SWE DIS H STAN DARD S
INS TITUTE
SVENSK STANDARD
SS-EN 12472:2005+A1:2009
Fastställd/Approved: 2009-06-29 Publicerad/Published: 2009-09-15 Utgåva/Edition: 1
Språk/Language: engelska/English ICS: 39.060
Metod som simulerar nötning och korrosion inför analys av frisättning av nickel från ytbelagda produkter
Method for the simulation of wear and corrosion for the detection of nickel release from coated items
This preview is downloaded from www.sis.se. Buy the entire This preview is downloaded from www.sis.se. Buy the entire This preview is downloaded from www.sis.se. Buy the entire This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
standard via https://www.sis.se/std-70130 standard via https://www.sis.se/std-70130 standard via https://www.sis.se/std-70130
Find the right product and the type of delivery that suits you
Standards
By complying with current standards, you can make your work more ecient and ensure reliability. Also, several of the standards are often supplied in packages.
Services
Subscription is the service that keeps you up to date with current standards when changes occur in the ones you have chosen to subscribe to. is ensures that you are always working with the right edition.
e-nav is our online service that gives you and your colleagues access to the standards you subscribe to 24 hours a day. With e-nav, the same standards can be used by several people at once.
Type of delivery
You choose how you want your standards delivered. We can supply them both on paper and as PDF les.
Other products
We have books that facilitate standards compliance. ey make it easier to understand how compliance works and how this benets you in your operation. We produce many publications of our own, and also act as retailers. is means that we have more than 500 unique titles for you to choose from. We also have technical reports, specications and workshop agreements.
Matrices, listed at sis.se, provide an overview of which publications belong together.
Standardisation project
You can inuence the content of future standards by taking part in one or other of SIS’s 400 or so Technical Committees.
Standarder
Genom att följa gällande standard både eektiviserar och säkrar du ditt arbete. Många standarder ingår dessutom ofta i paket.
Tjänster
Abonnemang är tjänsten där vi uppdaterar dig med aktuella standarder när förändringar sker på dem du valt att abonnera på.
På så sätt är du säker på att du alltid arbetar efter rätt utgåva.
e-nav är vår online-tjänst som ger dig och dina kollegor tillgång till standarder ni valt att abonnera på dygnet runt. Med e-nav kan samma standard användas av era personer samtidigt.
Leveranssätt
Du väljer hur du vill ha dina standarder levererade. Vi kan erbjuda dig dem på papper och som pdf.
Andra produkter
Vi har böcker som underlättar arbetet att följa en standard. Med våra böcker får du ökad förståelse för hur standarder ska följas och vilka fördelar den ger dig i ditt arbete. Vi tar fram många egna publikationer och fungerar även som återförsäljare. Det gör att du hos oss kan hitta över 500 unika titlar. Vi har även tekniska rapporter, specikationer och “workshop agreement”.
Matriser är en översikt på standarder och handböcker som bör läsas tillsammans. De nns på sis.se och ger dig en bra bild över hur olika produkter hör ihop.
Standardiseringsprojekt
Du kan påverka innehållet i framtida standarder genom att delta i någon av SIS ca 400 Tekniska Kommittéer.
Hitta rätt produkt och ett leveranssätt som passar dig
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
Upplysningar om sakinnehållet i standarden lämnas av SIS, Swedish Standards Institute, telefon 08-555 520 00.
Standarder kan beställas hos SIS Förlag AB som även lämnar allmänna upplysningar om svensk och utländsk standard.
Information about the content of the standard is available from the Swedish Standards Institute (SIS), tel +46 8 555 520 00.
Standards may be ordered from SIS Förlag AB, who can also provide general information about Swedish and foreign standards.
SIS Förlag AB, SE 118 80 Stockholm, Sweden. Tel: +46 8 555 523 10. Fax: +46 8 555 523 11.
E-mail: sis.sales@sis.se Internet: www.sis.se
© Copyright/Upphovsrätten till denna produkt tillhör SIS, Swedish Standards Institute, Stockholm, Sverige. Användningen av denna produkt regleras av slutanvändarlicensen som åternns i denna produkt, se standardens sista sidor.
© Copyright SIS, Swedish Standards Institute, Stockholm, Sweden. All rights reserved. The use of this product is governed by the end-user licence for this product. You will nd the licence in the end of this document.
!
Europastandarden EN 12472:2005+A1:2009 gäller som svensk standard. Detta dokument innehåller den officiella engelska versionen av EN 12472:2005+A1:2009.
Denna standard ersätter SS-EN 12472:2005, utgåva 2.
The European Standard EN 12472:2005+A1:2009 has the status of a Swedish Standard. This document contains the official English version of EN 12472:2005+A1:2009.
This standard supersedes the Swedish Standard SS-EN 12472:2005, edition 2.
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 12472:2005+A1
June 2009
ICS 39.060 Supersedes EN 12472:2005
English Version
Method for the simulation of wear and corrosion for the detection of nickel release from coated items
Méthode de simulation de l'usure et de la corrosion pour la détermination du nickel libéré par les objets revêtus
Simulierte Abrieb- und Korrosionsprüfung zum Nachweis der Nickelabgabe von mit Auflagen versehenen
Gegenständen
This European Standard was approved by CEN on 21 November 2005 and includes Amendment 1 approved by CEN on 21 May 2009.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION C O M IT É E U R O P É E N D E N O R M A LIS A T I O N EUROPÄISC HES KOM ITEE FÜR NOR MUNG
Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2009 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members.
Ref. No. EN 12472:2005+A1:2009: E This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
2
Contents
page
Foreword ... 3
Introduction ... 4
1 Scope ... 5
2 Normative references ... 5
3 Principle ... 5
4 Reagents and materials ... 5
4.1 Corrosion ... 5
4.2 Wear ... 6
5 Procedure ... 8
5.1 Sample preparation ... 8
5.2 Corrosion procedure ... 8
5.3 Wear procedure ... 8
5.4 Determination of nickel release ... 9
6 Test report ... 9
Annex A (informative) Detailed examples of how to attach different types of items ... 10
A.1 General ... 10
A.2 Attachment of items with only one side in contact with the skin ... 10
A.3 Spectacle frames ... 10
A.4 Chains, watches, bracelets, rings etc. ... 12
Bibliography ... 14 SS-EN 12472:2005+A1:2009 (E)This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
3
Foreword
This document (EN 12472:2005+A1:2009) has been prepared by Technical Committee CEN/TC 347 “Methods for analysis of allergens”, the secretariat of which is held by DS.
This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by December 2009, and conflicting national standards shall be withdrawn at the latest by December 2009.
This document includes Amendment 1, approved by CEN on 2009-05-21.
This European Standard supersedes !EN 12472:2005."
The start and finish of text introduced or altered by amendment is indicated in the text by tags !".
This European Standard has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
SS-EN 12472:2005+A1:2009 (E)
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
4
Introduction
The wear of objects in contact with the skin depends very much on the type and shape of the objects and the activities of the person concerned. This procedure attempts to simulate the wear and corrosion on a coated article during two years of normal use. By its nature this is a pragmatic solution to the problems posed by the evaluation of coated items in contact with the skin, which may be subject to several kinds and varying degrees of wear.
In order to show compliance with Directive 94/27/EC, items should be tested in accordance with the appropriate European harmonised standard(s), the references of which have been published by the European Commission in the Official Journal of the European Communities. Currently, these are EN 1810, EN 1811 and this European Standard.
SS-EN 12472:2005+A1:2009 (E)This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
5
1 Scope
This European Standard specifies a method for accelerated wear and corrosion, to be used prior to the detection of nickel release from coated items that come into direct and prolonged contact with the skin.
2 Normative references
The following referenced documents are indispensable for the application of this European Standard. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1811, Reference test method for release of nickel from products intended to come into direct and prolonged contact with the skin
3 Principle
The items to be tested are exposed to a corrosive atmosphere before being placed into a tumbling barrel together with a wear medium of abrasive paste and granules. The barrel is rotated so as to subject the test pieces to wear from the wear medium. The items are then tested for nickel release in accordance with EN 1811.
4 Reagents and materials
Except where indicated, all reagents and materials that can come into contact with samples or reagents shall be demonstrably free of nickel, and all reagents shall be of recognized analytical grade or better.
4.1 Corrosion 4.1.1 Container
Container with a lid and a device for suspending the test pieces, all parts made of inert material (e.g. glass or plastic).
SS-EN 12472:2005+A1:2009 (E)
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
6
4.1.2 Corrosive medium
Dissolve 50 g DL-lactic acid, > 85 % purity, and 100 g sodium chloride in 1 000 ml de-ionized water.
4.1.3 Degreasing solution
An appropriately diluted, neutral, commercially available detergent shall be used, for example, a 0,5 % aqueous solution of sodium dodecylbenzene sulfonate.
4.1.4 De-ionized water
De-ionized water, specific conductivity maximum 1 μS/cm.
4.1.5 Laboratory oven
Laboratory oven, capable of maintaining a temperature of (50 ± 2) °C.
4.2 Wear
4.2.1 Tumbling barrel and retaining assembly
The tumbling barrel and retaining assembly shall be in accordance with the following description:
barrel of hexagonal cross-section and internal diameter of 19 cm perpendicular distance between opposite sides designed to rotate around its axis which is orientated horizontally (see Figure 1);
retaining assembly, suitable for attaching the test items so that they do not come into contact with each other during tumbling;
retaining assembly, with items attached, shall be inserted into the barrel for tumbling.
NOTE Examples are given in Annex A of retaining assemblies suitable for attaching typical items.
SS-EN 12472:2005+A1:2009 (E)This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
EN 12472:2005+A1:2009 (E)
7 Dimensions in millimetres
Key
l length of barrel axis, as required a axis of rotation
Figure 1 — View of tumbling barrel
4.2.2 Wear test apparatus
A device capable of imparting to the barrel (4.2.1) a constant (30 ± 2) rotations per minute. The device shall be capable of allowing the direction of rotation to be reversed.
NOTE Information on sourcing suitable equipment is available from the CEN Management Centre.
4.2.3 Abrasive paste
Abrasive paste produced for dry-tumbling barrels. The abrasive paste shall comprise:
6 % to 8 % Ester wax of montanic acids-Wax E [CAS No. 73138-45-1];
3 % Octadecanoic acid (stearic acid) [CAS No. 57-11-4];
30 % to 35 % Petroleum distillates, hydrotreated light paraffinic [CAS No. 64742-55-8];
2 % Polyethylene glycol cetyl/oleyl ether [CAS No. 68920-66-1)] or Triethanolamine [CAS No. 102-71-6];
48 % Silicon dioxide (quartz) 200 μm mesh size [CAS No. 14808-60-7];
6 % to 9 % De-ionized water.
NOTE Information on sourcing a suitable paste is available from the CEN Management Centre.
SS-EN 12472:2005+A1:2009 (E)
This preview is downloaded from www.sis.se. Buy the entire standard via https://www.sis.se/std-70130
