRQ\PHU SURSDQRQ'LPHW\ONHWRQ 5($&+UHJQU &$6QU (*QU ,QGH[QU $UWLNHOQU

5HOHYDQWDLGHQWLILHUDGHDQYlQGQLQJDUDYlPQHWHOOHUEODQGQLQJHQRFK

DQYlQGQLQJDUVRPGHWDYUnGVIUnQ

$QYlQGQLQJVRPUnGH )|UWLOOYHUNQLQJDYIlUJRFKVRPO|VQLQJVPHGHO'HVLQIHNWLRQVPHGHO $QWLVHSWLVNWPHGHO$QWLIURVWYlWVND$OOPlQWUHQJ|ULQJVPHGHO

1lUPDUHXSSO\VQLQJDURPGHQVRPWLOOKDQGDKnOOHUVlNHUKHWVGDWDEODG

3URGXFHQW

)|UHWDJVQDPQ )UHG+ROPEHUJ &R$% %HV|NVDGUHVV *HLMHUVJDWDQ 3RVWDGUHVV %R[ 3RVWQU 6 3RVWRUW /LPKDPQ /DQG 6YHULJH 7HOHIRQ )D[ (SRVW LQIR#KROPEHUJVH :HEEDGUHVV KWWSZZZKROPEHUJVH

7HOHIRQQXPPHUI|UQ|GVLWXDWLRQHU

1|GWHOHIRQ $NXW%HJlU*LIWLQIRUPDWLRQVFHQWUDOHQ

$961,77)DUOLJDHJHQVNDSHU

.ODVVLILFHULQJDYlPQHWHOOHUEODQGQLQJHQ

.ODVVLILFHULQJHQOLJW((&HOOHU (& )5 ;L5 55 .ODVVLILFHULQJHQOLJW(&1R >&/3*+6@ )ODP/LT+ (\H,UULW+ 67276(+ (8+

0lUNQLQJVXSSJLIWHU

)DURSLNWRJUDP&/3

(20)

+2UVDNDUDOOYDUOLJ|JRQLUULWDWLRQ +.DQJ|UDDWWPDQEOLUGnVLJHOOHURPW|FNQDG (8+8SSUHSDGNRQWDNWNDQJHWRUUKXGHOOHUKXGVSULFNRU 6N\GGVDQJLYHOVHU 3)nULQWHXWVlWWDVI|UYlUPHJQLVWRU|SSHQOnJDKHWD\WRU±5|NQLQJ I|UEMXGHQ 3%HKnOODUHQVNDYDUDYlOWLOOVOXWHQ 39LGWDnWJlUGHUPRWVWDWLVNHOHNWULFLWHW 3$QYlQGVN\GGVKDQGVNDUVN\GGVNOlGHU|JRQVN\GGDQVLNWVVN\GG 3339,'+8'.217$.7lYHQKnUHW7DRPHGHOEDUWDYDOOD QHGVWlQNWDNOlGHU6N|OMKXGHQPHGYDWWHQGXVFKD 3339,'.217$.70('g*21(16N|OMI|UVLNWLJWPHG YDWWHQLIOHUDPLQXWHU7DXUHYHQWXHOODNRQWDNWOLQVHURPGHWJnUOlWW)RUWVlWW DWWVN|OMD 33)|UYDUDVSnYlOYHQWLOHUDGSODWV)|UYDUDVVYDOW .RPSOHWWHUDQGHPlUNQLQJ (8+8SSUHSDGNRQWDNWNDQJHWRUUKXGHOOHUKXGVSULFNRU

$QGUDIDURU

$QGUDIDURU ,QWHNlQW

$961,776DPPDQVlWWQLQJLQIRUPDWLRQRPEHVWnQGVGHODU

bPQHQ

bPQH ,GHQWLILHULQJ .ODVVLILFHULQJ ,QQHKnOO

$FHWRQ &$6QU (*QU ,QGH[QU 5HJLVWUHULQJVQXPPHU )5 ;L5 55 )ODP/LT+ (\H,UULW+ 67276(+ (8+

.ROXPQUXEULNHU &$6QU &KHPLFDO$EVWUDFWV6HUYLFH(*(LQHFVHOOHU(OLQFVQXPPHU (XURSHDQLQYHQWRU\RI([LVWLQJ&RPPHUFLDO&KHPLFDO6XEVWDQFHVbPQH 1DPQHQOLJWlPQHVOLVWDlPQHQVRPLQWHVWnULlPQHVOLVWDQPnVWH|YHUVlWWDV RPGHWJnU,QQHKnOODQJLYHWLYNWYNWYROYNWYROYROPJPSSE SSPYLNWYRO

)+)%)0 7 0\FNHWJLIWLJ7 *LIWLJ& )UlWDQGH;Q +lOVRVNDGOLJ;L ,UULWHUDQGH( ([SORVLYW2 2[LGHUDQGH) ([WUHPWEUDQGIDUOLJW) 0\FNHWEUDQGIDUOLJW1 0LOM|IDUOLJ

$961,77cWJlUGHUYLGI|UVWDKMlOSHQ

%HVNULYQLQJDYnWJlUGHUYLGI|UVWDKMlOSHQ

,QDQGQLQJ )O\WWDJHQDVWGHQVNDGDGHWLOOIULVNOXIW.RQWDNWDOlNDUHRPEHVYlUNYDUVWnU +XGNRQWDNW 7DJDYQHGVWlQNWDNOlGHURFKWYlWWDKXGHQQRJJUDQWPHGYDWWHQ gJRQNRQWDNW 6N|OMJHQDVWPHGULNOLJDPlQJGHUYDWWHQLXSSWLOOPLQ$YOlJVQDHYHQWXHOOD NRQWDNWOLQVHURFKKnOO|JDWYLG|SSHW.RQWDNWDOlNDUHRPEHVYlUNYDUVWnU )|UWlULQJ )|UV|NLQWHJHYlWVNDHOOHUIUDPNDOODNUlNQLQJRPGHQVNDGDGHlUPHGYHWVO|V )UDPNDOODLQWHNUlNQLQJ6N|OMPXQPHGYDWWHQ.RQWDNWDOlNDUHRPEHVYlU NYDUVWnU

'HYLNWLJDVWHV\PSWRPHQRFKHIIHNWHUQDEnGHDNXWDRFKI|UGU|MGD

,QIRUPDWLRQWLOOKlOVRYnUGVSHUVRQDO %HKDQGODV\PSWRPDWLVNW*HLQWHQnJRWDWWGULFNDYLGPHGYHWVO|VKHW

(21)

6OlFNPHGHO

/lPSOLJDVOlFNPHGHO 9LGEUDQGVOlFNQLQJDQYlQGDONRKROUHVLVWHQWVNXPNROV\UDSXOYHUHOOHU YDWWHQGLPPD

6lUVNLOGDIDURUVRPlPQHWHOOHUEODQGQLQJHQNDQPHGI|UD

%UDQGRFKH[SORVLRQVULVNHU 0<&.(7%5$1')$5/,*7cQJRUQDNDQELOGDH[SORVLYDEODQGQLQJDUPHGOXIW )DUOLJDI|UEUlQQLQJVSURGXNWHU 9LGEUDQGELOGDV.ROPRQR[LG&2.ROGLR[LG&2

5nGWLOOEUDQGEHNlPSQLQJVSHUVRQDO

%UDQGVOlFNQLQJVPHWRGHU ,QJHQVlUVNLOGEUDQGEHNlPSQLQJVPHWRGDQJLYHQ

$961,77cWJlUGHUYLGRDYVLNWOLJDXWVOlSS

3HUVRQOLJDVN\GGVnWJlUGHUVN\GGVXWUXVWQLQJRFKnWJlUGHUYLGQ|GVLWXDWLRQHU

3HUVRQOLJDVN\GGVnWJlUGHU $QYlQGOlPSOLJSHUVRQOLJVN\GGVXWUXVWQLQJLQNODQGQLQJVVN\GGYLG DYOlJVQDQGHDYVSLOOLEHJUlQVDWXWU\PPH6|UMI|UJRGYHQWLODWLRQ6WRSSD OlFNDRPGHWlUP|MOLJWXWDQULVN8QGYLNNRQWDNWPHGKXGRFK|JRQ8QGYLN LQDQGQLQJDYnQJRU$QJnHQGHSHUVRQOLJVN\GGVXWUXVWQLQJVHSXQNW

0LOM|VN\GGVnWJlUGHU

0LOM|VN\GGVnWJlUGHU 8QGYLNXWVOlSSLDYORSSSnPDUNHQRFKLYDWWHQPLOM|

0HWRGHURFKPDWHULDOI|ULQQHVOXWQLQJRFKVDQHULQJ

5HQJ|ULQJVPHWRG 9DOODLQRFKVXJXSSVSLOOPHGVDQGMRUGHOOHUDQQDWLFNHEUlQQEDUW PDWHULDO6SLOOVDPODVXSSLWlWDEHKnOODUHRFKOlPQDVI|UGHVWUXNWLRQHQOLJW JlOODQGHORNDODI|UHVNULIWHU

+lQYLVQLQJWLOODQGUDDYVQLWW

$QGUDDQYLVQLQJDU ,QIRUPDWLRQRPH[SRQHULQJSHUVRQOLJWVN\GGRFKDYIDOOVKDQWHULQJILQQVL DYVQLWWRFK,QIRUPDWLRQUHJDUGLQJH[SRVXUHSHUVRQDOSURWHFWLRQDQG GLVSRVDOVHHVHFWLRQDQG

$961,77+DQWHULQJRFKODJULQJ

)|UVLNWLJKHWVPnWWI|UVlNHUKDQWHULQJ

+DQWHULQJ 6N\GGDVIUnQYlUPHJQLVWRURFK|SSHQHOG9LGWDJnWJlUGHUPRWVWDWLVN HOHNWULFLWHW0HNDQLVNYHQWLODWLRQNDQYDUDQ|GYlQGLJ

6N\GGVnWJlUGHU

5nGRPDOOPlQDUEHWVK\JLHQ 5LNOLJDPlQJGHUYDWWHQRFK|JRQVSROIODVNDVNDOOYDUDOlWWWLOOJlQJOLJD

)|UKnOODQGHQI|UVlNHUODJULQJLQNOXVLYHHYHQWXHOORI|UHQOLJKHW

/DJULQJ 6N\GGDVIUnQYlUPHJQLVWRURFK|SSHQHOG%HKnOODUHRFKNRSSOLQJDUVNDOO MRUGDVI|UDWWXQGYLNDJQLVWRUDYVWDWLVNHOHNWULFLWHW)|UYDUDVVYDOWSnYlO YHQWLOHUDGSODWV

6SHFLILNVOXWDQYlQGQLQJ

6SHFLILNDDQYlQGQLQJVRPUnGHQ (MDQJLYHW

$961,77%HJUlQVQLQJDYH[SRQHULQJHQSHUVRQOLJWVN\GG

.RQWUROOSDUDPHWUDU

gYULJLQIRUPDWLRQRPJUlQVYlUGHQ 1RUVNHJUHQVHYHUGLHU)25YHGOHJJ $FHWRQWSSPPJP (XURSH,2(/97:$/LPLWYDOXHPJPSSP *UHDW%ULWDLQ:(/7:$/LPLWYDOXHPJPSSP

(22)

([SRQHULQJIUHNYHQV.RUWVLNWLJDNXW 7\SDYHIIHNW/RNDOHIIHNW 9lUGHPJP '1(/ *UXSS.RQVXPHQW ([SRQHULQJVYlJ,QDQGQLQJ ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 7\SDYHIIHNW6\VWHPLVNHIIHNW 9lUGHPJP '1(/ *UXSS.RQVXPHQW ([SRQHULQJVYlJ'HUPDO ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 7\SDYHIIHNW6\VWHPLVNHIIHNW 9lUGHPJP '1(/ *UXSS$UEHWDUH ([SRQHULQJVYlJ'HUPDO ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 7\SDYHIIHNW6\VWHPLVNHIIHNW 9lUGHPJNJ '1(/ *UXSS$UEHWDUH ([SRQHULQJVYlJ,QDQGQLQJ ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 7\SDYHIIHNW6\VWHPLVNHIIHNW 9lUGHPJP '1(/ *UXSS.RQVXPHQW ([SRQHULQJVYlJ2UDO ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 7\SDYHIIHNW6\VWHPLVNHIIHNW 9lUGHPJP 31(& ([SRQHULQJVYlJ6HGLPHQW 9lUGHPJNJGZW .RPPHQWDUIUHVKZDWHU 31(& ([SRQHULQJVYlJ6HGLPHQW 9lUGHPJNJGZW .RPPHQWDUPDULQHZDWHU 31(& ([SRQHULQJVYlJ-RUG 9lUGHPJNJGZW 31(& ([SRQHULQJVYlJ9DWWHQ 9lUGHPJO .RPPHQWDUPDULQHZDWHU 31(& ([SRQHULQJVYlJ9DWWHQ 9lUGHPJO .RPPHQWDUIUHVKZDWHU 31(& ([SRQHULQJVYlJ9DWWHQ ([SRQHULQJIUHNYHQV/nQJVLNWXSSUHSDG 9lUGHPJO 31(& ([SRQHULQJVYlJ5HQLQJVDQOlJJQLQJ 9lUGHPJO .RPPHQWDUYl[WSODQW 5LNWOLQMHUI|UH[SRQHULQJ 8UVSUXQJVODQG6YHULJH *UlQVYlUGHW\S.79 .RUWWLGVYlUGH.79YlUGHPJP

(23)

UHNRPPHQGHUDV'HWVNDOOILQQDVWLOOJnQJWLOOVQDEERFKULNOLJ|JRQVSROQLQJL DQVOXWQLQJWLOODUEHWVSODWVHQ

6lNHUKHWVVN\OWDU

$QGQLQJVVN\GG

$QGQLQJVVN\GG $QGQLQJVVN\GGVNDOODQYlQGDVQlUOXIWI|URUHQLQJHQ|YHUVWLJHUK\JLHQLVND JUlQVYlUGHW$QYlQGDQGQLQJVVN\GGPHGJDVILOWHUW\S$;

+DQGVN\GG

+DQGVN\GG $QYlQGVN\GGVKDQGVNDU.HPLNDOLHUHVLVWHQWDKDQGVNDUVNDOODQYlQGDVYLG OnQJYDULJHOOHUXSSUHSDGNRQWDNW+DQGVNDUDYQLWULOJXPPL39$HOOHU9LWRQ UHNRPPHQGHUDV

gJRQDQVLNWVVN\GG

gJRQVN\GG $QYlQGVN\GGVJODV|JRQHOOHUDQVLNWVVNlUPYLGULVNI|UVWlQN

+XGVN\GG

+XGVN\GGDYDQQDWlQKlQGHUQD 9LGULVNI|UKXGNRQWDNWVNDOOOlPSOLJDVN\GGVNOlGHUDQYlQGDV

+\JLHQ0LOM|

6lUVNLOGDK\JLHQLVNDnWJlUGHU 7YlWWDKlQGHUQDHIWHUNRQWDNW

$961,77)\VLNDOLVNDRFKNHPLVNDHJHQVNDSHU

,QIRUPDWLRQRPJUXQGOlJJDQGHI\VLNDOLVNDRFKNHPLVNDHJHQVNDSHU

)lUJ )lUJO|VW /XNW $ONRKROOXNW /XNWJUlQV 9lUGHSSP .RPPHQWDUHUS+OHYHUDQV ,QWHUHOHYDQW 6PlOWSXQNWVPlOWSXQNWVLQWHUYDOO 9lUGH& .RNSXQNWNRNSXQNWVLQWHUYDOO 9lUGH& )ODPSXQNW 9lUGH& ([SORVLRQVJUlQV 9lUGH cQJWU\FN 9lUGHN3D 7HVWWHPSHUDWXU& cQJGHQVLWHW 9lUGH 5HODWLYGHQVLWHW 9lUGHNJP 7HVWWHPSHUDWXU& %HVNULYQLQJDYO|VQLQJVI|UPnJD )XOOVWlQGLJWO|VOLJWLYDWWHQ/|VOLJWL2UJDQLVNDO|VQLQJVPHGHO )|UGHOQLQJVNRHIILFLHQWQ RNWDQROYDWWHQ 9lUGH 7HUPLVNWlQGWHPSHUDWXU 9lUGH& 9LVNRVLWHW 9lUGHP3DV 7HVWWHPSHUDWXU&

$QQDQLQIRUPDWLRQ

$961,776WDELOLWHWRFKUHDNWLYLWHW

5HDNWLYLWHW

(24)

)|UKnOODQGHQVRPVNDXQGYLNDV

)|UKnOODQGHQVRPVNDOOXQGYLNDV 8QGYLNYlUPHIODPPRURFKDQGUDDQWlQGQLQJVNlOORU

2I|UHQOLJDPDWHULDO

0DWHULDOVRPVNDOOXQGYLNDV 8QGYLNNRQWDNWPHGR[LGDWLRQVPHGHOWH[VDOSHWHUV\UDSHUR[LGHUNURPDW 6WDUNDV\URU

)DUOLJDV|QGHUGHOQLQJVSURGXNWHU

)DUOLJDV|QGHUGHOQLQJVSURGXNWHU 9LGEUDQGELOGDV.ROPRQR[LG&2.ROGLR[LG&2

$961,777R[LNRORJLVNLQIRUPDWLRQ

,QIRUPDWLRQRPGHWR[LNRORJLVNDHIIHNWHUQD

7R[LNRORJLVNLQIRUPDWLRQ

$QGUDWR[LNRORJLVNDGDWD $NXW7R[LFLWHW2UDO/'PJNJRUDOUnWWD $NXW7R[LFLWHW,QKDODWLRQ/&PJOnQJRUK $NXW7R[LFLWHW'HUPDO/'PJNJLSUnWWD!

3RWHQWLHOODDNXWDHIIHNWHU

,QDQGQLQJ ,K|JDNRQFHQWUDWLRQHUYHUNDUnQJRUQDI|UVO|DQGHRFKNDQJHKXYXGYlUN WU|WWKHW\UVHORFKLOODPnHQGH,FNHNODVVLILFHUDGVRPDVSLUDWLRQVWR[LVN1RW FODVVLILHGDVDVSWR[ +XGNRQWDNW /nQJYDULJHOOHUXSSUHSDGNRQWDNWNDQJHURGQDGNOnGDRFK HNVHPVSULFNELOGQLQJ$YIHWWDUKXGHQ gJRQNRQWDNW 2UVDNDUDOOYDUOLJ|JRQLUULWDWLRQ )|UWlULQJ )|UWlULQJDYVW|UUHPlQJGHUNDQOHGDWLOOPHGYHWVO|VKHW)|UWlULQJNDQGRFN RUVDNDLOODPnHQGHKXYXGYlUN\UVHORFKEHUXVQLQJ)|UWlULQJNDQRUVDND LUULWDWLRQDYPDJHWDUPNDQDONUlNQLQJDURFKGLDUUp.DQRUVDNDLUULWDWLRQLPXQ RFKVYDOJ

)|UGU|MGDHIIHNWHUXSSUHSDGH[SRQHULQJ

6HQVLELOLVHULQJ ,QWHNlQW .URQLVNDHIIHNWHU ,QJDNlQGD

&DQFHURJHQ0XWDJHQRFK5HSURGXNWLRQVWR[LVN

&DQFHUIUDPNDOODQGH ,QJHQ bUIWOLJKHWVVNDGRU ,QWHNlQW (JHQVNDSHUVNDGOLJDI|UIRVWUHW ,QWHNlQW 5HSURGXNWLRQVWR[LFLWHW ,QWHNlQW

$961,77(NRORJLVNLQIRUPDWLRQ

7R[LFLWHW

$NXWYDWWHQOHYDQGHILVN 9lUGHPJO 7HVWPHWRG/& )LVNDUWHU2QFRUK\QFKXVP\NLVV 9DUDNWLJKHWK $NXWYDWWHQOHYDQGHDOJ 9lUGH!PJO 7HVWPHWRG,& $OJDUW0LFURF\VWLVDHUXJLQRVD 9DUDNWLJKHWG $NXWYDWWHQOHYDQGH'DSKQLD 9lUGHPJO 7HVWPHWRG(& 'DSKQLDDUW'PDJQD

(25)

%LRORJLVNV\UHI|UEUXNQLQJ%2' 9lUGH 7HVWPHWRG%2'

%LRDFNXPXOHULQJVI|UPnJD

%LRDFNXPXOHULQJVI|UPnJD %LRDFNXPXOHUDULQWH %LRNRQFHQWUDWLRQVIDNWRU%&) 9lUGH 7HVWPHWRG%&)

5|UOLJKHWHQLMRUG

5|UOLJKHW 3URGXNWHQlUYDWWHQO|VOLJRFKNDQVSULGDVLYDWWHQPLOM|Q

5HVXOWDWDY3%7RFKY3Y%EHG|PQLQJHQ

3%7EHG|PQLQJUHVXOWDW bPQHWNODVVLILFHUDVLQWHVRP3%7HOOHUY3Y%

$QGUDVNDGOLJDHIIHNWHU

$QGUDVNDGOLJDHIIHNWHU $QPlUNQLQJ ,QJDNlQGD

$961,77$YIDOOVKDQWHULQJ

$YIDOOVEHKDQGOLQJVPHWRGHU

$961,777UDQVSRUWLQIRUPDWLRQ

81QXPPHU

$'5 5,' ,0'* ,&$2,$7$

2IILFLHOOWUDQVSRUWEHQlPQLQJ

$'5 $&(721 5,' $&(721 ,0'* $&(721( ,&$2,$7$ $&(721(

)DURNODVVI|UWUDQVSRUW

$'5 )DUOLJKHWVQXPPHU 5,' $'1 ,0'* ,&$2,$7$

)|USDFNQLQJVJUXSS

$'5 ,, 5,' ,, ,0'* ,,

(26)

%XONWUDQVSRUWHQOLJWELODJD,,WLOO0$532/RFK,%&NRGHQ

**$961,77*lOODQGHI|UHVNULIWHU**

(*QU

)|UHVNULIWHUODJVWLIWQLQJRPlPQHWHOOHUEODQGQLQJHQQlUGHWJlOOHUVlNHUKHW

KlOVDRFKPLOM|

$QGUDDQPlUNQLQJDU (XURSDSDUODPHQWHWVRFKUnGHWVI|URUGQLQJ(*QUDYGHQ GHFHPEHURPNODVVLILFHULQJPlUNQLQJRFKI|USDFNQLQJDYlPQHQRFK EODQGQLQJDUlQGULQJRFKXSSKlYDQGHDYGLUHNWLYHQ((*RFK (*VDPWlQGULQJDYI|URUGQLQJ(*QUPHGlQGULQJDU /DJDURFKI|URUGQLQJDU bPQHVGLUHNWLYHW((* .HPLNDOLHLQVSHNWLRQHQVI|UHVNULIWHURPNODVVLILFHULQJRFKPlUNQLQJDYNHPLVND SURGXNWHU.,)6PHGlQGULQJDURFK.HPLNDOLHLQVSHNWLRQHQVI|UHVNULIWHU .,)6RPNHPLVNDSURGXNWHURFKELRWHNQLVNDRUJDQLVPHUPHG lQGULQJDU $YIDOOVI|URUGQLQJPHGlQGULQJDU$YIDOOVI|URUGQLQJHQ

.HPLNDOLHVlNHUKHWVEHG|PQLQJ

$961,77$QQDQLQIRUPDWLRQ

)DURV\PERO

(27)

(28)

Identification of the Substance/Mixture and of the Company/Undertaking

1.

Product Name: BEVA® Artist Gesso-p

Identified uses:

Restoration purposes Uses advised against:

Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606

Importer:

--Emergency No. 1. 4.

Hazards Identification

2.

Flammable solids, hazard category 2 Skin irritation, category 2

Specific target organ toxicity (repeated exposure), category 2 Hazardous to the aquatic environment, acute category 2 Flammable solid.

H228 Cat.: 2

Causes skin irritation. H315

Cat.: 2

May cause damage to organs through prolonged or repeated exposure.

H373 Cat.: 2

Toxic to aquatic life. H401

Cat.: Classification according to EC Regulation No. 67/548 or No. 1999/45 Safety Phrases:

Possible Environmental Effects: Label Elements 2. 2. Classification according to EC Regulation 1272/2008 Hazard designation: 2 next page:

(29)

GHS02-1 GHS07 GHS08 Signal word: Warning Hazard designation: H228 Flammable solid.

H315 Causes skin irritation.

H373 May cause damage to organs through prolonged or repeated exposure.

H401 Toxic to aquatic life.

Safety designation:

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking.

P302+P352 If on skin: Wash with soap and water.

P308+P313 If exposed or concerned: Get medical advice/attention. P403+P235 Store in a well ventilated place. Keep cool.

Hazardous components for labelling: Other Hazards 2. 3.

Composition/Information on Ingredients

3.

Substance 3. 1. Mixture 3. 2. Chemical Characterization:

Hydrogenated hydrocarbon resins, ethylene vinyl acetate resins and chemically stable minerals.

Hydrogenated hydrocarbon resins and ethylene vinyl acetate resins: 24 % Hazardous Ingredients: CAS-Nr: 8032-32-4 EINECS-Nr: 232-453-7 EC-Nr: 40 - 46 % Aliphatic hydrocarbon solvent

(H225-304-315-361-336-373-411)

Additional information:

First Aid Measures

4.

Take affected persons out into the fresh air.

3 next page:

(30)

After inhalation:

Supply fresh air and seek medical advice in case of complaints. After skin contact:

Wash off immediately with soap and plenty of water. After eye contact:

Rinse open eyes with plenty of water for at least 15 minutes. After ingestion:

Do NOT induce vomiting. Consult a doctor. Most important Symptoms and Effects, both Acute and Delayed

4. 2.

Symptoms:

Irritates eyes, skin and respiratory system. Impairment of the central nervous system. Effects:

Indication of any Immediate Medical Attention and special Treatment needed 4. 3. Treatment: Treat symptomatically.

Fire-Fighting Measures

5.

Foam, carbon dioxide (CO2), extinguishing powder, water. Unsuitable extinguishing media:

None known. Special Hazards arising from the Substance or Mixture 5. 2.

Special hazards:

Product is combustible at high temperatures.

The vapor is heavier than air, spreads along the ground and distant ignition is possible.

Advice for Firefighters 5. 3.

Wear self-contained respiratory protective device and full protective gear.

Cool exposed containers with water spray.

Accidential Release Measures

6.

Keep away from sources of heat and ignition. Avoid contact with skin.

Environmental Precautions 6. 2.

(31)

Prevent contamination of soil, drains and surface waters. Methods and Material for Containment and Cleaning Up

6. 3.

Take up mechanically. Reference to other Sections

6. 4.

Protective clothing, see Section 8.

Handling and Storage

7.

Provide adequate ventilation. Hygienic measures:

Avoid contact with skin, eyes and clothing. Keep away from foodstuffs and drinks.

Wash hands at the end of work. Preventive skin protection recommended.

Conditions for Safe Storage, including any Incompatibilities 7. 2.

Store in tightly sealed containers in a dry and cool room. Keep away from ignitable sources, heat and fire.

Accesible for authorized persons only. Requirements for storage areas and

containers:

Storage: In the original container. Information on fire and explosion

protection:

Do not store together with ignitable and heat sources. Do not store together with: oxidants.

Flammability class: 1B Storage class (VCI):

Further Information: Specific End Use(s) 7. 3.

Exposure Controls/Personal Protection

8.

None known Parameters to be controlled (DE):

Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC):

Additional Information:

5 next page:

(32)

Exposure Controls 8. 2.

Provide adequate ventilation/exhaust system. Personal Protection

General protective measures:

Wear adequate protective clothing.

Keep away from foodstuffs, beverages and feed. Avoid contact with skin, eyes and clothing. Respiratory protection:

Recommended. Hand protection:

Protective gloves (EN 374) Protective glove material:

Eye protection:

Tightly fitting safety goggles (EN 166). Body protection:

Protective clothing. Environmental precautions:

Prevent from getting into the soil, surface water and sewage system.

Physical and Chemical Properties

9.

Information on Basic Physical and Chemical Properties 9. 1. Form: paste Color: white Odor: characteristic Odor threshold: 2 - 5 ppm pH-Value: not available Melting temperature: Boiling temperature: 150°C Flash point: 65°C Evaporation rate: No information available. Flammability (solid, gas):

Flammable solid Upper explosion limit:

no information available

6 next page:

(33)

Vapor pressure: 10 mm Hg (20°C) Vapor density:

No information available. Density:

not available

Solubility in water: insoluble

Coefficient of variation (n-Octanol/Water): no information available Auto-ignition temperature: No information available. Decomposition temperature: No data available. Viscosity, dynamic: not determined Explosive properties: not applicable Oxidizing properties: no information available Bulk density: Further Information 9. 2. Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information:

Stability and Reactivity

10.

Reactivity 10.1.

Stable if used according to specifications. Chemical Stability

10.2.

Stable if used according to specifications. Possibility of Hazardous Reactions

10.3.

Unknown. Conditions to Avoid

10.4.

Conditions to avoid:

Avoid heat and sources of ignition.

Dangerous fire hazard when exposed to heat, flamme or oxidizers.

(34)

Imcompatible Materials 10.5.

No information available. Hazardous Decomposition Products

10.6.

None if stored and handled according to specifications. Further Information

10.7.

Toxicological Information

11.

Information on Toxicological Effects 11. 1. Acute Toxicity No information available. LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin:

Continuous contact can cause irritation. Irritant effect on eyes:

May irritate eyes. Inhalation:

Can cause irritation of the respiratory system. Ingestion:

Can cause irritation of the mucous membrane. Sensitization:

May cause sensitization by skin contact. Mutagenicity: No data available. Reproductive toxicity: No data available. Cancerogenity: No data available. Teratogenicity: No information available. Specific target organ toxicity (STOT):

No data available. Additional toxicological information:

Ecological Information

12.

Aquatic Toxicity 12. 1. No information available. Fish toxicity: Daphnia toxicity: 8 next page:

(35)

Bacteria toxicity: Algae toxicity:

Persistency and Degradability 12. 2. No information available. Bioaccumulation 12. 3. No information available. Mobility 12. 4. No information available. Results of PBT- und vPvP Assessment

12. 5.

No data available. Other Adverse Effects

12. 6.

1, slightly hazardous. Behaviour in sewage systems:

Further ecological effects: AOX Value:

Disposal Considerations

13.

Product:

If possible reuse product. European Waste Code (EWC):

Uncleaned packaging:

Dispose of according to official local regulations. Waste Code No.:

Transport Information

14.

UN Number 14. 1.

ADR/RID:

No hazardous goods according to ADR (land transportation). IMDG/IATA:

14. 3. ADR Class: not applicable Hazard no.: Classification code: Tunnel no.:

IMDG Class (sea):

9 next page:

(36)

Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: Packaging Group 14. 4. ADR/RID: not applicable IMDG: IATA: Environmental Hazards 14. 5.

Special Precautions for User 14. 6.

14. 7. not applicable Further Information 14. 8.

Regulatory Information

15.

1, slightly hazardous for water (self-assessment) Local regulations on chemical accidents:

Employment restrictions:

15. 2.

A Chemical Safety Assessment has not been carried out for this product.

Other Information

16.

This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be

(37)

_________________________________________________________________________________________ Page 1 of 3

COMPANY/UNDERTAKING

Product Information:

Product Name:

Glass Bubbles, 150 - 210

µ Article No.:

59831

Application:

Artists’ and Restoration Material

Company:

Kremer Pigmente GmbH & Co. KG

Hauptstrasse 41-47, D - 88317 Aichstetten

Tel. +49 7565 914480 Fax. +49 7565 1606

www.kremer-pigmente.de, kremer-pigmente@t-online.de

2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Characterization:

SiO

2

72.5 %

NaO

13.7 %

CaO

9.8 %

MgO

3.3 %

Al

2

O

3

0.4 %

FeO/Fe

2

O

3

0.2 %

K

2

O

0.1 %

CAS-No.:

65997-17-3

EINECS-No.:

266-046-0

3. HAZARD IDENTIFICATION

Can cause irritation of eyes and respiratory system when the MAC (maximum workplace

concentration) value is exceeded.

4. FIRST AID MEASURES

General information:

No special measures required.

After inhalation:

Supply fresh air.

After skin contact:

Wash off with soap and water.

After eye contact:

Rinse open eye for several minutes under running water

After ingestion:

No hazards known.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media: Use fire fighting measures that suit the environment.

Protective equipment:

No special measures required.

(38)

_________________________________________________________________________________________ Page 2 of 3

Person-related safety measures: Avoid causing dust. Wear protective clothing.

Measures for environmental

protection:

No special measures required.

Methods of cleaning/adsorption: Collect mechanically and if possible reuse material. Avoid

causing dust when cleaning.

7. HANDLING AND STORAGE

Handling

Instructions on safe handling:

Prevent formation of dust. Increased risk of falling due to

spilled material.

Storage

Requirements for storage areas

and containers:

Keep bags and containers tightly closed. Store dry.

Storage group:

10-13

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Additional information about design of technical systems:

No further data.

Components with critical values that require monitoring at the workplace:

Max. dust level: 5 mg/m

3

(no free SiO

2

, all components are amorphe/not crystalline).

Personal protective equipment:

General protective measures:

Do not inhale dust. Avoid contact with eyes.

Hygiene measures:

Do not eat, drink or smoke while working. Wash hands

be-fore breaks and after work.

Respiratory protection:

Dust mask.

Eye protection:

Tightly sealed safety glasses.

Hand protection:

Not required.

Body protection:

Protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form:

solid

Color:

crystal clear

Odor:

odorless

Changes in physical state:

Softening point:

approx. 730°C

Inflammability (solid, gaseous): product is not inflammable

Danger of explosion:

none

Density:

approx. 2.6 g/cm

3

(20°C)

Solubility in water:

Insoluble in standard solvents.

(39)

_________________________________________________________________________________________ Page 3 of 3

10. STABILITY AND REACTIVITY

General information:

product is stable

11. TOXICOLOGICAL INFORMATION

Product can cause irritating effects on eyes and respiratory system at dust levels above the

maximum recommended limits.

12. ECOLOGICAL INFORMATION

Generally not hazardous for water. At present there are no ecotoxicological assessments.

13. DISPOSAL CONSIDERATIONS

Product:

If possible reuse product residues.

Uncleaned packaging:

Not contaminated packaging can be used again.

Cleaning agent: water.

14. TRANSPORT INFORMATION

Non-hazardous according to ADR/GGVS, RID/GGVE, ICAO/IATA, IMDG.

15. REGULATORY INFORMATION

Designation according to EC guidelines:

The material is not subject to classification

ac-cording to EC lists.

National Regulations (D):

Occupational regulation:

none

16. OTHER INFORMATION

This product should be stored, handled and used in accordance with good hygiene practices

and in conformity with any legal regulations. This information contained herein is based on

the present state of knowledge and is intended to describe our product from the point of view

of safety requirements. It should therefore not be construed as guaranteeing specific

proper-ties.

(40)

SÄKERHETSDATABLAD

DAS White and Terracotta

1. NAMNET PÅ BEREDNINGEN OCH FÖRETAGET

Handelsnamn:

DAS White and Terracotta

Användning:

Lufthärdande modellera

Distributör

FILA S.p.A., Italien

Svensk distributör:

LYRA SCANDINAVIA AB

Bilgatan 7 C

442 40 Kungälv

Nödtelefon:

112 Upplysningar om produkten:

0303-727460

E-post:

info@lyra.se

2. FARLIGA EGENSKAPER

Hälsofarliga egenskaper:

-

Fysikaliska/kemiska risker: -

Miljömässiga risker:

-

3. SAMMANSÄTTNING/INFORMATION OM BESTÅNDSDELAR

CAS-Nr: Ämne: Vikt-%: Symboler: R-fraser:

Vatten - -

Oorganiskt fyllnadsmaterial - -

Vegetabiliskt bindemedel - -

4. FÖRSTA HJÄLPEN

Inga olycksfall vid användning av produkten har noterats. Följande åtgärder kan sättas in om så krävs:

Inandning:

Osannolikt.

Hudkontakt:

Tvätta omedelbart med rikliga mängder vatten.

Stänk i ögonen:

Tag av ev. kontaktlinser. Håll ögonlocken brett isär och rulla med

ögonen. Skölj med rikliga mängder tempererat 20°C - 30°C vatten i minst

10 min.

Förtäring:

Tillkalla genast läkare. Framkalla kräkning endast om läkare tillråder det.

Ge aldrig något att äta eller drick till en medvetslös person.

(41)

5. BRANDBEKÄMPNINGSÅTGÄRDER

Produkten är inte brandfarlig. Flampunkt: > 100°C.

Lämpliga släckmedel:

Anpassas efter material i omgivningen.

Utsatta förpackningar:

Kyl förpackningar med vattenspray eller låt dem svalna för att undvika

nedbrytning och utveckling av ämnen som kan ge hälsoskadliga effekter.

Skyddsutrustning:

Använd för brandbekämpning sedvanlig utrustning.

6. ÅTGÄRDER VID OAVSIKTLIGA UTSLÄPP

Personliga

skyddsåtgärder:

Inga särskilda

Miljömässiga åtgärder:

Meddela Räddningsverket vid större spill.

Saneringsmetoder:

Samla upp spillet i lämpliga behållare. Spola bort rester med kraftig

vattenstråle.

7. HANTERING OCH LAGRING

Hantering:

Undvik dammbildande hantering.

Förebyggande åtgärder mot brand och explosion:

Se till att det finns utrustning för att kyla ner utsatta förpackningar för att förhindra övertryck och

överhettning i händelse av brand.

Lagring:

Förvara produkten i väl tillslutna förpackningar.

8. BEGRÄNSNING AV EXPONERINGEN/PERSONLIGT SKYDD

Hygieniska gränsvärden för ingående ämnen enligt Arbetsmiljöverkets författningssamling AFS

2005:17: Produkten innehåller inga ämnen som är föremål för gränsvärdesövervakning.

Skyddsåtgärder:

Ät, drick eller röka inte under hanteringen.

Andningsskydd:

Andningsskydd vid otillräcklig ventilation.

Skydd för händerna:

Skyddshandskar vid behov.

Ögonskydd:

Skyddsglasögon vid risk för stänk i ögonen.

(42)

9. FYSIKALISKA OCH KEMISKA EGENSKAPER

Allmänna kännetecken:

Form:

Fast ämne

Färg:

Vit och terrakotta

Lukt:

Typisk

Fysikalisk/kemiska egenskaper:

Löslighet:

Delvis löslig i vatten

pH:

7-8

Flampunkt:

> 100°C

Specifik vikt:

1,700 kg/l.

10. STABILITET OCH REAKTIVITET

Stabilitet:

Stabil vid normala användnings- och

lagringsförhållanden.

Farliga nedbrytningsprodukter:

Vid upphettning eller brand kan termisk nedbrytning

inträffa och potentiellt hälsoskadliga ångor utlösas.

11. TOXIKOLOGISK INFORMATION

Produkten innehåller inga hälsoskadliga ämnen.

Enligt tillverkarens uppgifter har produkten inte rapporterats ge några hälsoskadliga effekter. Man bör

emellertid handskas med produkten på ett ansvarsfullt sätt. Produkten kan ha en mindre negativ effekt

på känsliga individer vid inandning och/eller hudabsorption och/eller kontakt med ögonen och/eller

förtäring.

12. EKOLOGISK INFORMATION

Produkten innehåller inga miljöfarliga ämnen.

Undvik att skräpa ner naturen med produkten. Meddela Räddningsverket vid större utsläpp.

13. AVFALLSHANTERING

Lämnas till sopstation för kassering. Följ gällande, lokala föreskrifter för avfallshantering.

Förslag till avfallskod:

16 01 99

Annat avfall

14. TRANSPORTINFORMATION

(43)

15. GÄLLANDE FÖRESKRIFTER

Klassificering/märkning

Symbol/faroklass:

-

Riskfraser:

-

Skyddsfraser:

-

16. ANNAN INFORMATION

Säkerhetsdatabladet är utformat enligt riktlinjerna i Kemikalieinspektionens faktablad

Säkerhetsdatablad för produkter som släpps ut på den svenska marknaden. Översatt/REACH-anpassat

från engelska till svenska 2009-05-29 från originalet 2006-05-17.

(44)

6'6L|YHUHQVVWlPPHOVHPHG(XURSDSDUODPHQWHWVRFKUnGHWVI|URUGQLQJ(*QURPUHJLVWUHULQJ XWYlUGHULQJJRGNlQQDQGHRFKEHJUlQVQLQJDYNHPLNDOLHU5($&+

$961,771DPQHWSnlPQHWEODQGQLQJHQRFKERODJHWI|UHWDJHW

8WJLYQLQJVGDWXP

3URGXNWEHWHFNQLQJ

3URGXNWQDPQ %DRZDFKV 6\QRQ\PHU /DJQLQJVNLWW0MXNYD[ $UWLNHOQU

5HOHYDQWDLGHQWLILHUDGHDQYlQGQLQJDUDYlPQHWHOOHUEODQGQLQJHQRFK

DQYlQGQLQJDUVRPGHWDYUnGVIUnQ

$QYlQGQLQJVRPUnGH 5HSDUDWLRQDYP|EOHULWUlRFKDQGUDPDWHULDO

1lUPDUHXSSO\VQLQJDURPGHQVRPWLOOKDQGDKnOOHUVlNHUKHWVGDWDEODG

)|UHWDJVQDPQ (51673$% 3RVWDGUHVV %R[ 3RVWQU 3RVWRUW *|WHERUJ /DQG 6YHULJH 7HOHIRQ )D[ (SRVW LQIR#HUQVWSVH :HEEDGUHVV KWWSZZZHUQVWSVH 2UJQU

7HOHIRQQXPPHUI|UQ|GVLWXDWLRQHU

1|GWHOHIRQ *LIWLQIRUPDWLRQVFHQWUDOHQ

$961,77)DUOLJDHJHQVNDSHU

.ODVVLILFHULQJDYlPQHWHOOHUEODQGQLQJHQ

.ODVVLILFHULQJDQWHFNQLQJDU ,QWHNODVVLILFHUDGHQOLJW)|URUGQLQJ(*

0lUNQLQJVXSSJLIWHU

)DURDQJLYHOVHU ,QWHPlUNQLQJVSOLNWLJHQOLJW)|URUGQLQJ(* 6N\GGVDQJLYHOVHU ,QWHPlUNQLQJVSOLNWLJHQOLJW)|URUGQLQJ(* 92& 0D[LPDODKDOWHQDYIO\NWLJDRUJDQLVNDI|UHQLQJDU

$QGUDIDURU

$QGUDIDURU 'HQKlUEODQGQLQJHQLQQHKnOOHULQJHWlPQHVRPEHWUDNWDVVRPSHUVLVWHQW ELRDFNXPXOHUDQGHHOOHUWR[LVNW3%7'HQKlUEODQGQLQJHQLQQHKnOOHULQJHW lPQHVRPEHWUDNWDVVRPP\FNHWSHUVLVWHQWHOOHUP\FNHWELRDFNXPXOHUDQGH Y3Y%

$961,776DPPDQVlWWQLQJLQIRUPDWLRQRPEHVWnQGVGHODU

%ODQGQLQJDU

bPQH ,GHQWLILHULQJ .ODVVLILFHULQJ ,QQHKnOO

63905Aquazol® 500 Material Safety Data Sheet

Identification of the Substance/Mixture and of the Company/Undertaking

1.

Hazards Identification

2.

Composition/Information on Ingredients

3.

First Aid Measures

4.

Fire-Fighting Measures

5.

Accidential Release Measures

6.

Handling and Storage

7.

Exposure Controls/Personal Protection

8.

Physical and Chemical Properties

9.

Stability and Reactivity

10.

Toxicological Information

11.

Ecological Information

12.

Disposal Considerations

13.

Transport Information

14.

Regulatory Information

15.

Other Information

16.

Identification of the Substance/Mixture and of the Company/Undertaking

1.

Hazards Identification

2.

Composition/Information on Ingredients

3.

First Aid Measures

4.

Fire-Fighting Measures

5.

Accidential Release Measures

6.

Handling and Storage

7.

Exposure Controls/Personal Protection

8.

Physical and Chemical Properties

9.

Stability and Reactivity

10.

Toxicological Information

11.

Ecological Information

12.

Disposal Considerations

13.

Transport Information

14.

Regulatory Information

15.

Other Information

16.

$961,771DPQHWSnlPQHWEODQGQLQJHQRFKERODJHWI|UHWDJHW

3URGXNWEHWHFNQLQJ

5HOHYDQWDLGHQWLILHUDGHDQYlQGQLQJDUDYlPQHWHOOHUEODQGQLQJHQRFK

DQYlQGQLQJDUVRPGHWDYUnGVIUnQ

1lUPDUHXSSO\VQLQJDURPGHQVRPWLOOKDQGDKnOOHUVlNHUKHWVGDWDEODG

3URGXFHQW

7HOHIRQQXPPHUI|UQ|GVLWXDWLRQHU

$961,77)DUOLJDHJHQVNDSHU

.ODVVLILFHULQJDYlPQHWHOOHUEODQGQLQJHQ

0lUNQLQJVXSSJLIWHU

)DURSLNWRJUDP &/3

$QGUDIDURU

$961,776DPPDQVlWWQLQJLQIRUPDWLRQRPEHVWnQGVGHODU

bPQHQ

$961,77cWJlUGHUYLGI|UVWDKMlOSHQ

$961,771DPQHWSnlPQHWEODQGQLQJHQRFKERODJHWI|UHWDJHW

3URGXNWEHWHFNQLQJ

5HOHYDQWDLGHQWLILHUDGHDQYlQGQLQJDUDYlPQHWHOOHUEODQGQLQJHQRFK

1lUPDUHXSSO\VQLQJDURPGHQVRPWLOOKDQGDKnOOHUVlNHUKHWVGDWDEODG

7HOHIRQQXPPHUI|UQ|GVLWXDWLRQHU

$961,77)DUOLJDHJHQVNDSHU

.ODVVLILFHULQJDYlPQHWHOOHUEODQGQLQJHQ

0lUNQLQJVXSSJLIWHU

)DURSLNWRJUDP&/3

$QGUDIDURU

$961,776DPPDQVlWWQLQJLQIRUPDWLRQRPEHVWnQGVGHODU

bPQHQ

$961,77cWJlUGHUYLGI|UVWDKMlOSHQ

%HVNULYQLQJDYnWJlUGHUYLGI|UVWDKMlOSHQ

'HYLNWLJDVWHV\PSWRPHQRFKHIIHNWHUQDEnGHDNXWDRFKI|UGU|MGD

6OlFNPHGHO

6lUVNLOGDIDURUVRPlPQHWHOOHUEODQGQLQJHQNDQPHGI|UD

5nGWLOOEUDQGEHNlPSQLQJVSHUVRQDO

$961,77cWJlUGHUYLGRDYVLNWOLJDXWVOlSS

3HUVRQOLJDVN\GGVnWJlUGHUVN\GGVXWUXVWQLQJRFKnWJlUGHUYLGQ|GVLWXDWLRQHU

0LOM|VN\GGVnWJlUGHU

0HWRGHURFKPDWHULDOI|ULQQHVOXWQLQJRFKVDQHULQJ

+lQYLVQLQJWLOODQGUDDYVQLWW

$961,77+DQWHULQJRFKODJULQJ

)|UVLNWLJKHWVPnWWI|UVlNHUKDQWHULQJ

)|UKnOODQGHQI|UVlNHUODJULQJLQNOXVLYHHYHQWXHOORI|UHQOLJKHW

6SHFLILNVOXWDQYlQGQLQJ

$961,77%HJUlQVQLQJDYH[SRQHULQJHQSHUVRQOLJWVN\GG

.RQWUROOSDUDPHWUDU

gJRQDQVLNWVVN\GG

+\JLHQ0LOM|

$961,77)\VLNDOLVNDRFKNHPLVNDHJHQVNDSHU

,QIRUPDWLRQRPJUXQGOlJJDQGHI\VLNDOLVNDRFKNHPLVNDHJHQVNDSHU

$QQDQLQIRUPDWLRQ

$961,776WDELOLWHWRFKUHDNWLYLWHW

5HDNWLYLWHW

)|UKnOODQGHQVRPVNDXQGYLNDV

2I|UHQOLJDPDWHULDO

)DUOLJDV|QGHUGHOQLQJVSURGXNWHU

$961,777R[LNRORJLVNLQIRUPDWLRQ

,QIRUPDWLRQRPGHWR[LNRORJLVNDHIIHNWHUQD

)|UGU|MGDHIIHNWHUXSSUHSDGH[SRQHULQJ

&DQFHURJHQ0XWDJHQRFK5HSURGXNWLRQVWR[LVN

$961,77(NRORJLVNLQIRUPDWLRQ

7R[LFLWHW

%LRDFNXPXOHULQJVI|UPnJD

5|UOLJKHWHQLMRUG

5HVXOWDWDY3%7RFKY3Y%EHG|PQLQJHQ

$QGUDVNDGOLJDHIIHNWHU

$961,77$YIDOOVKDQWHULQJ

$YIDOOVEHKDQGOLQJVPHWRGHU

$961,777UDQVSRUWLQIRUPDWLRQ

81QXPPHU

2IILFLHOOWUDQVSRUWEHQlPQLQJ

)DURNODVVI|UWUDQVSRUW

)|USDFNQLQJVJUXSS

%XONWUDQVSRUWHQOLJWELODJD,,WLOO0$532/RFK,%&NRGHQ

**$961,77*lOODQGHI|UHVNULIWHU**

)|UHVNULIWHUODJVWLIWQLQJRPlPQHWHOOHUEODQGQLQJHQQlUGHWJlOOHUVlNHUKHW

.HPLNDOLHVlNHUKHWVEHG|PQLQJ

$961,77$QQDQLQIRUPDWLRQ