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Photoconductivity of bulk and liquid processed MoS2

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Photoconductivity of bulk and liquid processed MoS

2

Viviane Alecrim, Magnus Hummelgård, Renyun Zhang, Henrik Andersson,

Mattias Andersson and Håkan Olin

Mid Sweden University, Sundsvall, Holmgatan 10, 85170, Sweden.     

E-mail: viviane.alecrim@miun.se

Molybnenium Dissulfide, a transition metal dichalcogenide has been the focus of inumerous publications1–3 recently mainly due to the success of graphene4,5 and the increase interest on other 2D materials, proving that dimentionability plays a significant role on the materials properties. Besides, the absence of a bandgap in graphene makes MoS2 particularly interesting as it is an abundant and natural occurring n-type semiconductor.

Back in the 70’s Tributsch was the pioneer to exploit MoS2 electrodes for solar cells applications6,7 but back them the technology to achieve thin layers of the material was not as evolved as it is to date8–10. Nevertheless, limitations of scalability due to expensive or low yield manufacturing methods justify the focus of the present study. In the photoconductivity experiments we measured thickness and wavelength dependency of the material. Light sources were a halogen lamp together with a monochromator. Two types of samples were tested: MoS2 deposited on glass or pressed into pills both with gold contacting electrodes. Both these methods are scaleable. Results show that molybdenum disulfide is photoconducting.

References:

1. Mak, K. F., Lee, C., Hone, J., Shan, J. & Heinz, T. F. Atomically Thin MoS2: A New Direct-Gap Semiconductor. Phys. Rev. Lett. 105, 136805 (2010).

2. Chhowalla, M. et al. The chemistry of two-dimensional layered transition metal dichalcogenide

nanosheets. Nat. Chem. 5 (4), 263–275 (2013).

3. Wang, Q. H.. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

Nat. Nanotechnol. 7(11), 699–712 (2012).

4. Geim, A. K. & Novoselov, K. S. The rise of graphene. Nat. Mater. 6, 183–191 (2007).

5. Castro Neto, A. H., Peres, N. M. R., Novoselov, K. S. & Geim, A. K. The electronic properties of graphene. Rev. Mod. Phys. 81, 109–162 (2009).

6. Tributsch, H. Layer-Type Transition Metal Dichalcogenides - a New Class of Electrodes for Electrochemical Solar Cells. Berichte der Bunsengesellschaft für Phys. Chemie 81, 361–369 (1977). 7. Tributsch, H. Photoelectrochemical behaviour of layer-type transition metal dichalcogenides.

Faraday Discuss. Chem. Soc. 70, 189 (1980).

8. Furchi, M. M., Polyushkin, D. K., Pospischil, A. & Mueller, T. Mechanisms of photoconductivity in atomically thin MoS2. 22 (2014). at <http://arxiv.org/abs/1406.5640>

9. Gourmelon, E. et al. MS2 (M = W, Mo) photosensitive thin films for solar cells. Sol. Energy Mater. Sol. Cells 46, 115–121 (1997).

10. Cunningham, G. et al. Photoconductivity of solution-processed MoS2 films. J. Mater. Chem. C 1,

6899–6904 (2013).  

References

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