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Transition metal carbide

nanocomposite and

amorphous thin films

Olof Tengstrand

Linköping Studies in Science and Technology Dissertations No. 1576

Ol

of T

en

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ran

d

T

ran

siti

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eta

l c

arb

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an

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site a

nd a

m

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20

14

Linköping Studies in Science and Technology No. 1576, 2014 Thin Film Physics Division

Department of Physics, Chemistry and Biology SE-581 83 Linköping, Sweden

www.liu.se

This thesis investigates thin surface coatings consisting of advanced nanocomposites deposited by magnetron sputtering. I describe how structure and composition of such materials can affect their electrical and mechanical properties. This is important in order to tailor and optimize the properties of a functional surface intended for electrical contacts. The investigated materials are built up by one of the metals zirconium, niobium or titanium which together with carbon forms a composite material. The composite consists of nanometer sized carbide grains surrounded by amorphous carbon. I also add silicon and germanium in order to further alter the material properties. The thesis also shows how an amorphous material crystallizes during observation by electron microscopy, an important artefact to be considered but also an alternative way to form nanocomposites.

(2)

Transition metal carbide

nanocomposite and

amorphous thin films

Olof Tengstrand

Linköping Studies in Science and Technology Dissertations No. 1576

Ol

of T

en

gst

ran

d

T

ran

siti

on m

eta

l c

arb

ide n

an

oc

om

po

site a

nd a

m

orp

ho

us t

hin fi

lm

s

20

14

Linköping Studies in Science and Technology No. 1576, 2014 Thin Film Physics Division

Department of Physics, Chemistry and Biology SE-581 83 Linköping, Sweden

www.liu.se

This thesis investigates thin surface coatings consisting of advanced nanocomposites deposited by magnetron sputtering. I describe how structure and composition of such materials can affect their electrical and mechanical properties. This is important in order to tailor and optimize the properties of a functional surface intended for electrical contacts. The investigated materials are built up by one of the metals zirconium, niobium or titanium which together with carbon forms a composite material. The composite consists of nanometer sized carbide grains surrounded by amorphous carbon. I also add silicon and germanium in order to further alter the material properties. The thesis also shows how an amorphous material crystallizes during observation by electron microscopy, an important artefact to be considered but also an alternative way to form nanocomposites.

References

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