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BIBLIOGRAPHY ON INVERT SUGAR

(TO JUNE 1951)

I Acid Inversion

l, Commercial invert sugar. Its manufacture and uses. S. Jordan. Ind. Eng. Chem. 16, 307-10 (1924).--C.A. 18, 1061.

-

-2, Standardized inversion of cane or beet sugar gives best results with pH ,.control. A. A. Schaal and Otto Johnson. Biscuit and Cracker Mfrs. Assoc.,

Minneapolis. Food Industries!, 266-9(1929).--C.A. 23, 3120.

3, The laws of sugar inversion; effect of the concentration of the medium. H. Colin. Chimie & industrie Special No., 796-8(March, 1931).--C.A. 25,4432 •

..

4.

The rate of hydrolysis of sucrose by a strong acid is accelerated by addn. of a neutral salt of the same acid. H. Colin and A. Chaudun, Bull. assoc. chim. suer. dist.~, 369-74(1931).--C.A. 26, 2337.

5.

Acid inversion of sucrose in the presence of neutral salts. A. Colin and A. Chaudun. Bull. assoc. chim. suer. dist. 49, 365-70(1932),--C.A. 27, 4120. 6. Influence of neutral salts on the acid inversion of sucrose. H. Colin and A.

Chaudun. Compt. rend. 194, 1074-6(1932).-- 26, 3131.

7.

Inversion of surcose in sirup manufacture.

c.

A. Coppin. Barbados Agr. J.

!,

No. l, 37-40(1932),--C.A. 27, 4711.

8. The production of inverted sirups. J.

c.

Gonzalez Maiz. 6th Conf. Assoc. Sugar Technologists Cuba 1932; Sugar Abstracts {in Facts About Sugar) 28,97. --C.A. 27, 4712.

-9, Production of inverted (cane) sirups. R. E. Diago and M.A. Mascaro. Proc. Cuban Sugar Tech. Assoc. 10, 101-8(1936).--C.A. 31, 72784.

10. Probable yield and efficiency of the manufacture of inverted sirup. F. A. Lopez Ferrer. Mem. 15th conf. annual, Asoc, tecazucar. Cuba 1941,

201-4.--9

-C.A. 36, 3383. •

11 .. Inversion of cane sugar by tartaric acid. Dharm Singh, Kisben Lal and Chetan Anand. Proc. 15th Indian Sci. Congr. 1928, 174.--C.A. 25, 3507 •

. 12. The velocity of the inversion of sucrose by tartaric, citric, and phosphoric acids. Francisco Joao Maffei, Anais. assoc. quim. Brasil

7,

98-105(1948).--C.A.

!±].,

4503d. Abstr. in Intern. Sugar J. 52, 136(1950)~

13. Inversion of sucrose by various organic acids, Eiziro Hamaguti, Tosihide Simizu and Tokuhir~ Niinuma. J. Soc. Trop. Agr., Taihoku :Imp. Univ. 11, 300• 8(1939).--~ 7131.

14. The manufacture of invert sirup from surplus cane. Colin

w.

Waddell. Sugar News 16, 337-41(1935).--C,A, 29, 67852 •

(2)

15.

The invers:I.on problem in sugar mfg. F. G. Stadler. Archief. deel III, :

Mededeelingen 1931 No. 18, 689-722; good abstract - Int'l Sug. J. 34, 273

(1932).

-16. Sucrose 1.nversion in cgemical production. K, Sandera. Chem. Obzor 18, 178-81 (1943),--C.A. 39, 2002,

17. Invert sugar sirup. W, Reicher. Gaz. Cukrownicza

69,

49-57(1931).--C.A. 27,

621..

18.

19.

20.

21.

Inversion of sugar solutions. Hanz Karow. Destillateur u.

4Likorfabrikant 52, 613-1~·(1939) Chem, Zentr. 1939,II, 1983.--C.A. 35, 4151 •

Critical examination of the Osborn and Zisch method of acid

7inversion. M. Puliga. Ind. saccar. ital. 34, 229-36(1941) .--C.A. 35, 8338 .

Sucrose inversion in cane juice un~er the influence of different conditions of acidity ( sulfur dioxia.e) and temperature. Alejandro S. Alvarez. Rev.

ind. agr, Tucuman 32, 142-4(1942).--C,A, 37, 22073,

The inversion of sugar-beet juice by means of sulfu

3

ic acid, Martraire.

Bull, assoc. chim, 5i, 929-50 (1938).--C.A. 33,5219.

22. The acid inversion of sucrose. Frantisek Kastner. Listy Cukrovar §4, 201-3 (1948),--C.A. 42, 6559c,

23. Some observations on the acid inversion of sucrose. Theo R. Freeman (Florida Agr. Expt. Sta., Gainesville}, J. Dairy Sci. 29,101-13(19t~6) .--Florida Agr. Expt. Sta, Press Bull. 615,4pp.(1945);--C.A. Ii-0,26629;Abst. in Int'! Nat'l

Sugar J. 49,192-3(19!r"()-. -

-24. The inversion of sucrose. Eric Humphriss. Food Manuf. 15, 161-2(194

0).--C .A, )..~,6117'.9,

25. Invert-sugar types. A comparison of available sup

7

lies. K,E, Langwill. Mfg.

Confectioner 19, No, 3, 18 .. 9 (1939). C.A. 33,4449 .

26. Blending and distributing liquid sugar for all users. Ziemba, J.V. Food

Industries

_g~,

366-9 ,lJ.98-502(1948). 27.

28.

The inversion of sugar in the preparation of fruit preserves. S. Berlingozzi

and M, Liquori. Ann. chim. applicata 2~, 501-21(1930).--C.A. 25,1295,

Liquid sugar in food products. W.R,Junk, 0,M.Nelson, and M.H.Sherrill (Calif.

and Hawaiian Sugar Refining Co., Ltd., San Francisco). Food Technol. 1,

506-18(1947) .--C.A. 42,3872e.

-II Invertase Inversion

1. Comparison of the invertase and hydrochloric acid in

3

ersion methods. C,G,

Lemoncito. Philippine Agr. 23, 723-5(1935),--30,4036,

2, Inversion of sucrose solutions. J.J. Willaman. Sugar 28,

(3)

4.

- 3

Inversion of sucrose by invertase at low temperatures. Joslyn, M.A. &

Sherrill, M. Preliminary report. Ind. & Eng. Chem. 25, no.4, 416-17(1933)•

Inversion of sucrose in concentrated solutions and in marzipan pastes by means of technical invertase preparations. O. Spengler aud R. Weidenhagen.

z.

Ver. deut. Zuckerind. 84, 218-27(1934).--c.A. 28, 7577 •

-

-The inversion coefficient aGcording to Clerget, compared with diastatic

inversion. F..mile Saillard. Mon. prod. chim. 12, No. 128, 9-12(1929); Chem.

Zentr, 1930,

I,

2809.--c.A. 25, 4732.

-6.

The Clerget formula for inversion by ~iastase. G.G. Kindt. Ind. saccar,

ital. 28, 571-4(1935).--c.A. 30, 3267 •

-

-7.

The effects of some inorganic and organic salts on the hydrolysis of

sucrose by invertase. Florencio A. Soliven and Alfredo

u.

Agdeppa.

Philippine Agr. 27, 43-51 (1938).--c.A. 33, 42802~

8. Sucrose inversion catalyzed by invertase as a function of tem\erature.

Irwi~

w.

Sizer. Enzymologia

g,

215-21(1938);cf. C.A. ~, 8454 .--C.A. 32,

9101,

9.

Enzymes, variations of pH, and the amino acids of inverted sirups. J.J.

Lima Romero. ~em. 14th conf. anual, Asoc. tee. azucar. Cuba 1940,

305-8.--C.A.

J.2.,

5741 •

1, Specific rotation of invert sugar and the Clerget divisor.

F.

w.

Zerban.

J. Am, Chem, Soc. 47, 1104-11(1925).--C.A. 19, 1788.

2,

A rapid method for the detn. of invert sugar in white refined sugars.

H.c.s.

Whalley.

8 Bull, assoc. chim.

22,,

147-8 (1938).--see C,A. 31,7277~.-C,A.

32, 3650

-3. Refractive indexes of invert sugar solutions and the correction factor of de

Whalley•{• W. Zerban, J. Assoc, Official Agr. Chem. 26, 143-50 (1943). C,A.

,ll, 3294 •

-4.

Refractive indexes of dextrose and invert sugar solutions. Zerban, F.

w.

and

Mart

7

n, J. J. Assoc. Official Agr. Chem. 27, 295-3og(19!1-4); cf. C.A. 37,

3294 ,--C.A. 3~,44671•

-5,

Determination of invert sugar. K. Xiezopols~i and M. Cichocki, Jr. Gaz.

Cukrownicza 83, 88-92 (1938).--c.A •

.21,

1983.

6.

Application of conductometric methods in controlling sugar inversion.

Benigno R. Arguelles. Proc.

613th Ann. Conf., Asoc. tee. azucareros Cuba

1939, 195-9.--C.A •

.Ji,

8321.

7,

·chemical control in the manufacture of inverted sirups. F.A. Lopez Ferrer.

Mero. 14th conf. anual, Asoc. tee. azucar. Cuba 1940, 295-301,--C.A. 35,574L9.

8.

Saturation relations in mixtures of sucrose, dextrose and levulose. Jackson,

(4)

(June 1924). T 259,

9. Errors of Munson-Walker's reducing sugar tables and the precision of their

method. R.F. Jackson and E. J. McDonald. B. of

s.

J. Research 27, (Sept. 1941) RP 1417.

10. The normal wt. of invert sugar and a test of Vasburgh's rule. R, F.

Jackson and E. J.fcDonald. J. Assgc, Official Agr. Chem. 25, 675-80 (1942),

cf. C.A. 33, 9032 .--C.A. 36, 6832,

11. Study of Ofner's method for the determination of invert sugar. E. J.

McDonald & A. L. Turcotte. National Bureau of Standards Research Paper RP 1757, J. Research Nat'l Bureau of Standards 37, 429-34 (1946).

12. Further studies on Ofner's method for the determination of. invert sugar. Emma J. McDonald and Anne L. Turcotte (Natl. Bur. of Standards, Washington,

D.C.). J. Assoc. Official Agr. Chem. 30, 124-30(1947); cf. C.A. 41, 15771.

--C.A. 41, 3643f. --

-13. Invert formation in sucrose solutions. E. J. McDonald, Proc. Tech. Session

Bone Char 1949, 183-97, --C.A, 43, 8714h

J1•• Report on (the analysis of)brewing sugars and sirups.

s.

Laufer. J. Assoc.

Official Agr. Chem. 27, 378 (1944).--c.A. 38,60429.

15. The determination of invert sugar in candy with the polarograph.

r.

Vauruch

and E. Rubes. Listy Cukrovar. 64, 185-9(19!~8) .--C.A. 42,4690e.

16. Rapid determination of percent inversion in inverted sucrose syrups. R, N. Prince. Food Technol. }, 258-9(1949).

IV Theoretical

1. Inhibiting effect of amino acids on the inversion of sucrose by ·H ions.

J, W. L, van Ligten. Arch, Zuckerind. 29, 356-9 (1921).

2. The speed of reaction in concentrated solutions and the mechanism of the

inversion of sucrose. Scatchard, G.I.J. Am, Chem. Soc. 43, 2387-2406

(1921), II.45, 1580-92 (1923),

3. Influence of pectin on,the velocity of inversion of sucrose. Sergio

Berlingozzi ~nd Mario Testoni. Ann. chiw. applicata 25, 489-96(193

5),--C.A. 30,1455 .

4. pH and hydrolyzing power. Andree Chaudun. Bull. assoc. chim. 53, 448-56

(1936).--C.A. 30,47099,

5.

The laws of reaction between cop,P ... r-containing alkaline solutions and invert

sugar and sucrose in the heat. O. Spengler, F, Todt & M, Scheurer. Z,

Wirtschaftsgruppe Zuckerind. 86, 130-46,322-31 (1936).--C,A. 30,58257.

6. The determination of the Clerget divisor under different experimental

con-ditions. O. Spengler, K, Zablinsky and A, Wolf.

z

.

1

wirtschaftsgruppe

(5)

5

V Acid & Alkali Decomposition & Color Products.

1. A technical study on the decomposition of invert sugar by lime. V, Ctyroky.

z.

Zuckerind, cechoslovak. Rep. 51, 230-6(1927); Listy Cukrovar. 4~, 501 ff.

(1925-6) .-- C.A. ?l, 3761.

--2. The action of alkalies upon inverted sugar solutions. F. Stern. Listy

Cukrovar 55, 137-41;

z.

Zuckerind. cechoslovak. Rep. 61,

89-94(1936).---- 9 6887

-C.A. 31, 3727; -C.A. 31, 7 .

3. The decomposition of invert sugar by lime at low temperatures. Bohuslav

Zinnnermann. Listy Cukrovar. 54,489-91(1936).-- C.A. 30, 78937.

4. The color of the decomposition products of invert sugar. I. The influence of alka.lie·s. J.

7vasatko and v. Kasjanov. Listy Cukrovar. 5~, 261-5 (1937). --C. A. 31, 5198.

5, The color of the decomposition products of invert sugar. I, The influence

of alkalinity. J. Vasatko and V. Kasjanov.

z

.

Zuckerind. cechoslovak

Rep. 62, 217-21 (1938).--c.A. 32, 64931,

6. The color of the decomposition products of invert sugar. II. The re-sistance of the decomposition products of invert sugar toward changes in

the reaction of the solution and toward heat. J. Vasatko and

v.

Kasjanov. Listy Cukrovar. 55, 394-6(1937),- c. A. 31, 89741 .

7, The color of the decomposition products of invert sugar. III The influence

of the reaction time and of temperatures upon the chemical changes in alkaline in~ert sugar solutions. J. Va.satko and Kasjanov. Listy Cukrovar. 56, 49-52(1937),--C.A. 32, 3841.

8.

The destruction of the invert sugar by lime. J. Vasatko and M, Markovic.

J. fabr. sucre 78, 720-1 (1937); Chem.·1~,entr. 1938,_!,448.--c.A. 33, 76085. 9, Discoloration of .s~rup.during the acid hyrolysis of starch.

w.

Kroner agd

H. Kothe. Z. Sp1rrtusind. 60, 191, 199, 207-8(1937).-- C. A, 32, 3182.

10. Decomposition of invert sugar by lime. S.

z

.

Ivanov. Trudy Voronezh.

Khim.-Tekh. Inst.

1§~'

35-62 (1939); Khim

8

Referat. ~hur. 1940. No. 7, 119,-

-C,A. 36, 6833 : cf. C. A. 35, 8338

11. Stability of sugars in alkaline and acid solutions: behavior of sucrose and glucose in solutions in pH 4-7; H. S. Chaturvedi and

v.

s.

Kushwaha.

Proc. Sugar Tech. Assoc. India 12,

l,

159-63,--C, A, 3~, 51079.

12. The properties of coloring substances of juices from can sugar factory and their effect on the process of sugar manufacturing. VIII. Alkali de com-position of invert sugar.

8Takeo Yamane. J. Chem. Soc. Japan 64, 400-4

(1943); cf. C. A. 34, 7134 .--C.A. 41, 3644e. X. Ibid. 588-94.-34, 36L~4e

VI. Miscellaneous

1. Relative sweetness of invert sugar. J.

w

.

Sale and W.

w.

Skinner, Ind. Eng.

(6)

6

-2. A method for preparing invert sugar. Anon. Farmatsiya 4, No. 11/12,

16(1941).--A 40% soln. (for injection} of invert sugar Is prepd. from com.

refined sugar, distd. water and HCl.- ·C.A. 38, 2792ts.

3.

Influence of activated carbons on the biological inversion of sucrose

soluUons. A~ostino Amati. Ann. Chim. applicata 28, 487-96(1938)

.--C .A. 33, 2543 •

4.

Inversion of sugar by hydrogen adsorbed on platinized charcoal. B. Bruns and M. Vanyan. J. Phys. Chem. (USSR.)~' 381-4(1930).--c.A. 27, 5571.

5.

Inversion of sucrose during mashing and wort boiling. K. Schreder, R. Brunner and R. Hampe. i-/ochschr. Brau. 55, 49-54, 57-9 (1938) .--C,A. 33,

22779,

-VII Patents

1, Invert sugar. Eugene N. Ehrhart and Leonard Wickenden (to John J. Naugl~.)

U.S...:.. 1,886,875, Nov. 8.--C. A. 27, 1541.

2. Process for manufacturing a new sort of colloidal carbohydrate. Miyaguchi,

T. and Fukui, M., U, S. l,91~,639, May 30, 1933,--C.A. 27, 3995L

3. Invert sugar. Wm. A. LaLande, Jr. (to Attapulgus Clay co.) U.S. 2,461,163,

Feb.

8,

1949.- C.A. 43, 3222e.

4.

Inversion of sucrose. Wm. A, Blann (to American Cyanamid Co). U. S.

2,534,694, Dec. 19, 1950.- C. A, 45, 221J.7d.

-II

5, Sugar sirup. Jergen Meyer. Ger. 577,215, May 27, 1933.--c. A. 27., 3.995, 6. Invert sugar for making confections. Th~ Nulomoline Co. Ger. 618,324,

Sept. 6, 1935 (Cl,53f.3).--c. A. 30, 186.

7. Invert sugar. The Nulomoline Co, Brit. 373,413, May 26, 1931.-- C.A~

27, 3015

8.

Invert sugar from sucrose. Tsuneji Tanna (to Meiji Seito K.K.). Japan

References

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