Agenda for technical observers meeting, February 21 and 22, 1967

- ;

AGENDA FOR TECHNICAL CBsrmVi;;PS .i'.':i:::t:;fl'IXe:; FEBRUl'-,JW 21 AND 22, 1967

Note: ~hree hour break during midday for followup ~uestio~s, _ 3~ussia~

and inspection of facilities.

Ten minute breaks will be observed at 10:00 a.m. c.r:d 3;CC

each day. 9:15 t.o 10:00 10:10 to 11:00 2 : 00 ·co 4: 00 't'!edr'.esday 9:00 to 10:00 10:10 to 11:00 2:00 to 2:30 2:30 to 3:00 3:10 to 3:45 3:45 to 4:00 of Retort Seotion Studies

1 to 2 - 1/2 L:.c h

1/4 to 2 1/2 Inch Shale

1/4 to 1 Shale Material Balance Status Bench Scale Studies

Mechanical Models and Corrosion Future Plans

Mechanical Engineerinq Mining- Studies

Analytical Laboratory

Engineering & Economic Analyses Crushing Studies

~ecent Engineering Studies

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Handout 1

YIELDS - RETORT NO.3

Totalizer Raw Time Tape Raw Shale Rate Shale Rate

C990-3 thru 6 87.3 85.6 C990-7 and 8 90.5 88.7 C990-9 thru 19 87.2 85.2 C990-20 and 21 85.0 84.6 C990-22 thru 25 81.8 83.2 Average (86.4) (85.5) C990-3 thru 6 and C990-9 thru C990-l9 (87.3) (85.4)

Overall Material Balance C990 Series~ Average

Actual 101.2

Assume 1% error in Ash 100.4

---c

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C990 Series, Average

Actual

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Same as B952 100.7

Same

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j,.~. ..;...

Handout 2

DISTRIBUTION OF ORGANIC CARBON

Basis - 87% yield

- ±

unaccounted organic carbon

Assumed to be in vent gas

Wt % Organic Carbon In

Retort Shale size, Liquid Spent

Run No. No. inches Product Shale Vent

C990 (2 thru 26) 3 1 - 2 1/2 65.7 19.5 (14.2) (1) C990 (2 thru 26) 3 1 - 2 1/2 65.4 18.9 15.7 B952 (A thru L) 2 1 - 2 1/2 66.4 15.5 (18.1) B953 (A thru N) 2 1/4 - 2 1/2 65.7 14.3 (20.0) B817 (A thru U) 2 3/4 - 1 1/2 65.7 13.8 (20.5) B969 (A thru W) 2 1/4 - 1 66.3 10.8 (22.9) 794 thru 808 1 3/4

- 1.

1/2 65.2 15.3 (19.0) (Richness study)

Bench Scale FA equip- 8 . - 14 rresh 65.2 22.1 (12.7)

ment

(l)output Basis - Unaccounted (±) carbon distributed equally

percentage wise. ~

( )Inc1udes unaccounted (±) organ~c carbon.

Areas of Concern in Material Balances

1. Raw shale and spent shale sampling.

2. Raw shale measurements.

3. Oil and water measurements.

4. Gas measurements - air and vent.

5. Gas sampling.

EETurner 2/12/67

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ANALYTICAL LABORATORY SECTION

•

OUTLINE OF PRESENTATION TO TECHNICAL OBSERVERS February 21-22, 1967

I. Dust Counting

II. Moisture 'on Large Shale from Retort

III. Latest Quality Control Data

IV. Final Evaluation of Foxboro Total Hydrocarbon Analyzer

V. Final Paulsboro Data on Fischer As and Retort Oils

VI. Analysis of vJater Samples for Corrosion Work

DLiederman 2/17/67

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TYLAB MOISTURE CONTENT Ty1ab Oven Temperature 1/4 - 255 F 1/12 - 258 F

% of Total Loss --- % Loss In Weight ---­

Sample Sample Wt. 3 Days 4 Da:y:s 5 Da:y:s 6 Days 7 D~ 8 Days 9 Days' In 48 Hours

C990-16 77.6 1.0 1.3 1.3 1.3 77 C990-17 98.6 1.7 1.7 1.7 1.6 100 C990-24 87.2 1.6 1.6 100 C990-2.6 85.7 1.6 1.8 89 PTC994 85.0 1.3 1·.4 ~93 C994-2 155.6 1.6 1.9 84 C994-1 84.8 1.3 1.4 93 C997-1 160.8 0.6 1.0 1.1 55 C997-2 166.3 1.2 1.3 1.4 86 C998 Startup 50.6 2.0 2.0 (65· 100 Hours) C1000 Startup 69.8 1 .. 4 1.4 100 C1000 Startup 70.1 1.1 '1.1 100 RBernheimer 1/13/67

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Table 1

Reduced Pressure Distillation by ASTM Dl160

of Shale oil Bottoms From Analytical Distillations

Bottoms, 600

o

_F+,

_{Bottoms, 600°F+,}

Dist'n. J-963,

Dist'n. J-936,

Retort Oil

Fischer

Assa~Oil

RD Sample No.

66-39498

66-61578

" Volume

Obs • •p

Equiv. °P'*

Cbs.

of

Equiv. 0p*

Over

,I

mm

, 760 mm

, 1 mm

_I

_760pY!!

1BP

284

634

291

643

5

303

658

312

670

10

320

680

325

686

. 20

344

710

352

721

30

379

754

385

'761

40

410

792

413

796

50

442

831

443

833

60

473

869

475

871

-

70

515

919

514

918

80

563

976

559

971

90

628

1051

627

1050

95

690

1121

(Cracked)

*

"Vap. Press Charts for Petre Hydrocarbons"

Maxwell and Bonnell, April, 1955.

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FIGURE 48

•

C990

COMPARISON OF OBSERVED YIELD WITH YIELD . PREDICTED FROM RETORT NO. 2 DATA

e:s.r'_.J'Hre:O .. L1 9S"7" C.L~ C;.~ £t.J1.I C;C i .6 ) KIJagel 67

"..-­

~IR

RATE VERSUS 02 CONCENTRATION IN < ' _ _ _ _ _ , _ _ _ , , _ ,___. _

VENT~S

FOR VARIOUS AIR EQUIVALENT OXYGEN ---_P __ .._ _ _ _ _ _ _ _

CON~TION

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FI~49

(Basis: 300 Mass Rate Operation In Retort No.3)

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