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Health and Sustainable Agriculture

Editors: Leif Norrgren and Jeffrey M. Levengood

Ecology and Animal Health

2

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Introduction

For a very long time, sediments only came to attention when their physical presence interfered with the human use of a water body, primarily when a river mouth or har- bour became silted in and too shallow for ships to navi- gate. In those situations, the mud from the bottom of the river was removed, or dredged, and cast to the riverbank to allow for ship traffic to resume. As the Great Lakes basin became industrialised in the 19th century, water bodies became blocked with sediment materials that in- cluded not only the soil particles washing downstream from the surrounding watershed, but also by the physical by-products of tanning, meat packing, steel manufactur- ing, and other industrial operations that introduced their own unique waste materials.

These solid materials were not thought of as pollution, or contaminants, in the same way that we think today of constituents such as PCBs, dioxin, or lead. Instead, the focus of those trying to manage the waterways impacted by these materials was to simply remove the materials and find some other place to dispose of them. Dredging for the maintenance of navigation channels has been practised for hundreds of years, again with the emphasis until recently placed solely on removing solids from the navigable portion of the waterway.

With regard to the maintenance of navigable waterways, a variety of concerns about the environmental effects of

dredging and management of contaminated sediments has been expressed by resource agencies and the public since the 1960s (Miller, 2003). In response to these concerns, the US Congress passed the Rivers and Harbors Act of 1970, which authorised the construction of confined dis- posal facilities, or CDFs, specialised structures to confine the sediments dredged from navigational channels. These CDFs were the first systematic approach to the manage- ment of contaminated sediments in North America, but the sediments themselves were not being managed solely for the purpose of removing them and their associated contaminants from the aquatic ecosystem.

Sediment contamination, and its impact on aquatic ec- osystem, came into greater focus with the identification of several large Superfund sites in the early 1980s, among them the Hudson River, Kalamazoo River, Palos Verde Shelf, Commencement Bay Tidelands, and the Passaic River, all of which were centred on contamination issues in sediments. Each of the sites has been subject to in- tensive study for periods of decades, and remediation of them is estimated to cost billions of dollars.

The US EPA has developed comprehensive guidance for their project managers who are faced with addressing contaminated sediment sites (US EPA, 2005). This sec- tion can only provide a brief glimpse into the very basics of the complexity of managing contaminated sediment sites, which is covered in detail in the US EPA docu- ment. US EPA (2005) contains a very useful discussion

Sediment Management

Stephen Garbaciak Jr.

ARCADIS US, Chicago, IL, USA

32

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of the definition of contaminated sediments and their sources:

‘Contaminated sediment is soil, sand, organic mat- ter, or other minerals that accumulate on the bot- tom of a water body and contain toxic or hazard- ous materials at levels that may adversely affect human health or the environment. Contaminants adsorbed to soil or in other forms may wash from land, be deposited from air, erode from aquatic banks or beds, or form from the underwater break- down or buildup of minerals. Contaminated sedi- ment may be present in wetlands, streams, rivers, lakes, reservoirs, harbors, along ocean margins, or in other water bodies. Some contaminants have both anthropogenic sources and natural sources.’

The US EPA definition of contaminated sediments is functional, but does not completely illustrate why man- agement of them as an environmental matrix is impor- tant. Fortunately, the guidance goes on to say:

‘Many contaminants persist for years or decades because the contaminant does not degrade or de- grades very slowly in the aquatic environment.

Contaminants sorbed to sediment normally de- velop an equilibrium with the dissolved fraction in the pore water and in the overlying surface water to be taken up by fish and other aquatic organisms. Some bottom-dwelling organisms in- gest contaminated sediment, and in shallow wa- ter environments, humans may also come into direct contact with contaminated sediment. Some contaminants, such as most metals, are hazard- ous primarily because of direct toxicity. Although some metals do accumulate in biota (i.e., bioac- cumulate), generally they do not significantly in- crease in concentration as they are passed up the food chain (i.e., biomagnify). Others, called per- sistent bioaccumulative toxics (PBTs) [e.g., PCBs, pesticides, and methyl mercury] are of concern primarily because they may both bioaccumulate and biomagnify. Concentrations of PBTs in fish may endanger humans and wildlife that eat fish.

Women of childbearing age, young children, peo-

ple who derive much of their diet from fish and shellfish, and people with impaired immune sys- tems may be especially at risk.’

Let us look at how we can determine exactly what kind of problem a contaminated sediment site may present and what we can do to address the problem.

Site Assessment

As we observed with the history of sediment manage- ment, a problem with contaminated sediments can arise in two main ways – either the sediments need to be removed from a water body to provide navigable water depth, and the contaminants they contain make their handling and disposal complex (they cannot be simply cast to the side of the river), or the contaminants present in the sediments themselves present an unacceptable risk to human health or the environment, requiring the risk be managed by re- moving or otherwise managing the sediments.

Before identification of the best management strategy for addressing the contaminated sediment is possible, a thorough understanding of the physical, chemical and geo- technical characteristics of the site must be performed, and a comprehensive assessment of the risks posed by the sedi- ment contaminants is critical. The mere presence of a con- stituent in a sediment matrix does not predetermine a need to manage the site – it is the risk that must be addressed.

The fundamental purpose of the site assessment is to develop a conceptual site model (CSM). The CSM is a representation of an environmental system that is a tool for identifying releases, pathways of migration, potential receptors and the risk posed by the contaminated sedi- ments. Developing a CSM requires the collection of data on contaminant concentrations in sediments, water, soil, and biota. The types of data to be collected from sediment sites include (from US EPA, 2005):

Physical Data

• Sediment particle size distribution

• In situ bulk density

• Specific gravity

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• Bathymetry

• Resuspension rates

• Flood frequencies and velocity distributions Chemical Data

• Contaminant concentrations in surface and deep sedi- ment layers

• Contaminant concentrations in biota tissue, ground- water, surface water and pore water

• Conventional pollutant concentrations, including TOC in sediments and pH in water

• Simultaneously extracted metals and acid volatile sulphides (SEM/AVS) in sediments

• Radiometric dating of sediment core profiles for deposition rate estimates

Biological Data

• Sediment toxicity – acute and chronic

• Human consumption rates of fish and shellfish in the project area

• Abundance/diversity of bottom-dwelling species, fishes, vegetation

• Tumour and abnormality surveys

• Habitat stressors

The data collected are initially used for developing the CSM, establishing the nature and extent of the contami- nants of concern (CoCs), determining whether any sourc- es of CoCs are not yet controlled and could pose a threat to recontaminate the site after remediation, identifying risk pathways through which the CoCs can adversely af- fect human or ecosystem health, and finally for evalu- ating the fate and transport mechanisms that drive these processes.

Ultimately, the CSM must be used to drive an assess- ment of risks posed by the sediment CoCs. Screening and baseline risk assessments are designed to evaluate the potential threat to human health and the environment in the absence of any remedial action(US EPA, 2005). The risk assessment process is key to the overall ability to de- termine whether a sediment site is posing unacceptable risks, and how those risks can be feasibly managed. The risks of implementing possible remedial options should

be considered during the risk assessment, to provide a ba- sis for comparing alternatives.

When risks have been adequately characterised at the site, and a determination has been made by the appropri- ate group of regulators and stakeholders that unacceptable risks are present and they must be managed, the next step is to develop clearly defined remedial action objectives (RAOs). RAOs are typically general in nature, and are used to develop and compare alternatives. They may also lead to the development of contaminant-specific remedia- tion goals (RGs). RGs are generally expressed as numeri- cal values for CoCs in sediments at the site. Examples of RAOs include (from US EPA, 2005):

• Reduce to acceptable levels the risks to adults and children from ingestion of contaminated fish and shellfish taken from the site

• Reduce to acceptable levels the toxicity to benthic aquatic organisms at the site

Remediation Options and Implementation Considerations

The menu of remedial options available to address a con- taminated sediment problem has evolved from the basic choice of how to remove the target sediments from the waterway and where to dispose of the dredged material to a variety of management options that take into considera- tion the natural processes that may work to assist or deter from the achievement of project success.

There are three basic options available for remediating sediments:

Removal

Historically the preferred remedial alternative was to excavate the solids, water and associated contaminants from the bottom of the water body and dispose of them in a seemingly more secure and more readily monitored location. Sediments can be removed through mechani- cal means, where a cable-operated clamshell bucket or hydraulic excavator is used to physically dislodge the sediment from the water body and bring it to the surface.

When the crane or excavator is mounted on a floating

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barge, the process is referred to as dredging; when the equipment is shore-based the term excavation is more typically used. Sediments can also be dredged using hy- draulic methods, where a centrifugal pump is used to suc- tion the sediment solids and water from the water body bottom, sometimes with the additional use of a rotating cutter head at the suction inlet to dislodge the sediment and help introduce the slurry into the pipeline.

In Situ Capping

In many situations the ability to remove the target sedi- ments is difficult, the available options for disposal of the sediments are limited, or the impacts to the surrounding ecosystem from removal are too damaging, leaving it more effective to isolate the contaminated sediments in place by capping them with a layer or layers of clean ma- terial. Caps can be as simple as the placement of a thin lift of silty sand that covers and dilutes the surface concen- trations of the contaminants of concern or as complex as multiple layers of geotextile, sand, silts and large armour stone to resist erosive forces and ensure the cap and the underlying target sediments remain in place.

Monitored Natural Recovery

Although it is the most recently-accepted major category of contaminated sediment management techniques, all projects should consider the natural forces acting on a con- taminated sediment site to determine whether the remedial goals set for the site will be achieved with little or no hu- man intervention. Monitored natural recovery (MNR) uti- lises the processes of deposition, resuspension, transport, attenuation, biodegradation and volatilisation to reduce the concentrations of constituents of concern in the surface sediments to acceptable levels in a reasonable time frame.

The identification of an appropriate remedial alterna- tive, or combination of alternatives, must consider all components of the process. Sediment management be- gins with the consideration of the main technological ap- proach – determining the ramifications of that decision involves the consideration of dredged material transport, final disposal locations, the need for the placement of re- sidual capping materials, etc. Let us consider the main purposes of the three major remediation approaches, the site conditions that are most conducive to their imple- mentation, and their advantages.

Monitored Natural Recovery

Monitored natural recovery (MNR) relies on multiple naturally-occurring processes to reduce the risk posed by contaminated sediments to acceptable levels with little or no human intervention. According to US EPA (2005), the following are the different processes listed in order from most to least preferable:

• The contaminant is converted to a less toxic form through transformation processes, such as biodegra- dation or abiotic transformations

• Contaminant mobility and bioavailability are reduced through sorption or other processes binding contami- nants to the sediment matrix

• Exposure levels are reduced by a decrease in con- taminant concentration levels in the near-surface sediment zone through burial or mixing-in-place with cleaner sediment

• Exposure levels are reduced by a decrease in con- taminant concentration levels in the near-surface sediment zone through dispersion of particle-bound contaminants or diffusive or advective transport of contaminants to the water column

Site conditions that are particularly suitable for consid- eration of MNR as a remedial alternative include (from US EPA, 2005):

• Natural recovery processes have a reasonable degree of certainty to continue at rates that will contain, destroy, or reduce the bioavailability or toxicity of contaminants within an acceptable time frame

• Expected human exposure is low or can be reason- ably controlled by institutional controls

• Contaminant concentrations in biota and in the bio- logically active zone of sediment are moving towards risk-based goals on their own

• Contaminants are readily biodegradable or transform to lower toxicity forms

• Contaminant concentrations are low and cover large areas

The primary advantage of MNR is:

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• Little or no need for direct human intervention and disturbance

The disadvantages of MNR include:

• Contaminants are left in place at unacceptable levels for some period of time

• Burial-based risk reduction processes may be upset by unexpected strong forces

• Higher level of uncertainty in the prediction of reme- dial success

Capping

Caps are intended to reduce risk through the following primary functions xxi:

• Physical isolation of the contaminated sediment suf- ficient to reduce exposure due to direct contact and to reduce the ability of burrowing organisms to move contaminants to the surface

• Stabilisation of contaminated sediment and erosion protection of sediment and cap, sufficient to reduce resuspension and transport to other sites

• Chemical isolation of contaminated sediment suffi- cient to reduce exposure from dissolved and colloi- dally bound contaminants transported into the water column

There are certain site conditions that are particularly con- ducive to in situ capping and, if present, capping should receive detailed consideration as a remedial option for the site (from US EPA, 2005):

• Suitable types and quantities of cap material are read- ily available

• Water depth is adequate to accommodate the cap with anticipated uses (e.g. navigation)

• Incidence of cap-disturbing human behaviour, such as boat anchoring, is low or controllable

• Habitat improvements are provided by the cap

• Rates of groundwater flow in the cap area are low or not likely to create unacceptable contaminant releases through the cap

• Contamination covers contiguous areas The advantages of capping include:

• Rapid reduction of risk posed by concentrations of CoCs in surface sediments

• Minimal or beneficial changes in site bathymetry

• No need to transport and dispose of dredged material

• Lower potential for release and transport of CoCs during remedial activities

The disadvantages of capping include:

• Leaves CoC-containing sediments in the water body

• Prevents future dredging for navigation or other pur- poses

• Inevitable contaminant breakthrough

• Reduction in hydraulic carrying capacity possibly leading to changes in flood stage

Dredging

Palermo et al. (2008) define environmental dredging as

‘the removal of contaminated sediments from a water body for purpose of sediment remediation’ and go on to define the objectives of an environmental dredging op- eration to normally include:

• Dredge with sufficient accuracy such that contaminat- ed sediment is removed and sediment clean-up levels are met without excessive removal of clean sediment

• Dredge the sediment in a reasonable period of time and in a condition compatible with subsequent trans- port for treatment or disposal

• Reduce and/or control resuspension of contaminated sediments, downstream transport of re-suspended sediments, and releases of CoCs to water and air

• Dredge the sediments such that generation of residu- als is reduced and/or controlled

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Site conditions conducive to dredging include from US EPA, 2005):

• Suitable disposal site is available and easily reached by preferred transportation method

• Suitable area is available for staging and handling of dredged material

• Navigation dredging in the project area is scheduled or planned

• Adequate water depth to accommodate dredge

• Water diversion to facilitate excavation in dry condi- tions is practical

• Contaminated sediments to be removed are underlain by clean sediments, to allow for over-dredging

• High contaminant concentrations are located in rela- tively small areas and volumes

The advantages of dredging include:

• Permanent removal of CoCs from the water body

• Increased flexibility of future uses of the water body

• Rapid achievement of RAOs when residual concen- trations are low

Disadvantages of dredging include:

• Need for transportation, dewatering, re-handling and disposal of dredged material

• Inability of dredging techniques to remove all sedi- ments and associated CoCs

• Loss of CoCs during remediation resulting in down- stream contamination

The information presented above is but the briefest sum- mary of the three fundamental remedial options for con- taminated sediment. Each of them is a subject worthy of exploration and detailed discussion in their own chapter, or complete textbook. Beyond these three fundamental options, consideration must be given to several additional components of the sediment remediation process to en- sure that the most efficient, effective and least-cost option is selected for the site being managed. These additional components include:

• Dredged material transportation method – the methods available for transporting dredged material from the water body to the processing or disposal site depend on the dredging method. Mechanical dredges typically utilise barges or scows to move the material from the dredge to a shore-based offloading location where they are unloaded and the materials are further processed to remove excess water, or discharged directly to the disposal facility. Hydraulic dredges typically pump the dredged material in a slurry form through a pipeline directly to the offloading or disposal location. The distance to the disposal facility, and the ability of that facility to accept dredged mate- rial without additional processing, are key considera- tions in the selection of the dredging and dredged material transport method.

• Dredged material processing requirements – the facility where the dredged material will be disposed of will dictate the physical and chemical requirements for the material it can receive. If the disposal facility has been specifically built to accept dredged mate- rial, very little processing if any may be required, and direct disposal of the mechanically or hydraulically dredged material is possible. For contaminated sedi- ment remediation projects it is more common that the dredged material will be disposed of in an existing commercial landfill, and those landfills typically set requirements that include the elimination of all free water, plus requirements on the bearing strength of what they consider to be the waste material. Since dredged material is inherently a very wet soil matrix, these requirements by the disposal facility necessitate the removal of water, and often increase in strength, of the dredged material. Dewatering methods can range from the passive use of gravity drainage through the active use of mechanical dewatering techniques such as plate-and-frame filter presses.

Solidification agents such as Portland cement may be added to further reduce moisture contents and increase bearing capacity. Each of these processing steps adds time and cost to the overall project.

• Water treatment requirements – if the dredged mate- rial requires dewatering as described above, the sepa- rated water will very often require treating to remove any of the CoCs in the water. With mechanically

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dredged material being dewatered through gravity drainage, this can be a relatively simple process with low treatment flow rates. However, careful considera- tion must be given to the water treatment needs of a dredged material slurry generated from hydraulically dredged material, where the total volume of water requiring treatment can be 20 times the volume of in situ sediments being removed from the waterway.

• Sediment treatment requirements – in addition to the removal and subsequent treatment of water from the dredged material, certain CoCs may need to be re- moved, or their concentrations reduced in the dredged material matrix before they can be disposed at a land- fill. There are many chemical, physical, biological and thermal technologies available to destroy, extract or reduce the concentration of these target CoCs.

These technologies may require further processing of the dredged material in order to render it suitable for treatment. These technologies all add significant additional time and cost to the overall project, and those factors must be weighed against the benefit of the reduction or elimination of the target CoC from the waste material.

Measuring Success

The final step in the sediment management process is to develop and implement a monitoring programme that will not only measure the short-term impacts and benefits of the management approach, but will provide long-term data to determine whether the project has achieved the remedial goals set for it, i.e. has reduced the risk posed by the contaminated sediments.

US EPA (2005) identifies the key points that must be considered when monitoring the success of a sediment remediation project:

• Presentation of a monitoring plan is important for all types of sediment remedies, both during and follow- ing any physical construction, to ensure that exposure pathways and risks have been adequately managed

• Development of monitoring plans should follow a systematic planning process that identifies monitoring

objectives, decision criteria, endpoints and data col- lection, and data interpretation methods

• Before implementing a remedial action, project managers should determine if adequate baseline data exists for comparison to future monitoring data and, if not, collect additional data

• Where background conditions may be changing or where uncertainty exists concerning continuing off- site contaminant contributions to a site, it may be nec- essary to continue collecting data from upstream or other reference areas for comparison to site monitor- ing data

• Monitoring needs include both monitoring of con- struction and operation and monitoring intended to measure whether clean-up levels in sediment and remedial action objectives for biota or other media have been met

• Monitoring plans should be designed to evaluate whether performance standards of the remedial action are being met and should be flexible enough to allow revision if operating procedures are revised

• Field measurement methods and quick turnaround analysis methods with real-time feedback are espe- cially useful during capping and dredging operations to identify potential problems which may be cor- rected as the work progresses

• After completion of remedial action, long-term moni- toring should be used to identify recontamination, to assess continued containment of buried or capped contaminants, and to monitor dredging residuals and on-site disposal facilities

Conclusions

Sediment management is a continually evolving and ad- vancing combination of science, engineering and art. It is a very young practice as the very oldest sites where contaminated sediments were actively remediated are not even 40 years old, and few examples of in situ capping are over 20 years old. As time passes, we are expand- ing our understanding of which techniques are most ef- fective, which do not appear to work well, and what im- provements can be made to reduce the impacts and costs

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of implementation while maximising the net benefits to the environment.

The reader is strongly encouraged to consult the refer- ences for further details on the specific aspects of their unique sediment management project.

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Further Reading:

Lorenz, M.G. and Wackernagel, W. 1987. Adsorption of DNA to sand and variable degradation rates of adsorbed DNA. In: Appl. Environ.

Microbiol. 53: 2948-2952

Chapter 30

Baun, A., Jensen, S.D., Bjerg, P.L., Christensen, T.H. and Nyholm, N. 2000. Toxicity of organic chemical pollution in groundwater down gradient of a landfill (Grindsted, Denmark). In: Environ. Sci.

Technol. 34, pp.1647-1652.

European Commission, 1998. Environment: Drinking Water Directive.

http://ec.europa.eu/environment/water/water-drink/index_en.html European Landfill Directive (Council Directive 99/31/EC) which came

into force on 16.07.1999 (http://ec.europa.eu/environment/waste/

landfill_index.htm)

Johnson, P.C. and Ettinger, R.A. 1991. Heuristic model for predicting the intrusion rate of contaminant vapors in buildings. In: Environ.

Sci. Technol. 25: 1445-1452.

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Kurian, J., Esakku, S., Nagendran, R. and Visvanathan, C. 2005. A deci- sion making tool for dumpsite rehabilitation in developing countries.

In: Proc Sardinia 2005, Tenth Int’l Wasst Management and Landfill Symposium, Environmental Sanitary Engineering Centre, Italy.

LandSim. http://www.landsim.co.uk

Lee, G.F. and Jones-Lee, A. 1994. A groundwater protection strategy for lined landfills. In: Environ. Sci. Technol. 28, pp.584A – 585A.

Mackay, D. and Mackay, N. 2007. Mathematical models of chemical transport and fate. In: Suter II., G.W. Ecological Risk Assessment (2nd ed). CRC Press, Boca Raton, FL. Pp.217 -241.

Salvato, J.A., et al. 1971. Sanitary landfill-leaching prevention and control. In: Journal Water Pollution Control Federation, 43(10), pp:2084-2100.

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US EPA, 2007. Sediment toxicity identification evaluation (TIE).

Washington DC: EPA, Office of Research and Development, EPA/600/R-07/080. 145pp.

US EPA, 2010. National Recommended Water Quality Criteria. http://

water.epa.gov/scitech/swguidance/waterquality/standards/criteria/

index.cfm

US EPA, 2011a. Ground Water and Ecosystems Restoration Research:

Center for Subsurface Modeling Support. http://www.epa.gov/nrm- rl/gwerd/csmos/index.html

US EPA, 2011b. Drinking Water Contaminants: National Primary Drinking Water Regulations. http://www.epa.gov/safewater/con- taminants/index.html

US EPA, 2011c. Integrated Risk Information System (IRIS). http://

www.epa.gov/iris/

Chapter 31

Bierma, T.J. and Waterstraat, F.L. 1997. Innovative chemical supply contracts: A source of competitive advantage. WMRC Reports, TR- 31, Champaign, IL.

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Further Reading:

GLRPPR, Great Lakes Regional Pollution Prevention Roundtable Sector Resources – Metal Fabrication. http://www.glrppr.org/con- tacts/gltopichub.cfm?sectorid=46 (Retrieved 2011-10-26) Metal Fabrication & Machining Topic Hub. http://www.newmoa.org/

prevention/topichub/toc.cfm?hub=23&subsec=7&nav=7 (Retrieved 2011-10-26)

Primary Metals Pollution Prevention Notebook. Industry: A Manual for Technical Assistance Providers. http://www.wmrc.uiuc.edu/main_

sections/info_services/library_docs/manuals/primmetals/intro1.htm (Retrieved 2011-10-26)

USEPA Effluent Guidelines: Metal Products and Machinery: Final Rule Development Document http://www.epa.gov/waterscience/

guide/mpm/tdd/index.htm. Sections 8-9 cover Pollution Prevention and Wastewater Treatment Technologies and Technology Options.

USEPA Sector Notebook: Profile of the Metal Fabrication Industry.

http://www.epa.gov/compliance/resources/publications/assistance/

sectors/notebooks/fabric.html (Retrieved 2011-10-26)

Chapter 32

Miller, J, editor. 2003. Great Lakes Confined Disposal Facilities.

Buffalo NY: USACE/USEPA.

Palermo, M, P Schroeder, T Estes and N Francingues. 2008. Technical Guidelines for Environmental Dredging of Contaminated Sediments.

EL TR-08-20. Vicksburg MS: USACE ERDC.

USEPA, 2005. Contaminated Sediment Remediation Guidance for Hazardous Waste Sites. OSWER 9355.0-85. Washington DC:

USEPA.

Further Reading:

Davis, J, T Dekker, M Erickson, V Magar, C Patmont, and M Swindoll.

2003. Framework for evaluating the effectiveness of monitored

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natural recovery (MNR) as a contaminated sediment manage- ment option. In: Proceedings: 2nd International Conference on Remediation of Contaminated Sediments, Venice Italy (September 30, 2003). Columbus OH: Battelle.

National Research Council, Committee on Sediment Dredging at Superfund Megasites. 2007. Sediment Dredging at Superfund Megasites: Assessing the Effectiveness. Washington DC: The National Academies Press.

USEPA. 1994. Assessment and Remediation of Contaminated Sediments (ARCS) Program Remediation Guidance Document. EPA/905/R- 94/003. Chicago IL: USEPA.

USEPA. 1996. Estimating Contaminant Losses from Components of Remediation Alternatives for Contaminated Sediments. EPA/905/R- 96/001. Chicago IL: USEPA.

USEPA. 1998. Assessment and Remediation of Contaminated Sediments (ARCS) Program Guidance for In-Situ Subaqueous Capping of Contaminated Sediments. EPA/905/B-96/004. Chicago IL: USEPA.

USEPA. 2001. Methods for Collection, Storage and Manipulation of Sediments for Chemical and Toxicological Analyses: Technical Manual. EPA 823-B-01-002. Washington DC: USEPA.

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EPA842-B-92-008. Washington DC: USEPA/USACE.

Chapter 33

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Chapter 34

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References

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