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Diskussion och slutsatser

Som tidigare framhållits är modellering av emissioner från bränder en svår och komplex uppgift. Inga exakta metoder finns. Trots dessa svårigheter finns ett betydande behov av att kunna beräkna emissioner från bränder i samhället. Behovet finns både för direkta tekniska applikationer vid en brandplats, t.ex. som underlag för spridningsberäkningar runt brandområdet och för beräkningar av totala emissionerna från en brand. På det nationella planet finns behov av att kunna beräkna Sveriges totala emissioner från bränder. I projektet valdes en semi-empirisk strategi för modelleringen där teoretiska beräkningar blandades med empiriska mätdata för att skapa en praktiskt användbar modell. Denna strategi har fungerat väl i projektet och det har på detta sätt varit möjligt att ta fram en fungerande basmodell. Att utveckla en fullt fungerande emissionsmodell för bränder är givetvis en omfattande uppgift och det saknas i nuläget information för att till alla delar kunna ta fram en sådan generell modell. Det har därför inte funnits möjlighet att inom ramen för detta projekt att fullt ut utveckla modellen. Några emissionsparametrar och vissa ämnen, som t.ex. dioxin, har inte inkluderats ännu. Modellen behöver också testas och verifieras ytterligare. Projektet har dock varit mycket framgångsrikt i och med att det med all tydlighet visat att det är fullt möjligt att utveckla en praktiskt användbar emissionsmodell för bränder. För användning vid beräkning av nationella emissioner behövs också en utveckling göras för att kunna simulera emissioner från olika typer av bränder och därefter kombinera detta med den svenska brandstatistiken.

10

Referenser

1. Lindberg, Y., Gymnasieskolans Tabeller och Formler, Liber Läromedel, Malmö,

1984.

2. Rosser, W. G. V., An introduction to Statistcal Physics, Ellis Horwood Limited,

1986.

3. Haynes, B. S., "The formation and behaviour of nitrogen species in fuel rich

hydrocarbon flames", Dissertation, University New South Wales, 1975.

4. Fenimore, C. P., "Formation of nitric oxide from fuel nitrogen in ethylene

flames", Combustion and Flame, 19, 289-296, 1972.

5. Zevenhoven, R., Axelsen, E. P., Kilpinen, P., and Hupa, M., "Nitrogen oxides

from nitrogen-containing waste fuels at FBC conditions - Part 1", The 39th IEA FBC meeting, Madrid, Spain, 22-24 November, 1999.

6. Hakkarainen, T., Ed. "Smoke gas analysis by Fourier transform infrared

spectroscopy - Final report of the SAFIR project," VTT Building Technology, Finland, 1999.

7. Tewarson, A., "Generation of Heat and Chemical Compounds in Fires". In The

SFPE Handbook of Fire Protection Engineering (P. J. DiNenno, D. Drysdale, C.

L. Beyler, W. D. Walton, R. L. P. Custer, J. R. Hall, and J. M. Watts, Eds.), National Fire Protection Association, 3-82 -- 3-161, Quincy, MA, USA, 2002.

8. Rutkowski, J. V., and Levin, B. C., "Acrylonitile-Butadiene-Styrene Copolymers

(ABS): Pyrolysis and Combustion Products and their Toxicity - A Review of the literature", Fire and Materials, 10, 93-105, 1986.

9. Eberius, H., Just, T., and Kelm, S., "NOx Schadstoffbildung aus gebundenem

stickstoff in Propan/Luft-Flammen, Vergleich mit kinetischen Modellen", VDI- Verlag, VDI Berichte 498, Düsseldorf, Germany, pp. 183-192, 1983.

10. Kremer, H., Schults, W., and Zelkowski, J., "NOx-Entstehung in Feuerungen",

VGB-TB, 310, 24-43, 1985.

11. Wendt, J. O. L., "Fundamental coal combustion mechanisms and pollutant

formation in furnaces", Progress in Energy and Combustion Science, 6, 201-222, 1980.

12. Scheuer, A., "Theoretische und betriebliche Untersuchung zur Bildung und zum

Abbau von Stickstoffmonoxid in Zementdrehofenanlagen", Beton-Verlag GmbH, Schriftenreihe der Zementindustrie, Heft 49/1987, ISSN 0487-7217, 1987.

13. Fenimore, C. P., "Formation of nitric oxide in premixed hydrocarbone flames",

13th Symposium (International) on Combustion, 373-380, Pittsburgh, 1972.

14. De Soete, G. G., "Heterogene Stickstoffoxidreduzierung an festen Partikeln",

VDI Berichte, 498, 171-176, 1983.

15. Hulgaard, T., "Nitrous oxide from combustion - literature survey", DTH, Report

8909, Lyngby, Denmark, 1989.

16. Hupa, M., and Kilpinen, P., "Homogeneous N2O chemistry at fluidised bed

conditions", European Workshop on the emissions of N2O, Lisbon, Portugal, 6-8 June, 1990.

17. De Soete, G. G., "Actual knowledge status on heterogeneous mechanisms of

N2O formation and destruction during combustion and flue gas aftertreatment", European Workshop on the emissions of N2O, Lisbon, Portugal, 6-8 June, 1990.

18. Miettinen, H., Strömberg, D., and Lindqvist, O., "The influence of some oxide

and sulphate surfaces on N2O decomposition", Oorganisk kemi, Chalmers Tekniska Högskola, Internal report, Göteborg, Sweden, 1991.

19. Collin, R., "Eldningsteknik - fasta, flytande och gasformiga ämnen", Institutionen

för Värme- och Ugnsteknik, Högskolan i Stockholm, Kursmaterial, Stockholm, 1975.

20. Blomqvist, P., "Emissions from Fires - Consequences for Human Safety and the Environment", Doctoral thesis, Department of Fire Safety Engineering, Lund University, Lund, Sweden, 2005.

21. Glassman, I., Combustion, Academic Press, 1977.

22. Niessen, W. R., Combustion and Incineration Processes - Applications in

Environmental Engineering, 1978.

23. Wang, K. S., Chiang, K. Y., Lin, S. M., Tsai, C. C., and Sun, C. J., "Effects of

chlorides on emissions of hydrogen chloride formation in waste incineration",

Chemosphere, 38, 1571-1582, 1999.

24. Simonson, M., Blomqvist, P., Boldizar, A., Möller, K., Rosell, L., Tullin, C.,

Stripple, H., and Sundqvist, J. O., "Fire-LCA Model: TV Case Study", SP Swedish National Testing and Research Institute, SP REPORT 2000:13, Borås, Sweden, 2000.

25. Benbow, A. W., and Cullins, C. F., "The formation of toxic products during the

combustion of halogen-containing polymers", European Polymer Journal, 11, 723-727, 1975.

26. Blomqvist, P., Persson, B., and Simonson, M., "Utsläpp från bränder till miljön -

Utsläpp av dioxin, PAH och VOC till luften", Räddningsverket, P21-407/02, Karlstad, 2002.

27. SNV, "Kartläggning av källor till oavsiktligt bildade ämnen - Rapport till

regeringen 2005-03-31", Naturvårdsverket, Rapport 5462, Stockholm, Sweden, 2005.

28. Wikström, E., "The Role of Chlorine during Waste Combustion", PhD thesis,

Department of Chemistry, Environmental Chemistry, Umeå University, Umeå, Sweden, 1999.

29. Stehl, R. H., Papenfuss, R. R., Bredeweg, R. A., and Roberts, R. W., "The

stability of pentachlorophenol and chlorinated dioxins to sunlight, heat, and combustion". In Chlorodioxins - origin and fate (E. H. Blair, Ed.), American Chemical Society, Washington, DC, 1973.

30. Schaub, W. M., and Tsang, W., "Physical and chemical properties of dioxins in

relation to their disposal". In Human and Environmental Risks of Chhlorinated

Dioxins and Related Compounds (R. E. Tucker, A. L. Young, and A. P. Gray,

Eds.), Plenum Press, New York, NY, 1983.

31. Fängmark, I., Stomberg, G., Berge, N., and Rappe, C., "Influence of

postcombustion temperature profiles on the formation of PCDDs, PCDFs, PCBzs, and PCBs in a pilot incinerator", Environmental Science & Technology, 28, 624-629, 1994.

32. Vogg, H., Metzger, M., and Steiglitz, L., "Recent findings on the formation and

decomposition of PCDD/PCDF in municipal solid waste incineration", Waste

Management and Research, 5, 3, 285-294, 1987.

33. Vogg, H., Nunsinger, H., Merz, A., and Steiglitz, L., "Influencing the production

of dioxin/furan in solid waste incineration plats by measures affecting the

combustion as well as the flue gas cleaning systems", Chemosphere, 25, 1-2, 149- 152, 1992.

34. Öberg, T., Warman, K., and Bergström, J., "Production of chlorinated aromatics

in the post-combustion zone and boiler", Chemosphere, 19, 1-6, 317-322, 1989.

35. Weber, R., and Hagenmaier, H., "Mechanism of formation of polychlorinated

dibenzo-p-dioxins and dibenzofurans from chlorophenols in gas phase reactions",

Chemosphere, 38, 529-549, 1999.

36. Dickson, L. C., Lenoir, D., and Hutzinger, O., "Quantitative comparison of de

novo and precursor formation of polychlorinated dibenzo-p-dioxins under simulated municipal solid waste incinerator post combustion conditions",

37. Bruce, K. R., Beach, L. O., and Gullet, R. K., "The role of gas-phase Cl in the formation of PCDD/PCDF during waste combustion", Waste Management, 11, 97-102, 1991.

38. Cleverly, D. H., Morrison, R. M., Riddle, B. L., and Kellam, R. G., "Regulatory

analysis of pollutant emissions, including polychlorinated dibenzo-p-dioxins (CDDs) and dibenzofurans (CDFs), from municipal waste combustors". In

Health effects of municipal waste incineration (H. A. Hattemer and C. Travis,

Eds.), CRC Press, 47-65, Boca Raton, FL, 1991.

39. Gullet, B. K., Bruce, K. R., and Beach, L. O., "Formation of chlorinated organics

during solid waste combustion", waste Management and Research, 8, 203-214, 1990.

40. Commoner, B., Shapiro, K., and Webster, T., "The origin and health risks of

PCDD and PCDF", Waste Management and Research, 5, 327-346, 1987.

41. Dickson, L. C., and Karasek, F. W., "Mechanism of formation of polychlorinated

dibenzo-p-dioxins produced on municipal incinerator flyash from reactions of chlorinated phenols", Journal of Chromatography, 389, 127-137, 1987.

42. Addink, R., and Olie, K., "Mechanism of formation and destruction of

polychlorinated dibenzo-p-dioxins and dibenzofurans in heterogeneous systems",

Environmental Science & Technology, 29, 1425-1435, 1995.

43. Born, J. G. P., Mulder, P., and Louw, R., "Fly ash mediated reactions of phenol

and monochlorophenols: Oxychlorination, deep oxidation, and condensation",

Environmental Science & Technology, 27, 1849-1863, 1993.

44. Lasagni, M., Collina, E., Tettamanti, M., and Pitea, D., "Kinetics of MSWI fly

ash thermal degradation. 1. Emperical rate equation for native carbon gasification", Environmental Science & Technology, 34, 130-136, 2000.

45. Eklund, G., Pedersen, J. R., and Stromberg, B., "Methane, hydrogen chloride and

oxygen form a wide range of chlorinated species in the temperature range 400 ºC - 959 ºC", Chemosphere, 17, 3, 575-586, 1988.

46. KEMI, "Ämnen som används som flamskyddsmedel 2004",

Kemikalieinspektionen, http://www.kemi.se/templates/Page____3697.aspx,

2006-11-17.

47. Lewin, M., and Weil, E. D., "Mechanisms and modes of action in flame

retardancy of polymers". In Fire retardant materials (A. R. Horrocks and D. Price, Eds.), Woodhead Publishing Limited, 31-68, Cambridge, England, 2001.

48. KEMI, Kemikalieinspektionen, www.kemi.se, 2004-08-13.

49. Sternbeck, Palm, and Kaj, "Antimon i Sverige - användning, spridning och

miljöpåverkan", IVL Svenska Miljöinstitutet, IVL rapport Bl 473, Göteborg, Sverige, 2002.

50. SpecialChem, http://www.specialchem4polymers.com/index.aspx.

51. Morf, L. S., Brunner, P. H., and Spaun, H. S., "Effect of operation conditions and

input variation on the partitioning of metals in a municipal solid incinerator",

Waste Management and Research, 18, 4-15, 2000.

52. "Heavy Metals in Waste", European Commission DG ENV. E3, Project

ENV.E.3/ETU/2000/0058, 2002.

53. Schachermayer, E., Bauer, G., and Ritter, E., "Messung der Güter- und

Stoffbilanz einer Müllverbrennungsanlage", Monographie, Band 56, Wien, 1995.

54. Amagerforbrænding, "Miljøredegørelse 2000", I/S Amagerforbrændingen,

Copenhagen, 2000.

55. Lönnermark, A., "Analyses of Fire Debris after Tyre Fires and Fires in Electrical

and Electronics Waste", SP Swedish National Testing and Research Institute, SP REPORT 2005:44, Borås, Sweden, 2005.

56. Persson, B., Simonson, M., and Månsson, M., "Utsläpp från bränder till

atmosfären", SP Sveriges Provnings- och Forskningsinstitut, SP RAPPORT 1995:70, Borås, Sweden (in Swedish), 1995.

57. Pitts, W. M., "The Global Equivalence Ratio Concept and the Prediction of Carbon Monoxide Formation in Enclosure Fires", National Institute of Standards and Technology, NIST Monograph 179, Gaithersburg, MD, USA, 1994.

58. Beyler, C. L., "Major Species Production by Diffusion Flames in a Two-layer

Compartment Fire Environment", Fire Safety Journal, 10, 47-56, 1986.

59. Gottuk, D. T., "Carbon Monoxide Production in Compartment Fires", Journal of

Fire Protection Engineering, 4, 4, 133-150, 1992.

60. Gottuk, D. T., and Lattimer, B. Y., "Effect of Combustion Conditions on Species

Production". In SFPE Handbook of Fire Protection Engineering (P. J. DiNenno, Ed.), National Fire Protection Association, Inc, 2-54 -- 2-82, Quincy,

Massachusetts, USA, 2002.

61. Blomqvist, P., and Lönnermark, A., "Characterization of the Combustion

Products in Large-scale Fire Tests: Comparison of Three Experimental Configurations", Fire and Materials, 25, 71-81, 2001.

62. Carroll Jr., W. F., "The relative contribution of wood and poly(vinyl chloride) to

emissions of PCDD and PCDF from house fires", Chemosphere, 45, 1173-1180, 2001.

63. Andersson, P., Blomqvist, P., Rosell, L., Simonson, M., and Stripple, H., "The

Environmental Effects of Furniture", Interflam 2004, 1467-1478, Edinburgh, Scotland, 5-7 July, 2004.

64. Andersson, P., Simonson, M., Rosell, L., Blomqvist, P., and Stripple, H., "Fire-

LCA Model: Furniture Study", SP Swedish National Testing and Research Institute, SP REPORT 2003:22, Borås, Sweden, 2003.

65. Blomqvist, P., Rosell, L., and Simonson, M., "Emissions from Fires Part II:

Simulated Room Fires", Fire Technology, 40, 59-73, 2004.

66. Bhargava, A., Dlugogorski, B. Z., and Kennedy, E. M., "Emission of

polyaromatic hydrocarbons, polychlorinated biphenyls and polychlorinated dibenzo-p-dioxins and furans from fires of wood chips", Fire Safety Journal, 37, 659-672, 2002.

67. Sundström, B., Ed. "Fire Safety of Upholstered Furniture - the final report on the

CBUF research programme," European Commission Measurement and Testing Report EUR 16477 EN, 1995.

68. Hertzberg, T., Blomqvist, P., Dalene, M., and Skarping, G., "Particles and

isocyanates from fires", SP Swedish National Testing and Research Institute, SP Report 2003:05, Borås, Sweden, 2003.

69. Blomqvist, P., Hertzberg, T., Dalene, M., and Skarping, G., "Isocyanates,

aminoisocyanates and amines from fires - a screening of common materials found in buildings", Fire and Materials, 27, 275-294, 2003.

70. Simonson, M., Tuovinen, H., and Emanuelsson, V., "Formation of Hydrogen

Cyanide in Fires - A Literature and Experimental Investigation", SP Swedish National Testing and Research Institute, SP REPORT 2000:27, Borås, Sweden, 2000.

71. Hertzberg, T., Tuovinen, H., and Blomqvist, P., "Measurement and Simulation of

Fire Smoke", SP Swedish National Testing and Research Institute, SP REPORT 2005:29, Borås, Sweden, 2005.

72. Babrauskas, V., Parker, W. J., Mulholland, G., and Twilley, W. H., "The phi

meter: A simple, fuel-independent instrument for monitoring combustion equivalence ratio", Rev. Sci Instrum., 65, 7, 2367-2375, 1994.

73. Lönnermark, A., and Babrauskas, V., "TOXFIRE - Fire Characteristics and

Smoke Gas Analyses in Under-ventilated Large-scale Combustion Experiments: Theoretical Background and Calculations", SP Swedish National Testing and Research Institute, SP REPORT 1996:49, Borås, Sweden, 1997.

74. Neviaser, J. L., and Gann, R., G., "Evaluation of Toxic Potency Values for

75. Lighty, J. S., Veranth, J. M., and Sarofim, A. F., "Combustion Aerosols: Factors Governing Their Size and Composition and Implications to Human Health",

Journal of Air Waste Manage Association, 50, 1565-1618, 2000.

76. Rau, J. A., "Composition and Size Distribution of Residental Wood Smoke

Particles", Aerosol Science and Technology, 10, 181-192, 1989.

77. Lönnermark, A., and Blomqvist, P., "Emissions from an Automobile Fire",

Chemosphere, 62, 1043-1056, 2006.

78. Lönnermark, A., and Blomqvist, P., "Emissions from Fires in Electrical and

Electronics Waste", SP Swedish National Testing and Research Institute, SP REPORT 2005:42, Borås, Sweden, 2005.

79. Lönnermark, A., and Blomqvist, P., "Emissions from Tyre Fires", SP Swedish

National Testing and Research Institute, SP REPORT 2005:43, Borås, Sweden, 2005.

80. ISO 5660-1, "Reaction-to-fire tests - Heat release, smoke production and mass

loss rate - Part 1: Heat release rate (cone calorimeter method)", 2nd ed., 2002-12- 15, ISO, 2002.

81. Butler, K., M., and Mulholland, G. W., "Generation and Transport of Smoke

Components", Fire Technology, 40, 149-176, 2004.

82. Braun, E., and Levin, B. C., "Polyesters: A Review of the Literature on Products

of Combustion and Toxicity", Fire and Materials, 10, 107-123, 1986.

83. Paabo, M., and Levin, B. C., "A Literature Review of the Chemical Nature and

Toxicity of the Decomposition Products of Polyethylenes", Fire and Materials, 11, 55-70, 1987.

84. Gurman, J. L., Baier, L., and Levin, B. C., "Polystyrenes: A Review of the

Literature on the Products of Thermal Decomposition and Toxicity", Fire and

Materials, 11, 109-130, 1987.

85. Huggett, C., and Levin, B. C., "Toxicity of the Pyrolysis and Combustion

Products of Poly (Vinyl Chlorides): A Literature Assessment", Fire and

Materials, 11, 131-142, 1987.

86. Levin, B. C., "A Summary of the NBS Literature Reviews on the Chemical

Nature and Toxicity of the Pyrolysis and Combustion Products from Seven Plastics: Acrylonitrile-Butadiene-Styrenes (ABS), Nylons, Polyesters, Polyethylenes, Polystyrenes, Poly(Vinyl Chlorides) and Rigid Polyurethane Foams"", Fire and Materials, 11, 143-157, 1987.

87. Hull, T. R., Lebek, K., and Paul, K. T., "Correlation of Toxic Products Yields

from Tube Furnace Tests and Large Scale Fires", 8th International Symposium on Fire Safety Science, Beijing, China, 18-23 September, 2005.

88. Lönnermark, A., Blomqvist, P., Månsson, M., and Persson, H., "TOXFIRE - Fire

Characteristics and Smoke Gas Analysis in Under-ventilated Large-scale Combustion Experiments: Tests in the ISO 9705 Room", SP Swedish National Testing and Research Institute, SP REPORT 1996:45, Borås, Sweden, 1997.

89. Lönnermark, A., Blomqvist, P., Månsson, M., and Persson, H., "TOXFIRE - Fire

Characteristics and Smoke Gas Analyses in Under-ventilated Large-scale Combustion Experiments: Storage Configuration Tests", SP Swedish National Testing and Research Institute, SP REPORT 1996:46, Borås, Sweden, 1996.

90. Hietaniemi, J., Kallonen, R., and Mikkola, E., "Fires at chemical warehouses - A

cone calorimeter study on the burning charcteristics and fire effluent composition of selected chemical compounds", VTT Technical research centre of Finland, VTT Research Notes 1810, Espoo, Finland, 1997.

91. Månsson, M., Dahlberg, M., Blomqvist, P., and Ryderman, A., "Combustion of

Chemical Substances: Fire Characteristics and Smoke Gas Components in Large- Scale Experiments", SP Swedish National Testing and Research Institute, SP REPORT 1994:28, Borås, Sweden, 1995.

92. "Tire Fires", U.S. Environmental Protection Agency,

http://www.epa.gov/epaoswer/non-hw/muncpl/tires/fires.htm, 2 December 2003.

93. Yamaguchi, E., "Emissions from Open Tire Fires",

http://www.p2pays.org/ref/11/10504/html/intro/openfire.htm, 13 October 2000.

94. Reisman, J. I., "Air Emissions from Scrap Tire Combustion", United States

Environmental Protections Agency, EPA-600/R-97-115, 1997.

95. "Tyre fires - a pile of polution", Fire Prevention, 241, July/August, 22-26, 1991.

96. Steer, P. J., Tashiro, C. H. M., McIllveen, W. D., and Clement, R. E., "PCDD and

PCDF in Air, Soil, Vegetation and Oily Runoff from a Tire Fire", Water, Air and

Soil Pollution, 82, 659-674, 1995.

97. Thompson, T. S., Kolic, T. M., Townsend, J. A., and Mercer, R. S.,

"Determination of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Tire Fire Runoff Oil", Journal of Chromatography, 648, 613-219, 1993.

98. Lemieux, P. M., and DeMarini, D., "Mutagenicity of Emissions from the

Simulated Open Burning of Scrap Rubber Tires", U.S. Environmental Protection Agency, Control Technology Center, office of Research and Development, EPA- 600/R-92-127, 1992.

99. Lemieux, P. M., and Ryan, J. V., "Characterization of Air Pollutants Emitted

from a Simulated Scrap Tire Fire", Journal of the Air & Waste Management

Association, 43, 1106-1115, 1993.

100. Lemieux, P. M., Lutes, C. C., and Santoianni, D. A., "Emissions of organic air

toxics from open burning: a comprehensive review", Progress in Energy and

Combustion Science, 30, 1-32, 2004.

101. Büthe, N., "Combustion effluents of rubber",

http://www.buethe.onlinehome.de/research.htm.

102. Conesa, J. A., Martín-Gullón, I., Font, R., and Jauhiainen, J., "Complete Study of

the Pyrolysis and Gsification of Scrap Tires in a Pilot Plant Reactor",

Environmental Science & Technology, 38, 3189-3194, 2004.

103. Blomqvist, P., Rosell, L., and Simonson, M., "Emissions from Fires Part I: Fire

Retarded and Non-Fire Retarded TV-Sets", Fire Technology, 40, 39-58, 2004.

104. Grayson, S. J., van Hees, P., Vercellotti, U., Breulet, H., and Green, A., Fire

Performance of Electric Cables - new test methods and measurement techniques,

Final Report on the European Commission SMT Programme Sponsored Research Project SMT4-CT96-2059, Interscience Communications Limited, 2000.

105. Simonson, M., Andersson, P., Rosell, L., Emanuelsson, V., and Stripple, H.,

"Fire-LCA Model: Cables Case Study", SP Swedish National Testing and Research Institutes, SP REPORT 2001:22, Borås, Sweden, 2001.

106. Axelsson, J., van Hees, P., and Blomqvist, P., "Cable fires in difficulty acceccible

areas", SP Swedish National Testing and Research Institute, SP REPORT 2002:12, Borås, Sweden, 2002.

107. Noiton, D., Fowles, J., and Davies, h., "The Ecotoxicity of Fire-Water Runoff -

Part II: Analytical Results", New Zealand Fire Service Commission, New Zealand, 2001.

108. Blomqvist, P., Lönnermark, A., and Simonson, M., "Miljöbelastning vid bränder

och andra olyckor - Utvärdering av provtagning och analyser", Räddningsverket, P21-452/04, Karlstad, Sweden, 2004.

109. Wichmann, H., Lorenz, W., and Bahadir, M., "Release of PCDD/F and PAH

during Vehicle Fires in Traffic Tunnels", Chemosphere, 31, 2, 2755-2766, 1995.

110. Peterson, K. E., and Markert, F., "Assessment of Fires in Chemical Warehouses -

An Overview of the TOXFIRE Project", Risø National Laboratory, Risø-R- 932(EN), Roskilde, Denmark, 1999.

111. Månsson, M., Lönnermark, A., Blomqvist, P., Persson, H., and Babrauskas, V.,

Large-scale Combustion Experiments", SP Swedish National Testing and Research Institute, SP REPORT 1996:44, Borås, Sweden, 1998.

112. Jørgensen, K. H., and Smith-Hansen, L., "TOXFIRE - Flash Pyrolysis and DIN

53 436 Experiments", Risø National Laboratory, Risø-R-765(EN), Roskilde, Denmark, 1995.

113. Smith-Hansen, L., "Toxic Haxards from Chemical Warehouse Fires", Risø

National Laboratory, Risø-R-713(EN), Roskilde, Denmark, 1994.

114. Battye, W., and Battye, R., "Development of Emissions Inventory Methods for

Wildland Fire", U.S. Environmental Protection Agency, Final Report, EPA Contract No. 68-D-98-046, North Carolina, USA, 2002.

115. Yokelson, R. J., Griffith, D. W. T., and Ward, D. E., "Open-path Fourier

transform infrared studies of large-scale laboratory biomass fires", Journal of

Geophysical Research, 101, D15, 21,067-21,080, 1996.

116. Yokelson, R. J., Susott, R., Ward, D. E., Reardon, J., and Griffith, D. W. T.,

"Emissions from smoldering combustion of biomas measured by open-path Fuorier transform infrared spectroscopy", Journal of Geophysical Research, 102, D15, 18,865-18,877, 1997.

117. Goode, J. G., Yokelson, R. J., Susott, R. A., and Ward, D. E., "Trace gas

emissions from laboratory biomass fires measured by open-path Fourier transform infrared spectroscopy: Fires in grass and surface fuels", Journal of

Geophysical Research, 104, D17, 21,237-21,245, 1999.

118. Yokelson, R. J., Goode, J. G., Ward, D. E., Susott, R. A., Babbitt, R. E., Wade,

D. D., Bertschi, I., Griffith, D. W. T., and Hao, W. M., "Emissions of

formaldehyde, acetic acid, methanol, and other trace gases from biomass fires in North Carolina measured by airborne Fourier transform infrared spectrascopy",

Journal of Geophysical Research, 104, D23, 30,109-30,125, 1999.

119. Goode, J. G., Yokelson, R. J., Ward, D. E., Susott, R. A., Babbitt, R. E., Davies,

M. A., and Hao, W. M., "Measurements of excess O3, CO2, CO, CH4, C2H4, C2H2, HCN, NO, NH3, HCOOH, CH3COOH, HCHO, and CH3OH in 1997 Alaskan biomass burning plumes by airborne Fourier transform infrared spectroscopy (AFTIR)", Journal of Geophysical Research, 105, D17, 22,147- 22,166, 2000.

120. Mason, S. A., Field, R. J., Yokelson, R. J., Kochivar, M. A., Tinsley, M. R.,

Ward, D. E., and Hao, W. M., "Complex effects arising in smoke plume simulations due to inclusion of direct emissions of oxygenated organic species from biomass combustion", Journal of Geophysical Research, 106, D12, 12,527- 12,539, 2001.

121. Hao, W. M., Ward, D. E., Olbu, G., and Baker, S. P., "Emissions of CO2, CO,

and hydrocarbons from fires in diverse African savanna ecosystems", Journal of

Geophysical Research, 101, D19, 23,577-23,584, 1996.

122. Yamasoe, M. A., Artaxo, P., Miguel, A. H., and Allen, A. G., "Chemical

composition of aerosol particles from direct emissions of vegetation fires in the Amazon Basin: water-soluble species and trace elements", Atmospheric

Environment, 34, 1641-1653, 2000.

123. Notarianni, K. A., Evans, D. D., and Walton, W., D., "Smoke Production from

Large Oil Pool Fires", Interflam '93 - Sixth International Fire Conference, 111- 119, Oxford, England, 30 March - 1 April, 1993.

124. Booher, L. E., and Janke, B., "Air Emissions from Petroleum Hydrocarbon Fires

During Controlled Burning", American Industrial Hygiene Association Journal, 58, May, 359-365, 1997.

125. Wooley, W. D., and Fardell, P. J., "Basic Aspects of Combustion Toxicology",

Fire Safety Journal, 5, 29-48, 1982.

126. Lönnermark, A., "On the Characteristics of Fires in Tunnels", Doctoral Thesis,

127. ISO TR 9122-1, "Toxicity testing of fire effluents - Part 1: General", First ed., 1989-11-15, ISO, 1989.

128. Andersson, B., Babrauskas, V., Holmstedt, G., Särdqvist, S., and Winter, G.,

"Simulated Fires in Substances of Pesticide Type", Department of Fire Safety Engineering, Lund Univertsity, Report 3087, Lund, Sweden, 1999.

129. Levendis, Y. A., Atal, A., Carlson, J., Dunayevskiy, Y., and Vouros, P.,

"Comparative Study on the Combustion and Emissions of Waste Tire Crumb and Pulverized Coal", Environmental Science & Technology, 30, 2742-2754, 1996.

130. Atal, A., Levendis, Y. A., Carlson, J., Dunayevskiy, Y., and Vouros, P., "On the

Survivability and Pyrosynthesis of PAH During Combustion of Pulverized Coal and Tire Crumb", Combustion and Flame, 110, 462-478, 1997.

131. Levendis, Y. A., Atal, A., and Carlson, J. B., "On the Correlation of CO and PAH

Emissions from the Combustion of Pulverized Coal and Waste Tires",

Environmental Science & Technology, 32, 3767-3777, 1998.

132. Tolocka, M. P., Richardson, P. B., and Miller, J. H., "The Effect of Global

Equivalence Ratio and Postflame Temperature on the Composition of Emissions from Laminar Ethylene/Air Diffusion Flames", Combustion and Flame, 118, 521-536, 1999.

133. McGrath, T. E., Chan, W. G., and Hajaligol, M. R., "Low temperature

mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose", Journal of Analytical and Applied Pyrolysis, 66, 51-70,

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