Analysis of waters for campaign 1947-1948 Billings factory

(1)

cc-General Chemist ..,,--Asst. Gen. Supt. Superintendent

District Engineer

Laboratory

ANALYSIS OF WATERS FOR CAMPAIGN

1947-1948

BILLINGS

FACTORY

THE

GREAT

WE3TERN

SUG

AR

CCMPANY

()

"

JU

7 1948

GE~'L

lJHt~i

oT

G. W,

S. CO

(2)

INDEX

KIND OF

W

ATER

PAGE

Main Tank

1 City

2 Battery Supply

₃

Press

W

ash

₄

Centrifugal

W

ash

₅

Cold Sacch. Cake

W

ash

6 Boiler Feed

₇

(3)

Form 448-2M--7-45-Pads 100

WATER ANALYSIS

.

...

.

...

BILLINGS

...

..

...

.

. Factory

...

. June

..

1 .

.

...

.

..

...

..

194 ..

8 .

Kind of Water:

River

Water

Description of Sample:

_Average

_{Sal!!Ple for 1947-48 Ca.J!lpaigp.}

_.

pH

8 .

1

Source of Water:

_{Yellowstone River}

Intake one mile south of factory

ANALYSIS

M

HYPOTHETICAL COMBINATIONS

M

PartsPermw,c Parts Per :IXIKIKO

Silica Iron Calcium Magnesi~m Sodium Chlorine Sulfuric~ Carbonic Acid Phosphoric Acid Si0₂ Fe Ca Mg Na Cl

so

C0 3 _ _ _ _ _ _ _ _ _ _ P04_

17 o

0

1.0

39 .

2

14 .

2

3 .

3

Silica Sodium Chloride Sodium Sulfate Sodium Carbonate Sodium Phosphate

8.. 5

Magnesium Chloride

7 4..

9 ___

___!1:agnesium Sulfate

80 .

5

Magnesium Carbonate Si02 NaCl Na2S04 Na₂C0₃ Na3P04 MgC1₂ MgS0₄ MgC03 -_ _ _ _ _ _ Magnesium Phosphate Mg₃(P0₄)₂, _ _ _ _ _ _ _

Calcium Sulfate CaS04

Calcium Carbonate Calcium Phosphate

---·

· -~

CaC03

Ca3(P04) 2

Ferrous Carbonate FeC0₃

Ferrous Phosphate _Fe₃(P0₄~ _ _ _ _ _ _ _

_________________

,;;;....

&.u,5._6

__

-Organic and Volatil:._(by differen.=_e) ]

1

6

Organic and Volatile (by difference)

_ _ _ _ T_O __ T_A_L_ S_O_L_I_D_S_A_T_l0_6_0

_C _ _ _

__;;;

2

•

2

TOTAL SOLIDS AT 106 ° C

COPIES TO

General Chemist

· Asst. General Supt. District Engineer Superintendent Laboratory

17.0

14 .

0

76.6

28 .

9 _

29 .

1

2 .

1

265 .

6 ll

,

6 2-TI

.

2 -1

-

Chief Chemiet.

(4)

Form 4·l3~-2M-7-45- Pads 100

WATER ANALYSIS

________________

_

BILLINGS _

__________________ Factory

_

___

__

________

____

_

__

___

__ J.:une.

__ ).

_

__

_____

____

_

___

194 __

8 __

Kind of Water:

: Description of Sample:

_

City Water

_

Average Sample f0.r

1947-48

Campaign.

Source of Water:

_{River water treated and filtered...}

_{thru City}

_{W.ater Plant.}

-Silica _ _ _ _ _ · Si0 2 Iron _ _ ..,... Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl Sulfuric Acid _S04_ _ Carbonic Acid _ _ C03 Phosphoric Acid PO ANALYSIS

M

PartsPerUl!XIKl) 18.2

1.3

43 .

7

17.4

27.3

8.3 _ _ _ _ _ _ _ _ _

74 .

9 ___________

91.

___

__,__.;_·

---HYPOTHETICAL COMBINATIONS

M

Silica Sodium Chloride Sodium Sulfate Sodium Carbonate Sodium Phos,phate Magnesium Chloride Magnesium Sulfate Magnesium Carbonate Magnesium Phosphate Calcium Sulfate Calcium Carbonate Calcium Phosphate Ferrous Carbonate Ferrous Phosphate Si02 NaCl Na2S04 Na2C03 Na3P04 Mgc1; -Parts Per 120QR 18.2

13 .. 7

67.6

MgS04_ _ _ _ _ _ _ _ _

36.,6

MgCOa, _ _ _ _ _ _ _ _ _

34_.

7

Mg3(P04)2 CaS04 CaC03 Ca₃(P0_{4 ) 2} FeC03 Fe₃(P0_{4 ) 2}

2.

Organic and ~olatile (by difference)

282.6

_ _ _ .;;;2a..:a0a...,...,6:.. - - - -Organic and Volatile (by difference)

303.2

TOTAL SOLIDSAT 105° C

82 ....6

20.6

TOTAL SOLIDS AT 105° C

COPIES TO

General Chemist Asst. General Supt. District Engineer Superintendent Laboratory

30J.

-2-Chief Chemist.

(5)

Form 448 -2M-7-45- Pads 100

WATER ANALYSIS

____

____________________

BILLINGS

___________

Factory

__________________________________

June

_

1 ___________

194 __

_

8_

Kind of Water: Description of Sample: Source of Water: Silica Iron Calcium Magnesi~ Sodium Chlorine Si02 Fe Ca Mg Na Cl S0₄

Battery

Supply

Average

Sample for the 1947-48 Campaign.

--~---All

drips from hot

condensers

of Evanorators,

drips

__

from Vapor Pan, ove_

rflow from Press

Wash

.

- - - -

-ANALYSIS

M

Parts Per llOIKll®C

10 ... 2

1 .

4

28 .9

14.2

8.2 6 .. 5

_ _ _ _ _ _ _ _

_

a.6

HYPOTHETICAL COMBINATIONS M Silica Sodium Chloride Sodium Sulfate Si02

...

Nii"""c

l

Na2S04 Na₂C0₃ Na3P04 MgCl₂ -PartsPer~O

---10.2

10.7 4J.2

MgS04

24.J

Sulfuric Acid Carbonic Acid_ Phosphoric _Acid C0 3 , _ _ _ _ _ _ _ _ _ _ _ _

67..'J

Sodium Carbonate Sodium Phosphate Magnesium Chloride Magnesium Sulfate Magnesium Carbonate Magnesium Phosphate Calcium Sulfate Calcium Carbonate MgC03

- - - -

J2.2

Mg3(P04)2 POA

COPIES TO

~ - -

195.1.

20.3

2

6

Q - Calcium Phosphate Fer'rous Carbonate

Ferrous Phosphate CaS04 CaC03 Ca₃(P0_{4 ) 2} FeC0₃ Fe₃(P0_{4 ) 2}

-3-72.2

2.9 _ _

195.7

20.3

216.0

Chief Chemist.

(6)

Form 443~2M-7-46--.Pads 100

WATER ANALYSIS

______________________

:alli1

_

JNQQ

_______________ Factory

_{··-···June_}

₁

_{_______________}

_{194_8}_{__}

Kind of Water: Description of Sample: Source of Water: Silica Iron Calcium Magnesi~ Sodium Chlorine

Press Wash

.Aver.age Sample _for t

h

e

J.9.47-48

Campaign

Condensed waters from all 1st effect evaporators, Battery

Calorisators, all heaters and overflow from Boiler Feed.

Possible to send Battery Supply

to

Press

W

ash..., and drip

§....

from

all

evaporators,

blow-up traps, and o..ffice hea

.

ting

system.

ANALYSIS

_M

PartsPerilm,@jjK HYPOTHETICAL COMBINATIONS Silica Sodium Chloride Si02 . NaCl Sodium Sulfate Na2S04 Sodium Carbonate Na2C03

Sodium Phosphate NagP04

Si02 Fe Ca Mg Na Cl

so

..._

_______________

._

.

Magnesium Chloride MgC12 Magnesium Sulfate MgS04 Magnesium Carbonate MgC03

M

Parts P e r ~ Sulfuric Acid_ Carbonic Acid Phosphoric Acid C03

P0₄ Magnesium Phosphate Mg₃(PO,;..a,:):.a.. _ _ _ _ _ _ _ _ _ _ _ _ _

Organic and Volatile (byd ifference)

COPIES TO

2a ..

o

·

Calcium Sulfate .CaS0₄

Calcium Carbonate CaC03

Calcium Phosphate Ca₃(P04 );

-Ferrous Carbonate FeC0₃ Fenous Phosphate Fe₃(P0_{4 ) 2}

Organic- ; ;d Volatile (by difference)

, _ _ _ _ _ _ _ _ T...,;O_T_A.;,,.L_S.;,,.O.;,,.L_I.;,,.D...,;S...,;A.;,,.T.;,,_l.;,,.06;...0

_C:;;.,_ _ _

__;

2 ..;,,;

8.,0,'

(7)

Form 448 -2M- 7-45 -Pads 100

WATER ANALYSIS

..

....

.

...

. BILLINGS .

...

..

... Factory

······;············J.une ..

l~

....

.

....

.

194 .

.8 .

.

Kind of Water:

_W

_{ater used to wash white sugar}

_.

-Description of Sample:

_{Average sample}

_.

_{f.or the}

₁₉₄₇

_-

₄₈

_Ca

_m

_{r.e.ign.._}

- -~----~

--- ---

---Source of Water:

_Drips

_{fro the steam}

_{_}

_ch.es

_t..

_{of the}

_3rd

_efi'ect

f

north evaporators

.

_---~--

_----

-ANALYSIS

M HYPOTHETICAL COMBINATIONS

M

PartsPerlQ!!I

Silica _Si02 Silica

Iron Fe Sodium Chloride

Calcium Ca Sodium Sulfate

Magnesium Mg Sodium Carbonate

Sodium Na Sodium Phosphate

Chlorine Cl Magnesium Chloride

Sulfuric Acid. _ _ _ _ -""Sc.;:O,,._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Magnesium Sulfate . Carboni."'-c_.A""'c,,.i.,._ _ _ _ C0₃_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

1 Magn~sium Carbonate

_ Pho§illl~ric Acid P04 Magnesium Phosphate

Calcium Sulfate Calcium Carbonate Calcium Phosphate Ferro~ Carbonate Ferrous Phosphate Si02 NaCl Na2S04 Na₂C0₃ Na3P04 Parts Per lwgtl

---MgCl2 MgSOi MgCO ..l!-Mg3(P04) CaS04 CaC03 Ca₃(P0_{4 ) 2} FeC0₃ Fe₃(P0_{4 ) 2}

--- ---0-rg-anic and Volatile (by difference_)_ _ _ _ Organic and Vo_la_t_il_e_(b_y_d_i_fferenc~e_) = ~

-_ -_ -_ -_ -_ -_ -_ -_ T::..O~T~A=L:..::.S~O::..:L:::I:.:::D~S;..:A:.:.T::....;;1.;;,;05:;..0

_C,;;... _ _ _ _ '"""'·'LlQ.,___._ _ _ _ _ _ _ _ T_O_T_A_L_ S_O_L_I_D_S_A_T_l0_5_0

_

c

____

...,..._

..,O

COPIES TO

(8)

Form 443----'2M-7-45- 'Pads 100

WATER ANALYSIS

__

_

____________

___

_

____

__

BILLINGS

___________

Factory

_···

_··

_·

_-

_···-

_·

_··

_{-··-··-··}

_··-

_---June

_....

_{1 __________}

₁₉₄

_...

₈

Kind of Water: Description of Sample:

Cold Saccharate Cake Wash Water

Average

Sample

for

Campaign.

- - - -

--

- -

-

--~

--- --- --- --- --- --- --- --- --- ---

-Source of Water: Silica Iron Calcium Magnesium Sodium Chlorine Sulfur~ id _ _ _ Carbonic Acid Phosphoric A1.d

6C!/o

City

W

ater

40%

Well

Water

ANALYSIS Parts Per 100,000 Si02

26.0

Fe

1.0

Ca

31.4

Mg

22.9

Na _ _ _ _ _ _ _ _ _ _ _ _

.._()()._l

Cl

l3.D

so

~

23.05

C03

780

9

P0₄ HYPOTHETICAL COMBINATIONS Silica _Si02 Sodium Chloride NaCl Sodium Sulfate _Na2S0₄ Sodium Carbonate _Na2C0₃ Sodium Phos,phate Na₃P0₄ Magnesium Chloride _MgCl2 Parts Per 100,000

26.0

21.4

283.2

_ Magnesium Sulfate ~ gS0₄, _ _ _ _ _ _ _ _ _ _

5.1.~

43.3

Magnesium Carbonate MgC0₃ Magnesium Phosphate Mg₃(P0_{4 )}₂

Calcium Sulfate

CasO:--Calcium Carbonate CaC03

- - - ·•- Calcium Phosphate Ca

3(P04)2

---Organic and Volatile (by difference)

---COPIES TO

General Chemist Asst, General Supt. District Engineer Superintendent Laboratory

5-05 ... 8

26,8

532.6

Ferrous Carbonate FeC0₃ Ferrous Phosphate Fe₃(P0_{4 )}₂

----

_{TOTAL SOLIDS}

- -

_AT

--

_106°_C

-6-2.1

_

50~8

26.8

532 .&_

Chief Chemist.

(9)

Form 443--'>!M-7-4'.5-'.t'ads 100

WATER ANALYSIS

BILLINGS

.

..

.

...

.

...

..

...

... Factory

..

.

...

....

June

..

1 ...

194 ...

8

Kind of Water: Description of Sample: Source of Water:

Wa.t_er

in

Boiler Feed Tank

AYerage

· sample for Campaign.

----~--

~---Dri2s

from

2nd,

3rd,

4th, and

5th bodies

of the evaporators.

Drips fro.m. pans after

flashing

to Exhaust

All live steam traps

---

---ANALYSIS M PartsPertXOOlllO HYPOTHETICAL COMBINATIONS PartsPerlL Silica Si0 2 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _Silica _Si0 2 NaCl Na2S04 Na2C03 Na3P04 MgC1₂ MgS0₄ Iron Fe Calcium

_{- - -}

Ca Magnesium Mg Sodilll_!!_ Na Chlorine Cl Sulfuric Acid SO _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Carbo ic cid _ _ _ _ 0'-'"'0₃ Phosphoric Acid PO

Sodium Chloride Sodium Sulfate Sodium Carbonate

Sodium Phos,phate Magnesium Chloride

-M2-esium Sulfate Magnesium Carbonate Magnesium Phosphate Calcium Sulfate Calcium Carbonate Calcium Phosphate Ferrous Carbonate Ferrous Phosphate MgC0 3 _ _ _ _ _ _ _ _ _ Mg 3(_P_O""') _ _ _ _ _ _ _ _ _ _ _ _ _ CaS0₄ CaC0₃ Ca₃(P0~.;;;,_ _{4 ) 2}

______ _

FeC0₃ Fe₃(P0_{4 ) 2}

Organic and Volatile (by difference) _Organic and Volatile (by difference)

_ _ _ _ _ _ _ ,_;;T;..;;;O;..;;;T;.;;;A;.;;L;...S;;;..O;;;.,;L;;;,;I;,;;D~S'-'A""T~ l.;..;05'-0 _C;;.._ _ _ _ . -2 7 -- - ' - - - -T-O--T __ A __ L ____ SO--L_I __ D...;.S;_A.;.;;.;;.T __ l.,;,.05--0 _C~ - -

_27.0

\

COPIES TO General Cliemist Asst. General Supt. District Engineer Superintendent Laboratory

(10)

Form 448-2M- 7-46-Pads 100 ' t '

"

WATER ANALYSIS

____

___

__

_

____

_

___

___ .B.JJ.L..lNG.$.

____

_

________

Factory

_---

_--

_---

_----

_--

_-

_---

_-June

_{_}

_l

_~--

_----

_-

_-·

_·

_·-

_{·-·194 .}

_.

₈

Kind of Water: Description of Sample: Source of Water: Silica Si0₂ Iron Fe Calcium Ca Magnesium Mg Sodium Na Chlorine Cl _ Sulfuric Acid S04 Carbonic Acid C0₃ Phosphoric Acid P04

Water in

Boilers

Average Sample

for

1947

-

48 Campaign

.

Added to Boilers: Caustic

Soda

Tri.

Sod.

Phos

.

SQ<l

.

Sul_phite

Alkalinity

Hardness

P04

Pounds

For Camp

.

2935

1820

279 EE!!!

20,f-

4-BO

-A

g._

131 Per

Day

34 .9

21 .

7

3 .

3 ______

__.

ANALYSIS _M HYPOTHETICAL COMBINATIONS

_M

Parts P e r ~

9 .

0

2 .

8 T

.

9

426 .

0

13 .

5

92 .

6

52 .

7

80 .

0

Silica Si02

Sodium Chloride NaCl Sodium Sulfate Na2S04 Sodium Carbonate Na2C03 Sodium Phos,phate Na₃P0₄ Magnesium Chloride MgC12 Magnesium Sulfate MgS04 Magnesium Carbonate MgC08 Magnesium Phosphate Mg3(P04 ) 2

Calcium Sulfate CaS04 Calcium Carbonate CaC03

Calcium Phosphate Ca₃(P0_{4 ) 2} Ferrous Carbonate FeC0₈ Ferrous Phosphate Fe₃(P04 ) 2 Parts P e r ~