X-ray Spectroscopy of Molecules Driven by Strong IR Fields
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(159) QF F3
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(367) 4 B B/8(
(368) . G =4
(369) 6 4 E 4
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(372) =43B +'5 E =B<
(373)
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(375) 4 =F B >4E 3" -$
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(378) 43B . 43 ,
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(382) lB ;
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(384) 4 = 3B
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(387) ;$
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(395) F 4E B B 4
(396) 54$6
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(402) 3= !4
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(404) 4; 3
(405) <(0
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(407) 4 =DE 83 <
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(409) <*( 4 4E 4E74 F= 4 ;< 4 B 8(
(410) + 7E
(411) ; 7 ; FB
(412)
(413) F33
(414) <
(415) =
(416) F 4 EB ! B 8(
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(418) : < 4 =
(419) F
(420) 4 4 543B 73
(421) 74B B 4E $
(422) ;
(423) =DC 4 B 2 3
(424) 6F3 E
(425)
(426) = 4
(427) F =B B ( 4 B +=DE
(428) 8
(429) 54 =B 54 B F B 4 E 8=F
(430)
(431) ;
(432) =DC 4
(433) 6F 4 E !4 B B F3=F3
(434) B 43 B 4 E
(435) 4
(436)
(437) ;
(438) 3F3
(439) 6F 65 4D
(440)
(441) 8(
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(444) 3 B
(445) .;
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(450) F <
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(452) B 4B 4
(453) 4 B 54 B 7
(454)
(455) F3 F3
(456) 4 B EB 4 E
(457) 44 E E
(458) B 4 E 3
(459) F3 4 B F 3 = 4 E 4
(460) = 4 B ! B 4 E 8=F3
(461) $
(462) ;
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(464) E = 84 E 8(
(465) . =4 +=DE
(466) = 3 =
(467) 65 4E 4
(468) B :4 E E
(469) 7B 4 E F3 4 B 4 E
(470) ;
(471) =DC 4 4 E B E 4 E 3 54 = B 4E B 8(
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(473) 4 B ( EB 4 B <(0
(474) +=4D
(475) 4 3B =DE
(476) F3 E 4 B F; 8(
(477) .7 =4
(478)
(479) > 4 ; 4B 4E> E
(480)
(481) 4 3B
(482) F3
(483) 743 6 4 . 4 E F3 E E
(484) B 4 E F3 3 = 4 E B F=F
(485) <
(486) 3=
(487) F3B E. 4 E :
(488) 6 3B< 6 =B =B
(489)
(490) 6F 4E 4E B+ B ;+6
(491) 4 3B 6
(492) C8 B 4 E B 4D
(493) 43 $
(494) ;
(495) B
(496) 4 3B. 3= 4
(497) E
(498) B q =4 E3=DE
(499) B 3 3. 4 =DE < 3 !4 3?B =DE 3=
(500) F <
(501) 3=?B q 84 4 =
(502) F3 04?3? EB 4 E
(503) 4?4 E
(504) F$ 4
(505) 4 3 54
(506) =4 B 4 E 4 E
(507) q = 4 4 E B 6 = 4 E 4 E
(508) B 6 F3 B,; F
(509)
(510) 4E!4 F3B 4 E>F3=4B = =B F q =4 <(0
(511) EB 4B+F3= 4 B = ( 4 B =B 5 E3=DE E
(512) = 54 F
(513) 4 4
(514) =4
(515) 4 4 543B B 84
(516) F3 4 4 B 4 4 ;<4 4 B 54
(517) B F=F
(518) 84
(519) =43B . EB 4 E
(520) 42
(521) F3 E
(522) =24 E
(523) !4D
(524) 43B B A4 E =B F ( q =4 4 E B E 4 E B
(525) 43B B 2 <4 ; ;<36
(526) 4 B
(527) F
(528) ;
(529) =DC 4 E 4EB !7B 8(
(530) . :
(531)
(532) 7=
(533) 44 . B B F3=F 4E !4 B 3 +(0B 64 =B F3
(534) ==B
(535) 3 65 F= 4 B +( EB F3 3 54
(536) = 4 3B >3 ; FB
(537)
(538) F3 4B F3
(539) 4 B B AB
(540) 54 8(
(541)
(542)
(543) . =
(544) 44 3 B 4 E FA B F3=F =3
(545) FA
(546) 4 4 543B 3
(547) 3 4 B4 E 4EB 43=
(548) F 4 EB<B FB 4 B = 4E =B 4
(549) 4 B
(550) F =B !4:B B $
(551) ;
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(554)
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(557) EB !4F3=4 B
(558) 4 3= F3 4 E
(559) 44
(560)
(561) 44
(562) = 4 3 +( =
(563) 3 84 4 4 B 4 3 54 3 3= B 4 54 3
(564) F 4B 5; !4 5
(565) 4 4E <
(566) 3= B 8
(567) 54 <!4 :3
(568) F 43 =
(569) F3
(570) 6 =
(571) B 4E B 63F4 4 B
(572) F3
(573) 4 <
(574) 54 !4D
(575) 4 3 (0B F ; >F
(576) =4 B =B 2B . = 4 ; >4 E 4 3 B A<
(577) 3=
(578) F B ( = $ !4 =4
(579) FA=DE 4 ! <63B F3B
(580) 4 E E5<3= B E
(581) 4
(582) 43B E:=B E 54 B 4 3B B 8
(583) 84 4
(584) 4 B $
(585) ;
(586) =DC 4 4 E
(587) 4 =
(588) 6 =
(589) 4 65 F3=4 B
(590) (. 4 3= F
(591) >=B 4B 6 3 B 4D
(592) 84: q 54?6
(593) =DEB E5+ 3=
(594) B<. 4 =DE B FB EF3
(595) $3 4 E?3
(596) F 4B+B F 4B =B 54B F B ; 7 4 E $
(597) ;
(598) =DC 4 B +( !4 4EB E4E ;
(599)
(600) 43B B 4EF3 E54
(601)
(602) 4 8 = E
(603) +
(604) 4 B 43 ?
(605) 3 54 4 7B 4 E B 84 B ;+ B =
(606)
(607) . 4E
(608) 4 F
(609)
(610)
(611) 6F3 4 B
(612) =4>
(613) =
(614) 4D
(615) F< 4 ;<3 4E4D
(616) 4 4B 4E 3
(617) 6F3 4
(618) 4 3B 4D
(619) 4
(620)
(621) F B<= 4 3 54 +( B 6 = 4 B =B 5 4 B 4 4B 6 4E
(622) <
(623) 4 4 4B 4 F 4
(624)
(625) 4 8
(626) 54 <
(627) 3= B F= 4 B
(628) 8=F3 B
(629) F3 4E
(630) 4 B 4 3B B 4 E 8=F
(631)
(632) ;
(633) =DC 4:3 4 E B 4 54
(634) F
(635) = E $
(636) ;
(637) =DC 4: 4 E
(638) 4
(639) F =B = 4
(640) 4 EB 4 3=
(641) F 4B+B F 4 B = 36 4E4 ; B F4 B B <
(642) 54 !+!4 4E <4 = 4 B *' >B E3!4 B 3=
(643) F
(644) = 4 B ?4E <
(645) 54 4EB !
(646) = ( 4 B =B 5 F3F 6 6 3 3 = E 3 54
(647) F ; B F4 B 4E ; F3B 54B EB 4 F
(648) F>
(649) 4 E 3 B
(650) 4 B 4E
(651) 4 =
(652) 6 B,;< 65 4E F4
(653) EB 4 F
(654) F
(655) 54 3 += ' CB += :' ED 3 3=
(656) 4 4 B 4 E 8
(657) 54 =B 54 B F B ?4 E
(658) 4B =
(659) B F3=F3
(660) <!4 4 E
(661) 4 F
(662) 24B 4 B
(663) B
(664)
(665) 4 E:
(666) =43B =B 84B F
(667) 4 E 8
(668) 84 =B 4D
(669) 4 3B
(670) FF 4E =DE
(671) 4 4 E += ' G ; B 4 4B
(672). ,. 6 .< k !< 5 G 4 4 4 "_5 T :< ? U 4 *u - 4 X214365P5 * ! / , k s A_ < 4 ' " , G QU C "87:9<; 5 " $ - N T 4 "< E < h p - ; & ? ? G G "s5 ] / " < " m 4 n T 7< 4 + 5 @ 4 / - $ h 4 4 8< N Am n m n i< - R ,^ '. g. . 4 . T. h. . .
(673) . G. . 4 R E 4. .
(674) . m O!n T. E
(675) 4 ; >4 ( B F; =4B =B 5 E3=DE =B 6 :EB 4
(676)
(677) < =DEB 4B
(678)
(679) 43B F3 4B !4 + F 4
(680)
(681) 4 8=F3
(682) <
(683) 3= +=DE C< B : = ( 4 B =B 5 3
(684) B 3 54D
(685) F 4B+B F !4 3 B >4 B
(686) 6 >4 B =B B+= 3 B F3=F3
(687) E5<=
(688) =DE 3!4 !. 4. . "!. , " @ &. $. . &. % ",- / )> ,-)> ? #>'! ( #>'< : )* ? ) %", . . 0. T. 4 . Q P< "s5 NO. . )*& +,#* #> %. ? ?U s . G ,. 4B =
(689) FF = 4 B =B 5
(690) 4 E
(691)
(692) E 8
(693) 54 =DE
(694) 3=
(695) !4 == F3F
(696) F33 +
(697) 4 E E5+ 3=:6 E3 4E
(698) 4 B ? =
(699) B F=F
(700) = 4
(701) F F3 $
(702) B F3B >4 E
(703) 3
(704) B 8
(705) 54 =DE
(706) = E>"$
(707) F3 !( <6 8
(708) 4 3B . ,. h <. ). &U. 1 = Ry λ. -. G <. 1 1 − 2 2 nf ni. !. T. m!''n. ,. k. ;. . =
(709) 6 =B
(710) 4 E !4
(711) ==
(712) 4 3 3=
(713) F8 = 4 B B A4 E B 43B B 4 E
(714) 4 B 3= = 4
(715) F F33 3=4 ' ' 34 E $
(716) ; F3 4E
(717) 3 54
(718)
(719) λ n i , nf Ry ;
(720) F=B !4D
(721) 54 2 4E
(722) B ' - -?D
(723) 7'.- -NG<5"$
(724) F EB 3
(725) B 4 3 54 4 3 =3 = 4 F 64
(726) = 4
(727) FF 8 B F3B <3 =B.; 7
(728) B F3
(729) 4B>=B 4 :4 E ' % F3 B 4 E
(730) EB =4
(731)
(732) FF:4E F3 3 4E ;<3 36F B '.- % <6 B 4 4 E "$
(733) F 3B 3 4 B
(734) ; F3 4 E
(735) E +4 44 B = 36 4 E B ?4E
(736) F3C
(737) F 4D
(738) F3 4 E
(739) FC
(740) F3
(741) 4 E
(742) B 4E F 54 84B<=3 4 E
(743)
(744) 4 !' ' E=DE C< B
(745) 4 E <6 =B 4D
(746) 84. T. . . . k. . *, 4 . T. m 'K\<V(m 4 nTn R. -. 4. f . y. P '4'A " k E54. !. ,. 4 P ' % R @ O T . T. . F33 = 4
(747). O. G. ,.
(748)
(749)
(750)
(751)
(752) . 4 *u . K\<Xm 4 Wn J ] N N Q< , r?5 l< ku "Q5 < 5 * 4 G s0 W T " G `< c I `K V0 T 8M 5 4 6< -5 R / 4 _< *u e m * 4 n W p R\0 %< W ' 4 ! >< < ] f5 e , . . , h. G $ < h V , ] 4 4 7 'O T r Q \ h TL , iI eI 4 , h :< ( >< " @ , @ % % + 1 9 1 5 = - . 04 B 6F3 4 B =B B *' ' 4E
(753) 4 4 E
(754) .; F 4E B 4 E =4
(755) F F33
(756)
(757) F $
(758) < ;
(759) ?4 E>rq = 6 4 4 B 8
(760) 8443
(761) 4 E
(762) 4 B 8 =
(763) 4 68
(764) F ;
(765) F =B 4
(766) 54 E " B E
(767) 4 B 3= B+F B '.%'B E=DE =B +( 8
(768) 54 7 B 54D
(769) B 4EF=4B 3
(770) =DE F3=4B =B 64+6 B E54 4E
(771) =4 4 B 4E E " B E 4EB 3
(772) 6F 4B =B =4F =36 4EE5< B
(773) 4 B B !4 3 B+=3 4E "$
(774) F $ 8
(775) 43B 7
(776)
(777) 7
(778)
(779) F84 =
(780) F 3B B $4 E <6 =B 4
(781) 54 E7" B E = +4 3B B 4E E5+B
(782) 4 B 3
(783) 6F3 4 B =36 4 E B 4 B B :4 E F3 3 4 E
(784) 4 B 3= =4
(785) B ; 4E3$4EB ! 3
(786) 6F4 B F3
(787) 3 4E 3!4 3643B B 3 54 4 B 4E: =4
(788) F F3 @
(789) FA4EB B =4
(790) F F3
(791) 63F4 B F
(792) 424 E =
(793) 43B B 8
(794) 54& =DE
(795) =
(796) .; =DE
(797) = B +=DE <3
(798)
(799) 4 =DE
(800) 3= B " B 3 86
(801) B
(802) E ; FB 54 B 4E 8
(803) 54 4EB !
(804) B 4 E
(805) 4 B 3= B+F $
(806)
(807) ( q B 4>B
(808) 5 =3 843!4 E 3
(809)
(810) 6 B 44E
(811) 4 B E3=DE 4
(812) 4 4 B76 ; F3B 68 4 E
(813) +( = 54 C EF3B B E
(814) =DE; 4 8
(815) 54 B 4E 6 B 4 E 4 E = 84 ' # B $
(816)
(817) + =
(818)
(819) 4E
(820) 4 4 E 6
(821) =DC B B 4E 8
(822) 84&4 EB 3 F3F8!4D
(823) 6<( F3E :B ; 4 E =
(824) B 4$6 =B
(825) 4 E? B
(826) =DE 8
(827) 54 =DE
(828) = @ =4
(829) FF 4 E 8
(830) 54 4 EB EB 4 E
(831) 4 3 B 6F3 4 B 63F
(832) 5 =43 74 =DE<(. B FB =
(833) F ;<3=?4 E
(834) 4 =B =;
(835) 6F B 4 E =F3
(836) 3=
(837) F 4EB 3 +B
(838) F B = 84 ; F3B 54
(839) 8
(840) 54 4F B 4
(841) 4 B
(842) 8
(843) 54 =B 4D
(844) 43B E
(845)
(846) FB 4 B 4EB 43=
(847) F
(848) 3 54D
(849) F q B !4 3 4E
(850)
(851) 64 B
(852) $ 4 E B 4 E
(853) 4
(854) =43=
(855) F E
(856) 4:=DE
(857) F3F3 B B< =3 = 3 4 E E5<=B =B F <!4 . !" #$ %"'&()* + +, - $ . /'01/ - )*03254 )*06& $ 7 +098. P '4 gA. !. "!`i. . −→. −→. : ;=< > ?A@CB DE;=F < G HEIAJAJAK. −→. L*M L9M1N'O1?APRQ ?A@ B HEIASATAK. −→. UVM1WYX1> O1DEF Z ?AF [ B HES\HAH=K. 4. −→. ]^M1_V?AO1F`B HES\HEa6K. 4 E. <B C =3 54 3!4 :
(858) =DE B B FB =
(859) F ; B F343B B. −→. b\c O1F d\[1e @1fADEFB H=SAgAhAK
(860) 4B 3= B+F. . / );'kj #'! +' "' /A /# ) # / + /" . Z * E54 @?-FkU=
(861) 4 B 65 <4 F3
(862) 4 K2 3 3B Bh;O:
(863)
(864) 4 3B =
(865) FF3 Z @KO 3 B Bh 4 E
(866) 4 4 4=DE B F3B4 =
(867) F
(868) =DE; 54 Bh 4E 4 E = 54 !4\5 EU 4 F
(869) :=B !4 =4 3 '.% $5 E 4E6 B+= B 43 F
(870) 4 3B m
(871) h 4 2K23 4 3 Vn4 B
(872) %Fk F* E54
(873) .; 3 B 4 BP B+= B B+=DE B
(874) 4 =?F3k E54r\5 E F3
(875) , 4
(876) 4. B 4E/- B 4 E.
(877) . .
(878) . h\ .5 G ? > +85 - , ; R +3 =>4E> 3 - 4 E2
(879) 4 3B B EB 4
(880) F 4
(881) EB 4 F
(882) )F3 E
(883) ?=;
(884) =B
(885) 6F3:3 54 4f B 4 E?=3 84k U = =B 4 45 E
(886) B > B 4 E 4E
(887) 4 EB !4
(888) F 4
(889) EB !4?F3
(890) !F3 E
(891) ; 3 =
(892) ,
(893) F3=
(894) 43B
(895) 5 3 43 = 4?6
(896) =DEB = = F3C B F3
(897) B443= 63B4E5<= B< B
(898) 43B
(899) =B > 3=
(900) 4 B 4 =DE B FB4 3 5 E7
(901) 4- B+=& B 3 !4D
(902) = =
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